离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用

引用本文: 杨新月, 高莉, 孙亚明, 赵文杰, 向国强, 江秀明, 何丽君, 张书胜. 离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用[J]. 分析化学, 2020, 48(12): 1607-1615. doi: 10.19756/j.issn.0253-3820.201421 shu

Citation: YANG Xin-Yue, GAO Li, SUN Ya-Ming, ZHAO Wen-Jie, XIANG Guo-Qiang, JIANG Xiu-Ming, HE Li-Jun, ZHANG Shu-Sheng. Preparation of Ionic Liquids-modified Metal Organic Frameworks Composite Materials and Their Application in Separation Analysis[J]. Chinese Journal of Analytical Chemistry, 2020, 48(12): 1607-1615. doi: 10.19756/j.issn.0253-3820.201421 shu

离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用

杨新月 ^1, ,
高莉 ^1, ,
孙亚明 ^1, ,
赵文杰 ^1, ,
向国强 ^1, ,
江秀明 ^1, ,
何丽君 ^{1,
,} ,
张书胜 ^2,

1.
河南工业大学化学化工学院, 郑州 450001;
2.
郑州大学现代分析与基因测序中心, 郑州 450001

通讯作者: 何丽君, lijunhe@haut.edu.cn

基金项目:
本文系国家自然科学基金项目（No.21577031）和河南省属高校基本科研业务费专项资金（No.2018RCJH03）资助

摘要: 金属有机骨架（MOFs）是一类新型多孔材料，具有孔径均匀、孔结构可调、易于合成和结构多样等特点。用离子液体（ILs）修饰MOFs构建的ILs/MOFs复合材料，在保留MOFs的结构特点外，还兼具ILs物化性质可调控和稳定性高等优点，在分离分析领域具有较大的发展潜力，引起了研究者的极大兴趣。本文主要综述了近五年来ILs/MOFs复合材料的制备方法及其在分离分析中的研究和应用进展，包括在吸附/萃取、色谱分离以及光谱和电化学分析中的应用研究，并对其发展趋势进行了展望。

关键词:

English

Preparation of Ionic Liquids-modified Metal Organic Frameworks Composite Materials and Their Application in Separation Analysis

1.
School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China;
2.
Modern Analysis and Gene Sequencing Center, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: HE Li-Jun, lijunhe@haut.edu.cn

Received Date: 17 July 2020
Revised Date: 11 September 2020
Fund Project:
This work was supported by the National Natural Science Foundation of China (No. 21577031) and the Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology (No. 2018RCJH03).

Abstract: Metal organic frameworks (MOFs) are a new type of porous materials with some unique characteristics such as uniform pore size, adjustable pore structure, easy synthesis and structural diversity. Ionic liquids-modified MOFs (ILs/MOFs) composite materials not only retain the structural characteristics of MOFs, but also have advantages of adjustable physical chemical properties and high stability of ILs, showing great application potentials in separation and analysis fields. This article mainly summarizes different preparation methods of ILs/MOFs composite materials, and provides an overview of ILs/MOFs in separation and analysis, including adsorption/extraction, chromatographic separation, spectrum and electrochemical analysis, in the latest five years. The trends of future development are also discussed.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用

通讯作者: 何丽君, lijunhe@haut.edu.cn

English

Preparation of Ionic Liquids-modified Metal Organic Frameworks Composite Materials and Their Application in Separation Analysis

Corresponding author: HE Li-Jun, lijunhe@haut.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

离子液体修饰金属有机骨架复合材料的制备及其在分离分析中的应用

通讯作者: 何丽君, lijunhe@haut.edu.cn

English

Preparation of Ionic Liquids-modified Metal Organic Frameworks Composite Materials and Their Application in Separation Analysis

Corresponding author: HE Li-Jun, lijunhe@haut.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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