Capacitance Characterization of the Effect of pH Value on the Self-assembled Monolayers of Octadecanethiol

Ke Qiang DING Qing Fei WANG Ru Ting TONG Hui Bo SHAO

引用本文: Ke Qiang DING,  Qing Fei WANG,  Ru Ting TONG,  Hui Bo SHAO. Capacitance Characterization of the Effect of pH Value on the Self-assembled Monolayers of Octadecanethiol[J]. Chinese Chemical Letters, 2003, 14(4): 411-412. shu
Citation:  Ke Qiang DING,  Qing Fei WANG,  Ru Ting TONG,  Hui Bo SHAO. Capacitance Characterization of the Effect of pH Value on the Self-assembled Monolayers of Octadecanethiol[J]. Chinese Chemical Letters, 2003, 14(4): 411-412. shu

Capacitance Characterization of the Effect of pH Value on the Self-assembled Monolayers of Octadecanethiol

  • 基金项目:

    This work was supported by the NNSFC (29973026).

摘要: In this paper, the membrane capacitance (Cm), which was obtained from the electro-chemical impedance spectroscopy (EIS) method, was used to characterize the effect of pH value on the self-assembled monolayers (SAMs) of octadecanethiol(18SH) for the first time. The results not only strongly proved that inorganic ions could penetrate the SAMs of 18SH, but also ascertained that SAMs of 18SH were not an absolute of free of ion-penetration. Verifying the existence of pin-holes in the octadecanethiol SAMs was the main contribution of this paper, which coincided with the former conjecture very well.

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  • 收稿日期:  2002-05-08
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