Photocatalytic C-H Bonds Activation:Ambient Carbonylation of Cyclohexane by Co (acac)2 Under Ultraviolet Irradiation

Da Bin GAO Jing Mei YIN Ming GUO Yuan YU Yong An MA

引用本文: Da Bin GAO,  Jing Mei YIN,  Ming GUO,  Yuan YU,  Yong An MA. Photocatalytic C-H Bonds Activation:Ambient Carbonylation of Cyclohexane by Co (acac)2 Under Ultraviolet Irradiation[J]. Chinese Chemical Letters, 1997, 8(9): 763-764. shu
Citation:  Da Bin GAO,  Jing Mei YIN,  Ming GUO,  Yuan YU,  Yong An MA. Photocatalytic C-H Bonds Activation:Ambient Carbonylation of Cyclohexane by Co (acac)2 Under Ultraviolet Irradiation[J]. Chinese Chemical Letters, 1997, 8(9): 763-764. shu

Photocatalytic C-H Bonds Activation:Ambient Carbonylation of Cyclohexane by Co (acac)2 Under Ultraviolet Irradiation

  • 基金项目:

    The authors are indebted to the Natural Sciences & Technology Foundation Council of Liaoning Province, and Carbon Resource Open Laboratory Foundation of Dalian University of Technology, for the generous financial support.

摘要: A high turnover number was achieved in the photocatalytic carbonylation of C-H bonds of cyclohexane catalyzed by Co (acac)2 under ambient conditions (1 atm,25℃)to give mainly cyclohexanecarboxaldehyde.

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  • 收稿日期:  1997-04-28
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