引用本文:
赵毅莎, 黄洁, 宋纪蓉, 何建云, 马聪, 徐抗震. N-(2,4-二氯苯基)-N'-(苯甲酰基)硫脲脱硫物合铜(Ⅱ)配合物的合成与晶体结构[J]. 应用化学,
2013, 30(8): 897-902.
doi:
10.3724/SP.J.1095.2013.20456
Citation: ZHAO Yisha, HUANG Jie, SONG Jirong, HE Jianyun, MA Cong, XU Kangzhen. Preparation and Crystal Structure of a New Cu(Ⅱ) Complex Derived from the Desulfurization of N-(2,4-Dichlorophenyl)-N'-(benzoyl)-thiourea[J]. Chinese Journal of Applied Chemistry, 2013, 30(8): 897-902. doi: 10.3724/SP.J.1095.2013.20456
Citation: ZHAO Yisha, HUANG Jie, SONG Jirong, HE Jianyun, MA Cong, XU Kangzhen. Preparation and Crystal Structure of a New Cu(Ⅱ) Complex Derived from the Desulfurization of N-(2,4-Dichlorophenyl)-N'-(benzoyl)-thiourea[J]. Chinese Journal of Applied Chemistry, 2013, 30(8): 897-902. doi: 10.3724/SP.J.1095.2013.20456
N-(2,4-二氯苯基)-N'-(苯甲酰基)硫脲脱硫物合铜(Ⅱ)配合物的合成与晶体结构
摘要:
在甲醇中由N-(2,4-二氯苯基)-N'-(苯甲酰基)硫脲(H2met)和CuCl2回流,合成了脱H2S的CuL2(HL=N-(苯甲酰基)-O-甲基-N'-(2,4-二氯苯基)假硫脲),其中HL由H2met脱硫得到。在室温条件下,采用缓慢挥发溶剂法培养出适合用于X射线衍射测试的单晶。由X单晶衍射确定了其晶体和分子结构,在配合物分子中,Cu(Ⅱ)与2个配体分子(HL)的N原子和2个羰基O原子发生配位,形成了2个六元螯合环[N(1A)-Cu-N(1)的键角为180.0°,O(1A)-Cu(1)-O(1)的键角为180.0°]组成的配合物。
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关键词:
- N-(二氯苯基)-N'-(苯甲酰基)硫脲
- / Cu(Ⅱ)配合物
- / 晶体结构
English
Preparation and Crystal Structure of a New Cu(Ⅱ) Complex Derived from the Desulfurization of N-(2,4-Dichlorophenyl)-N'-(benzoyl)-thiourea
Abstract:
In CH3OH the reaction of CuCl2 with N-(2,4-dichlorophenyl)-N'-(benzoyl)-thiourea gave a new copper(Ⅱ) complex,CuL2(HL=N-benzoyl-N'-(2,4-dichlorophenyl)-O-methyl-isourea),which was derived from the desulfurated hydrogen of N-(2,4-dichlorophenyl)-N'-(benzoyl)-thiourea(H2met). Single crystal was obtained by slowly evaporating solvent at the room temperature,and the molecule structure was determined with X-ray diffractions. The copper(Ⅱ) ion is coordinated by two N atoms and two carbonyl O atoms of two ligand molecules and forms a complex with two six-membered chelate rings[N(1A)-Cu-N(1)=180.0°,O(1A)-Cu(1)-O(1)=180.0°].
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