引用本文:
Yao Yu WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO, Zhong Yuan ZHOU. Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol[J]. Chinese Chemical Letters,
1998, 9(11): 1069-1072.
Citation: Yao Yu WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO, Zhong Yuan ZHOU. Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol[J]. Chinese Chemical Letters, 1998, 9(11): 1069-1072.
Citation: Yao Yu WANG, Qian SHI, Qi Zhen SHI, Yi Ci GAO, Zhong Yuan ZHOU. Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol[J]. Chinese Chemical Letters, 1998, 9(11): 1069-1072.
Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol
摘要:
Copper (Ⅱ) α-methacrylate reacts with triphenylphosphine to form mixed-valence copper (Ⅰ,Ⅱ) complex Cu4 (CH2=C(CH3)COO)6 (PPh3)4 (CH3OH)2 in methanol solution. The crystal and molecular structure of the complex has been determined by single crystal X-ray structural analysis. This material forms pale green crystals with triclinic symmetry, space group Pi, a=1.3567(2) nm, b=1.3946(3)nm, c=1.4569(3)nm, α=66.069(14)°,β=84.234(14)°, γ=69.975 (13)°, R=0.0536.
English
Synthesis and Crystul Structure of A New Mixed-Valence Complex of Copper (Ⅰ, Ⅱ) α-Methacrylate with Triphenylphosphine and Methanol
Abstract:
Copper (Ⅱ) α-methacrylate reacts with triphenylphosphine to form mixed-valence copper (Ⅰ,Ⅱ) complex Cu4 (CH2=C(CH3)COO)6 (PPh3)4 (CH3OH)2 in methanol solution. The crystal and molecular structure of the complex has been determined by single crystal X-ray structural analysis. This material forms pale green crystals with triclinic symmetry, space group Pi, a=1.3567(2) nm, b=1.3946(3)nm, c=1.4569(3)nm, α=66.069(14)°,β=84.234(14)°, γ=69.975 (13)°, R=0.0536.
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Key words:
- mixed-valence complex
- / synthesis
- / crystal structure
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