大气压辉光放电结合圆柱约束增强激光诱导击穿光谱应用于土壤中稀土元素的检测

引用本文: 李悦, 张国霞, 蔡朝晴, 邱汉迅, 汪正. 大气压辉光放电结合圆柱约束增强激光诱导击穿光谱应用于土壤中稀土元素的检测[J]. 分析化学, 2022, 50(9): 1384-1390. doi: 10.19756/j.issn.0253-3820.221100 shu

Citation: LI Yue, ZHANG Guo-Xia, CAI Zhao-Qing, QIU Han-Xun, WANG Zheng. Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil[J]. Chinese Journal of Analytical Chemistry, 2022, 50(9): 1384-1390. doi: 10.19756/j.issn.0253-3820.221100 shu

大气压辉光放电结合圆柱约束增强激光诱导击穿光谱应用于土壤中稀土元素的检测

李悦 ^1,2, ,
张国霞 ^2, ,
蔡朝晴 ^2,3, ,
邱汉迅 ^{1,
,} ,
汪正 ^{2,3,
,}

1.
上海理工大学材料与化学学院, 上海 200093;
2.
中国科学院上海硅酸盐研究所, 上海 201899;
3.
中国科学院大学材料科学与光电工程中心, 北京 100049

通讯作者: 邱汉迅,E-mail:hxqiu@usst.edu.cn; 汪正,E-mail:wangzheng@mail.sic.ac.cn

基金项目:
国家自然科学基金项目（No.E27GJ616）、中国科学院仪器设备功能开发技术创新项目（No.E07YQ7170G）和上海市无机材料测试与表征技术平台项目（No.19DZ2290700）资助。

摘要: 土壤中的稀土污染会影响植物生长并通过食物链在动物和人类体内富集,引发环境问题,危害人类健康,因此有必要对土壤中稀土元素的含量进行检测。激光诱导击穿光谱(Laser-induced breakdown spectroscopy,LIBS)在土壤等固体样品分析方面具有原位、无损、实时及多元素同步分析等优势,但该技术的检测灵敏度无法满足痕量元素定量分析的要求。本研究采用大气压辉光放电(Atmospheric pressure glow discharge,APGD)和圆柱约束(Cylindrical confinement,CC)相结合的方法,提高LIBS的检测灵敏度,并将其应用于土壤中稀土元素(Y、La、Eu、Yb和Lu)的检测。结果表明,APGD和CC将LIBS对Y、La、Eu、Yb和Lu元素的检测灵敏度分别提升了11.6、9.3、7.9、8.2和7.6倍。将所构建系统应用于土壤标准物质和未知土壤样品的分析,测得标准样品及未知土壤样品中Y、La、Eu、Yb和Lu元素的含量与ICP-OES测量值的相对误差分别为1.5%~8.6%和1.8%~7.0%,表明所构建系统具有良好的准确度。

关键词:

English

Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil

1.
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China;
2.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China;
3.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: QIU Han-Xun, ; WANG Zheng,

Received Date: 25 February 2022
Revised Date: 26 May 2022
Fund Project:
Supported by the National Natural Science Foundation of China (No.E27GJ616), the Technical Innovation Project of Instrument and Equipment Function Development of Chinese Academy of Sciences (No. E07YQ7170G) and the Shanghai Technical Platform for Testing and Characterization on Inorganic Materials (No.19DZ2290700).

Abstract: Rare earth pollution in soil affects plant growth and accumulates in animals and humans through the food chain, and causes serious environmental and human health issues. To take effective measures to control the rare earth pollution, it is necessary to detect the content of rare earth elements in soil. Laser-induced breakdown spectroscopy (LIBS) has many advantages including in-situ, non-destructive, real-time and multi-element simultaneous analysis for solid samples such as soil. However, the sensitivity of this technique is low, which limits its application in the quantitative analysis of trace elements. In this work, a new method utilizing the combination of atmospheric pressure glow discharge (APGD) and cylindrical confinement (CC) was proposed to improve the detection sensitivity of laser-induced breakdown spectroscopy, which was applied to determination of Y, La, Eu, Yb and Lu rare earth elements in soil. The results showed that the detection sensitivity of LIBS for Y, La, Eu, Yb and Lu were enhanced by 11.6, 9.3, 7.9, 8.2 and 7.6 times by APGD and CC, respectively. To verify the accuracy of the proposed system, it was applied to the detection of soil certified reference materials and an unknown soil sample, and the relative errors between the detection values of this work and those of ICP-OES were 1.5%-8.6% and 1.8%-7.0%, respectively.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

大气压辉光放电结合圆柱约束增强激光诱导击穿光谱应用于土壤中稀土元素的检测

通讯作者: 邱汉迅,E-mail:hxqiu@usst.edu.cn; 汪正,E-mail:wangzheng@mail.sic.ac.cn

English

Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil

Corresponding author: QIU Han-Xun, ; WANG Zheng,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

大气压辉光放电结合圆柱约束增强激光诱导击穿光谱应用于土壤中稀土元素的检测

通讯作者: 邱汉迅,E-mail:hxqiu@usst.edu.cn; 汪正,E-mail:wangzheng@mail.sic.ac.cn

English

Atmospheric Pressure Glow Discharge Combined with Cylindrical Confinement Enhanced Laser-Induced Breakdown Spectroscopy for Determination of Rare Earth in Soil

Corresponding author: QIU Han-Xun, ; WANG Zheng,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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