An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from α-Santonin

Wu Jiong XIA De Run LI Yong Qiang TU Ao Cheng CAO

引用本文: Wu Jiong XIA,  De Run LI,  Yong Qiang TU,  Ao Cheng CAO. An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from α-Santonin[J]. Chinese Chemical Letters, 2001, 12(1): 21-24. shu
Citation:  Wu Jiong XIA,  De Run LI,  Yong Qiang TU,  Ao Cheng CAO. An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from α-Santonin[J]. Chinese Chemical Letters, 2001, 12(1): 21-24. shu

An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from α-Santonin

  • 基金项目:

    We are grateful for financial support from the National Natural Science Foundation of China (NO.29972019)

    Educational Council Foundation (No.99208) and Excellent Young Teacher Foundation.

摘要: A short and efficient procedure for introduction of tertiary hydroxyl to C-11 of eudesmanolide based on the rearrangement-oxidation of the exocylic double bond has been developed, which is synthetically valuable for a series of natural eudesmanolide sesquiterpenoids containing the 11,12-diol.

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  • 发布日期:  2001-02-01
  • 收稿日期:  2000-06-05
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