引用本文:
Yuan Yong YAN, Huan Pei ZUO, Zi Lin JIN. AQUEOUS PHASE RHODIUM HYDROFORMYLATION OF DODECENE-1 WITH SURFACE ACTIVE WATER-SOLUBLE PHOSPHINE[J]. Chinese Chemical Letters,
1996, 7(4): 377-380.
Citation: Yuan Yong YAN, Huan Pei ZUO, Zi Lin JIN. AQUEOUS PHASE RHODIUM HYDROFORMYLATION OF DODECENE-1 WITH SURFACE ACTIVE WATER-SOLUBLE PHOSPHINE[J]. Chinese Chemical Letters, 1996, 7(4): 377-380.
Citation: Yuan Yong YAN, Huan Pei ZUO, Zi Lin JIN. AQUEOUS PHASE RHODIUM HYDROFORMYLATION OF DODECENE-1 WITH SURFACE ACTIVE WATER-SOLUBLE PHOSPHINE[J]. Chinese Chemical Letters, 1996, 7(4): 377-380.
AQUEOUS PHASE RHODIUM HYDROFORMYLATION OF DODECENE-1 WITH SURFACE ACTIVE WATER-SOLUBLE PHOSPHINE
摘要:
The surface active water-soluble phosphine,P[p-C6H4O(CH2CH2O)nH]3,n=4,is used to generate an aqueous rhodium catalyst for the hydroformylation of dodecene-1.Under 100℃,5.0 MPa (CO/H2=1:1),pH=6.5,and reaction time 4h,the conversion of dodecene-1 was 96.0%,the yield for aldehyde was 84.0%,and n/i=1.8.The catalyst can be reused for more than four times without any appreciable loss in activity and selectivity.
English
AQUEOUS PHASE RHODIUM HYDROFORMYLATION OF DODECENE-1 WITH SURFACE ACTIVE WATER-SOLUBLE PHOSPHINE
Abstract:
The surface active water-soluble phosphine,P[p-C6H4O(CH2CH2O)nH]3,n=4,is used to generate an aqueous rhodium catalyst for the hydroformylation of dodecene-1.Under 100℃,5.0 MPa (CO/H2=1:1),pH=6.5,and reaction time 4h,the conversion of dodecene-1 was 96.0%,the yield for aldehyde was 84.0%,and n/i=1.8.The catalyst can be reused for more than four times without any appreciable loss in activity and selectivity.
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