引用本文:
Jian Min DOU, Ying LIU, Lan Ying ZHU, De Zhi SUN, Pei Ju ZHENGZ, Chen Xia DU, Yu ZHU. Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]2[Pd(SCN)4][J]. Chinese Chemical Letters,
2000, 11(5): 463-466.
Citation: Jian Min DOU, Ying LIU, Lan Ying ZHU, De Zhi SUN, Pei Ju ZHENGZ, Chen Xia DU, Yu ZHU. Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]2[Pd(SCN)4][J]. Chinese Chemical Letters, 2000, 11(5): 463-466.
Citation: Jian Min DOU, Ying LIU, Lan Ying ZHU, De Zhi SUN, Pei Ju ZHENGZ, Chen Xia DU, Yu ZHU. Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]2[Pd(SCN)4][J]. Chinese Chemical Letters, 2000, 11(5): 463-466.
Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]2[Pd(SCN)4]
摘要:
A novel Pd(Ⅱ)-dibenzo-18-crown-6 (DB18C6) complex[K(DB18C6)]2[Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi-one-dimensional infinite chain of two[K(DB18C6)]+ complex cations and a[Pd(SCN)4]2- anion bridged by K+-π interactions between adjacent[K(DB18C6)]+ units.
English
Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex:[K(DB18C6)]2[Pd(SCN)4]
Abstract:
A novel Pd(Ⅱ)-dibenzo-18-crown-6 (DB18C6) complex[K(DB18C6)]2[Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi-one-dimensional infinite chain of two[K(DB18C6)]+ complex cations and a[Pd(SCN)4]2- anion bridged by K+-π interactions between adjacent[K(DB18C6)]+ units.
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Key words:
- Cation-π interactions
- / crown ether
- / crystal structure
- / palladium complex
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