Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Citation: Rong Liang, Yi-chun Chen, Chun-qiu Zhang, Jing Yin, Xue-lei Liu, Lu-kai Wang, Rui Kong, Xin Feng, Jin-jun Yang. Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate[J]. Chinese Journal of Polymer Science, 2017, 35(4): 558-568. doi: 10.1007/s10118-017-1917-6 shu

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

通讯作者: , tjyjj_2014@tjut.edu.cn

English

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

a.
School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China
b.
School of Mechanical Engineering, Tianjin University of Technology, Tianjin 300384, China
^† These authors contributed equally to this work.

Corresponding author: Jin-jun Yang, tjyjj_2014@tjut.edu.cn

Received Date: 03 September 2016
Accepted Date: 11 October 2016
Revised Date: 09 October 2016
Available Online: 01 April 2017
Fund Project:

Abstract: Zinc phenylphosphonate (PPZn), a benign and biocompatible nucleating agent, was prepared and incorporated into the biodegradable poly (ethylene adipate) (PEA) to investigate its effect on the crystallization behavior, crystallization kinetics and spherulite morphology of PEA. Upon addition of PPZn, the crystallization temperature and crystallinity of PEA in the non-isothermal crystallization process increased significantly. Analysis of crystallization kinetics by Avrami equation suggests that the crystallization time shortened greatly and crystallization rate increased markedly after addition of PPZn. In the presence of PPZn, the spherulite size decreased and spherulite density increased significantly. It suggests that PPZn is an efficient nucleating agent for the crystallization of PEA. The accelerated crystallization in the presence of PPZn is mainly attributed to the epitaxial nucleation of PEA crystals on the surface of PPZn crystals, that is, a perfect lattice matching between PEA crystal and PPZn crystal occurs.

Key words:

1. [1]
  Yang, J., Pan, P., Dong, T. and Inoue, Y., Polymer, 2010, 51:807 doi: 10.1016/j.polymer.2009.11.065
2. [2]
  Pan, P. and Inoue, Y., Prog. Polym. Sci., 2009, 34:605 doi: 10.1016/j.progpolymsci.2009.01.003
3. [3]
  Han, Y., Um, J., Im, S. and Kim, B., J. Polym. Sci., Part A:Polym. Chem., 2001, 39:2143 doi: 10.1002/(ISSN)1099-0518
4. [4]
  Siriphannon, P. and Monvisade, P., J. Biomater. Sci. Polymer Ed., 2008, 19:925 doi: 10.1163/156856208784613569
5. [5]
  Fuller, C.S. and Erickson, C.L., J. Am. Chem. Soc., 1937, 59:344 doi: 10.1021/ja01281a037
6. [6]
  Fuller, C.S. and Frosch, C.J., J. Phys. Chem., 1939, 43:323 doi: 10.1021/j150390a005
7. [7]
  Fuller, C.S., Chem. Rev., 1940, 26; 143
8. [8]
  Turner-Jones, A. and Bunn, C.W., Acta Crystallogr., 1962, 15:105 doi: 10.1107/S0365110X62000316
9. [9]
  Hobbs, S.Y. and Billmeyer, F.W., J. Polym. Sci. Part A-2, Polym. Phys., 1969, 7:1119 doi: 10.1002/pol.1969.160070613
10. [10]
  Teitel'Baum, B.Y., Palikhov, N.A., Maklakov, L.I., Anoshina, N.P., Murtazina, I.O. and Kovalenko, V.I., Polym. Sci. USSR, 1967, 9:1880 doi: 10.1016/0032-3950(67)90435-2
11. [11]
  Popescu, M.C. and Vasile, C., Spectrochim. Acta A, 2011, 79:45 doi: 10.1016/j.saa.2011.01.042
12. [12]
  Takayanagi, M. and Yamashita, T., J. Polym. Sci., 1956, 22:552 doi: 10.1002/pol.1956.1202210223
13. [13]
  Keith, H.D. and Padden, F.J., J. Polym. Sci., 1959, 39:123 doi: 10.1002/pol.1959.1203913510
14. [14]
  Murayama, E., Polym. Preprints JPN., 2002, 51:460 https://www.mysciencework.com/publication/show/1c0217af70c962ae58d083f6379f89a9
15. [15]
  Wang, T., Wang, H., Li, H., Gan, Z. and Yan, S., Phys. Chem. Chem. Phys., 2009, 11:1619 doi: 10.1039/b817597g
16. [16]
  Meyer, A., Yen, K.C., Li, S.H., Förster, S. and Woo, E.M., Ind. Eng. Chem. Res., 2010, 49:12084 doi: 10.1021/ie901356q
17. [17]
  Li, Y., Huang, H., He, T. and Wang, Z., ACS Macro Lett., 2011, 1:154 doi: 10.1021/mz2000785?journalCode=amlccd
18. [18]
  Woo, E.M., Wang, L.Y. and Nurkhamidah, S., Macromolecules, 2012, 45:1375 doi: 10.1021/ma202222e
19. [19]
  Lugito, G. and Woo, E.M., Colloid Polym. Sci., 2013, 291:817 doi: 10.1007/s00396-012-2793-9
20. [20]
  Li, Y., Huang, H., Wang, Z. and He, T., Macromolecules, 2014, 47:1783 doi: 10.1021/ma402579d
21. [21]
  Lugito, G. and Woo, E.M., Cryst. Growth Des., 2014, 14:4929 doi: 10.1021/cg5002539
22. [22]
  Lugito, G. and Woo, E.M., Soft Matter, 2015, 11:908 doi: 10.1039/C4SM02489C
23. [23]
  Hobbs, S.Y. and Billmeyer, F.W., J. Polym. Sci. Part A-2, Polym. Phys., 1970, 8:1387 doi: 10.1002/pol.1970.160080810
24. [24]
  Hobbs, S.Y. and Billmeyer, F.W., J. Polym. Sci. Part A-2, Polym. Phys., 1970, 8:1395 doi: 10.1002/pol.1970.160080811
25. [25]
  Privalko, V.P., Polym. Sci. USSR, 1972, 14:1381 doi: 10.1016/0032-3950(72)90113-X
26. [26]
  Varma-Nair, M., Pan, R. and Wunderlich, B., J. Polym. Sci., Part B:Polym. Phys., 1991, 29:1107 doi: 10.1002/polb.1991.090290909
27. [27]
  Woo, E.M., Wu, P.L., Wu, M.C. and Yan, K.C., Macromol. Chem. Phys., 2006, 207:2232 doi: 10.1002/(ISSN)1521-3935
28. [28]
  Zorba, T., Chrissafis, K., Paraskevopoulos, K.M. and Bikiaris, D.N., Polym. Degrad. Stab., 2007, 92:22 http://www.sciencedirect.com/science/article/pii/S0141391007000444
29. [29]
  Yang, J., Pan, P., Dong, T., Hua, L. and Inoue, Y., Macromolecules, 2010, 3:8610 doi: 10.1021/ma1000546
30. [30]
  Yang, J., Pan, P., Hua, L., Xie, Y., Dong, T., Zhu, B., Inoue, Y. and Feng, X., Polymer, 2011, 52:3460 doi: 10.1016/j.polymer.2011.05.041
31. [31]
  Yang, J., Pan, P., Hua, L., Feng, X., Yue, J., Ge, Y. and Inoue, Y., J. Phys. Chem. B, 2012, 116:1265 doi: 10.1021/jp209626x
32. [32]
  Haponiuk, J.T. and Foks, J., J. Therm. Anal. Calori., 1990, 36:2253 doi: 10.1007/BF01914163
33. [33]
  Foks, J. and Luszczek, M., J. Cryst. Growth, 1993, 134:347 doi: 10.1016/0022-0248(93)90145-M
34. [34]
  Foks, J., Haponiuk, J.T. and Luszczek, M., J. Therm. Anal. Calori., 1995, 43:309 doi: 10.1007/BF02635999
35. [35]
  Nakafuku, C., Polym. J., 1998, 30:761 doi: 10.1295/polymj.30.761
36. [36]
  Wu, H. and Qiu, Z., Ind. Eng. Chem. Res., 2012, 51:13323 doi: 10.1021/ie301968f
37. [37]
  Yan, C.Z., Guo, L., Chang, H.B. and Yan, S.K., Chinese J. Polym. Sci., 2013, 31:1173 doi: 10.1007/s10118-013-1292-x
38. [38]
  Wang, H.J., Feng, H.P., Wang, X.C., Du, Q.C. and Yan, C., Chinese J. Polym. Sci., 2015, 33:823 doi: 10.1007/s10118-015-1627-x
39. [39]
  Jiang, Z. and Qiu, Z., RSC Adv., 2015, 5:55486 doi: 10.1039/C5RA10332K
40. [40]
  Sun, L.Y., Boo, W.J., Sun, D., Clearfield, A. and Sue, H.J., Chem. Mater., 2007, 19:1749 doi: 10.1021/cm062993r
41. [41]
  Boo, W.J., Sun, L.Y., Liu, J., Clearfield, A., Sue, H.J., Mullins, M.J. and Pham, H., Compos. Sci. Technol., 2007, 67:262 doi: 10.1016/j.compscitech.2006.08.012
42. [42]
  Zhang, R., Hu, Y., Li, B., Chen, Z. and Fan, W., J. Mater. Sci., 2007, 42:5641 doi: 10.1007/s10853-006-0629-z
43. [43]
  Brandao, L.S., Mendes, L.C., Medeiros, M.E., Sirelli, L. and Dias, M.L., J. Appl. Polym. Sci., 2006, 102:3868 doi: 10.1002/(ISSN)1097-4628
44. [44]
  Wright, P.A., Jones, R.H., Natarajan, S., Bell, R.G., Chen, J., Hursthouse, M.B. and Thomas, J.M., J. Chem. Soc. Chem. Commun., 1993, 7:633 http://pubs.rsc.org/EN/content/articlelanding/1993/c3/c39930000633#!divAbstract
45. [45]
  Jaber, M., Larlus, O. and Miehe-Brendlé, J., Solid State Sci., 2007, 9:144 doi: 10.1016/j.solidstatesciences.2006.11.007
46. [46]
  Zhang, B. and Clearfield, A., J. Am. Chem. Soc., 1997, 119:2751 doi: 10.1021/ja9634583
47. [47]
  Alberti, G., Costantino, Y., Marmottini, F., Vivani, R. and Zappelli, P., Angew. Chem. Int. Ed. En., 1993, 32:1357 doi: 10.1002/(ISSN)1521-3773
48. [48]
  Dorozhkin, S.V. and Epple, M., Angew. Chem. Int. Ed., 2002, 41:3130 doi: 10.1002/1521-3773(20020902)41:17<>1.0.CO;2-C
49. [49]
  Bujoli, B., Lane, S.M., Nonglaton, G., Pipelier, M., Léger, J., Talham, D.R. and Tellier, C., Chem-Eur. J., 2005, 11:1980 doi: 10.1002/chem.200400960
50. [50]
  Herschke, L., Lieberwirth, I. and Wegner, G., J. Mater. Sci. Mater. Med., 2006, 17:95 doi: 10.1007/s10856-006-6333-3
51. [51]
  Pan, P., Liang, Z., Cao, A. and Inoue, Y., ACS Appl. Mater. Inter., 2009, 1:402 doi: 10.1021/am800106f
52. [52]
  Chen, Y., Wang, S., Chen, Q., Xi, Z., Wang, C., Chen, X., Feng, X., Liang, R. and Yang, J., Eur. Polym. J., 2015, 72:222 doi: 10.1016/j.eurpolymj.2015.09.020
53. [53]
  Cao, G., Lee, H., Lynch, V.M. and Mallouk, T.E., Inorg. Chem., 1988, 27:2781 doi: 10.1021/ic00289a008
54. [54]
  Frink, K.J., Wang, R.C., Colón, J.L. and Clearfield, A., Inorg. Chem., 1991, 30:1438 doi: 10.1021/ic00007a004
55. [55]
  Gedde, U.W., "Polymer physics", Chapman & Hall, London, 1995
56. [56]
  Pan, P., Liang, Z., Nakamura, N., Miyagawa, T. and Inoue, Y., Macromol. Biosci., 2009, 9:585 doi: 10.1002/mabi.v9:6
57. [57]
  Yang, J., Chen, Y., Qin, S., Liu, J., Bi, C., Liang, R., Dong, T. and Feng, Xin., Ind. Eng. Chem. Res., 2015, 54:8048 doi: 10.1021/acs.iecr.5b02150
58. [58]
  Yang, J., Chen, Y., Hua, L., Liang, R. and Zhu, D., J. Appl. Polym. Sci., 2016, 133:42957 doi: 10.1002/app.42957/full
59. [59]
  Jia, J., Yang, J., Zhao, Y., Liang, H. and Chen, M., RSC Adv., 2016, 6:43855 doi: 10.1039/C6RA05514A
60. [60]
  Legras, R., Mercier, J.P. and Nield, E., Nature, 1983, 304:432 doi: 10.1038/304432a0
61. [61]
  Libster, D., Aserin, A. and Garti, N., Polym. Adv. Technol., 2007, 18:685 doi: 10.1002/pat.v18:9
62. [62]
  Sun, Y., Li, H., Huang, Y., Chen, E., Zhao, L., Gan, Z. and Yan, S., Macromolecules, 2005, 38:2739 doi: 10.1021/ma0474269
63. [63]
  Sun, Y., Li, H., Huang, Y., Chen, E., Gan, Z. and Yan, S., Polymer, 2006, 47:2455 doi: 10.1016/j.polymer.2006.02.002
64. [64]
  Mathieu, C., Thierry, A., Wittmann, J.C. and Lotz, B., J. Polym. Sci., Part B:Polym. Phys., 2002, 40:2504 doi: 10.1002/(ISSN)1099-0488
65. [65]
  Haubruge, H.G., Daussin, R., Jonas, A.M., Legras, R., Wittmann, J.C. and Lotz, B., Macromolecules, 2003, 36:4452 doi: 10.1021/ma0341723

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 946
HTML全文浏览量: 5

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

通讯作者: , tjyjj_2014@tjut.edu.cn

English

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Corresponding author: Jin-jun Yang, tjyjj_2014@tjut.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

通讯作者: , tjyjj_2014@tjut.edu.cn

English

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Corresponding author: Jin-jun Yang, tjyjj_2014@tjut.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs