引用本文:
Zhen Guang LIN, Hua Yang CHEN, Yu Juan LIN, Feng Hua HUANG. The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE2B4［36］ENE-O6N8·2THF[J]. Chinese Chemical Letters,
1996, 7(10): 884-885.
Citation: Zhen Guang LIN, Hua Yang CHEN, Yu Juan LIN, Feng Hua HUANG. The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE2B4［36］ENE-O6N8·2THF[J]. Chinese Chemical Letters, 1996, 7(10): 884-885.
Citation: Zhen Guang LIN, Hua Yang CHEN, Yu Juan LIN, Feng Hua HUANG. The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE2B4［36］ENE-O6N8·2THF[J]. Chinese Chemical Letters, 1996, 7(10): 884-885.
The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE2B4［36］ENE-O6N8·2THF
摘要:
New Schiff base Macrocyclic compound of 2, 3:11, 12:20, 21:29, 30-tetrabenzo-l, 13, 16, 19, 31, 34-hexaoxa-5, 6, 8, 9, 23, 24, 26, 27-octaaza-7, 25-dithione-2, 3:4, 5:9, 10:11, 12:22, 23:27, 28:29, 30-cyclo-[36]ene (thione2B4[36]ene-O6N8) containing THF has been prepared.It crystallizes in the monoclinic, space group P21/n, with parameters a=9.829(5)Å, b=24.23(1)Å, c=10.181(9)Å, β =92.93(5)°, Z=2, V=2422(3)Å3, Dc=1.25gcm-3.Data collection:Rigaku AFC-5R diffractometer, (MoKα, λ =0.71069Å), ω/2θ scans, θmax=25°, empirical absorption correction, 4658 measured reflections, 4387 independent, 1743 observed reflections [I≥ 3σ(I)].The final R=0.056, RW=0.069, S=1.54, (△/σ)max=0.01, △ρmax=0.36eÅ-3.
English
The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE2B4［36］ENE-O6N8·2THF
Abstract:
New Schiff base Macrocyclic compound of 2, 3:11, 12:20, 21:29, 30-tetrabenzo-l, 13, 16, 19, 31, 34-hexaoxa-5, 6, 8, 9, 23, 24, 26, 27-octaaza-7, 25-dithione-2, 3:4, 5:9, 10:11, 12:22, 23:27, 28:29, 30-cyclo-[36]ene (thione2B4[36]ene-O6N8) containing THF has been prepared.It crystallizes in the monoclinic, space group P21/n, with parameters a=9.829(5)Å, b=24.23(1)Å, c=10.181(9)Å, β =92.93(5)°, Z=2, V=2422(3)Å3, Dc=1.25gcm-3.Data collection:Rigaku AFC-5R diffractometer, (MoKα, λ =0.71069Å), ω/2θ scans, θmax=25°, empirical absorption correction, 4658 measured reflections, 4387 independent, 1743 observed reflections [I≥ 3σ(I)].The final R=0.056, RW=0.069, S=1.54, (△/σ)max=0.01, △ρmax=0.36eÅ-3.
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