引用本文:
Jing Jiang LIU, Lian De LU. THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule[J]. Chinese Chemical Letters,
1990, 1(1): 9-12.
Citation: Jing Jiang LIU, Lian De LU. THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule[J]. Chinese Chemical Letters, 1990, 1(1): 9-12.
Citation: Jing Jiang LIU, Lian De LU. THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule[J]. Chinese Chemical Letters, 1990, 1(1): 9-12.
THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule
摘要:
The electrostatic potential of carbene and nitrene, have been calculated by ABINITIO method with 6-31G** basis set, there are positive potential regions in the directionsof vacant P orbitals, and negative regions in the directions of lone-pair electrons.Therefore, atoms in these molecules have different electric properties in differentdirections.The idea of electrophilic and nucleophilic directions of an atom in moleculesshould be introduced.
English
THE ELECTRIC PROPERTY OF SINGLET CARBENE AND ITS ISOELECTRONIC SYSTEM--Electrophilic and Nucleophilic Directions of an Atom in the Molecule
Abstract:
The electrostatic potential of carbene and nitrene, have been calculated by ABINITIO method with 6-31G** basis set, there are positive potential regions in the directionsof vacant P orbitals, and negative regions in the directions of lone-pair electrons.Therefore, atoms in these molecules have different electric properties in differentdirections.The idea of electrophilic and nucleophilic directions of an atom in moleculesshould be introduced.
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