二硫化钼-碳复合材料用作钠离子电容电池负极材料

引用本文: 赵立平, 孟未帅, 王宏宇, 齐力. 二硫化钼-碳复合材料用作钠离子电容电池负极材料[J]. 物理化学学报, 2017, 33(4): 787-794. doi: 10.3866/PKU.WHXB201612152 shu

Citation: ZHAO Li-Ping, MENG Wei-Shuai, WANG Hong-Yu, QI Li. MoS₂-C Composite as Negative Electrode Material for Sodium-Ion Supercapattery[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 787-794. doi: 10.3866/PKU.WHXB201612152 shu

二硫化钼-碳复合材料用作钠离子电容电池负极材料

1.
辽宁石油化工大学化学化工与环境学部, 辽宁抚顺 113001;
2.
中国科学院长春应用化学研究所, 电分析国家重点实验室, 长春 130022;
3.
东北师范大学化学学院, 长春 130024
基金项目:
国家自然科学基金（21571173）及辽宁石油化工大学引进人才科研启动基金资助项目（2016XJJ-020）

摘要: 采用水热方法合成了二硫化钼-碳复合材料（MoS₂-C）。使用X射线衍射，扫描电子显微镜，透射电子显微镜，氮气吸-脱附和热重分析等手段对材料进行了物性表征。研究了MoS₂-C储钠机理，将其用作有机系钠离子电容电池负极材料，组装了MoS₂-C/AC电容电池，研究了电容电池的电化学性能。测试结果显示电容电池具有较高比能量和比功率，也表现出了较好的循环稳定性，经1000次循环后容量保持率高达96%。

关键词:

English

MoS₂-C Composite as Negative Electrode Material for Sodium-Ion Supercapattery

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China;
2.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
3.
College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
Received Date: 18 October 2016
Revised Date: 15 December 2016
Available Online: 15 December 2016
Fund Project:
The project was supported by the National Natural Science Foundation of China (21571173) and Talent Scientific Research Fund of Liaoning Shihua University, China (2016XJJ-020).

Abstract: Amolybdenum disulfide-carbon composite (MoS₂-C) was prepared by a hydrothermal method. Xray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and N₂ adsorption-desorption tests were employed to characterize the physical properties of the composite. The charge storage mechanism of the MoS₂-C was also investigated. The MoS₂-C can be used as the negative electrode for supercapatteries using Na+-based organic electrolytes. A supercapattery of MoS₂-C/AC (activated carbon) was constructed and its electrochemical performance was studied. The fabricated supercapattery exhibited relatively high energy density and power density. It also showed high cycle stability, displaying a 96% capacity retention after 1000 cycles.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

二硫化钼-碳复合材料用作钠离子电容电池负极材料

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MoS₂-C Composite as Negative Electrode Material for Sodium-Ion Supercapattery

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