引用本文:
Feng ZHOU, Shu Juan LIU, Bo WANG, Ting Mei WANG, Miao CHEN, Wei Min LIU. Preparation of End Grafted Polyacrylonitrile Brushes through Surface Confined Radical Chain Transfer Reaction[J]. Chinese Chemical Letters,
2003, 14(1): 47-50.
Citation: Feng ZHOU, Shu Juan LIU, Bo WANG, Ting Mei WANG, Miao CHEN, Wei Min LIU. Preparation of End Grafted Polyacrylonitrile Brushes through Surface Confined Radical Chain Transfer Reaction[J]. Chinese Chemical Letters, 2003, 14(1): 47-50.
Citation: Feng ZHOU, Shu Juan LIU, Bo WANG, Ting Mei WANG, Miao CHEN, Wei Min LIU. Preparation of End Grafted Polyacrylonitrile Brushes through Surface Confined Radical Chain Transfer Reaction[J]. Chinese Chemical Letters, 2003, 14(1): 47-50.
Preparation of End Grafted Polyacrylonitrile Brushes through Surface Confined Radical Chain Transfer Reaction
摘要:
End grafted polyacrylonitrile (PAN) brush was prepared through surface initiated polymerization via the chain transfer process. The thiol-terminated monolayer and PAN brushes were characterized by FTIR, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), ellipsometry and contact angle measurements ete. It is demonstrated that radical chain transfer reaction and surface initiated precipitate polymerization can be used to prepare end-grafted polymer brushes.
English
Preparation of End Grafted Polyacrylonitrile Brushes through Surface Confined Radical Chain Transfer Reaction
Abstract:
End grafted polyacrylonitrile (PAN) brush was prepared through surface initiated polymerization via the chain transfer process. The thiol-terminated monolayer and PAN brushes were characterized by FTIR, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), ellipsometry and contact angle measurements ete. It is demonstrated that radical chain transfer reaction and surface initiated precipitate polymerization can be used to prepare end-grafted polymer brushes.
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Key words:
- Surface initiated polymerization
- / chain transfer
- / polymer brush
- / acrylonitrile
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