A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu3SnH and allylic bromides

La Mei Yu Wen Yan Hao Ming Zhong Cai

引用本文: La Mei Yu,  Wen Yan Hao,  Ming Zhong Cai. A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu3SnH and allylic bromides[J]. Chinese Chemical Letters, 2008, 19(9): 1047-1050. doi: 10.1016/j.cclet.2008.06.029 shu
Citation:  La Mei Yu,  Wen Yan Hao,  Ming Zhong Cai. A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu3SnH and allylic bromides[J]. Chinese Chemical Letters, 2008, 19(9): 1047-1050. doi: 10.1016/j.cclet.2008.06.029 shu

A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu3SnH and allylic bromides

  • 基金项目:

    We thank the National Natural Science Foundation of China (No. 20462002) and Natural Science Foundation of Jiangxi Province (No. 2007GZW0172) for financial support.

摘要: 1,4-Dienyl selenides can be stereoselectively synthesized in one pot under mild conditions in good yields by the palladium-catalyzed hydrostannylation of acetylenic selenides, followed by Stille coupling with allylic bromides.

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  • 收稿日期:  2008-03-19
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