白蒿挥发油成分的测定及其抗氧化活性分析

引用本文: 孙志恒, 吕敏兰, 张智嘉, 张迎, 韩晓军. 白蒿挥发油成分的测定及其抗氧化活性分析[J]. 分析化学, 2017, 45(11): 1655-1661. doi: 10.11895/j.issn.0253-3820.170333 shu

Citation: SUN Zhi-Heng, LYU Min-Lan, ZHANG Zhi-Jia, ZHANG Ying, HAN Xiao-Jun. Components and Their Antioxidant Activity of Essential Oil of Herba Artimisiae Sieversianae from Different Growth Periods[J]. Chinese Journal of Analytical Chemistry, 2017, 45(11): 1655-1661. doi: 10.11895/j.issn.0253-3820.170333 shu

白蒿挥发油成分的测定及其抗氧化活性分析

新能源转换与储存关键材料技术工信部重点实验室, 城市水资源与水环境国家重点实验室, 哈尔滨工业大学化工与化学学院, 哈尔滨 150001
基金项目:
本文系国家自然科学基金项目（Nos.21773050，21528501）、城市水资源与水环境国家重点实验室（哈尔滨工业大学）自主课题（No.2017DX05）和哈尔滨工业大学环境生态创新专项基金项目（No.HSCJ201607）资助

摘要: 采用乙醇浸提法提取生长期和花果期白蒿的挥发油，通过正交实验确定最佳提取条件为：提取3次、浸提90 min、对于生长期和花果期白蒿液料比分别为10 mL∶1 g和8 mL∶1 g。通过红外光谱和液相色谱-质谱联用分析了产物的主要成分，生长期白蒿挥发油的主要成分为桉树脑、樟脑、右旋龙脑、石竹烯、Cadina-1，4-diene、白菖烯、棕榈酸乙酯等；花果期白蒿挥发油的主要成分为樟脑、石竹烯、龙脑、甲酸橙花酯等。通过1，1-二苯基-2-三硝基苯肼（DPPH）自由基清除实验对产物的自由基清除活性进行了测定，生长期和花果期白蒿挥发油对0.05 mmol/L DPPH溶液的IC₅₀值分别为0.40和1.66 mg/mL。研究结果表明，乙醇浸提的生长期和花果期白蒿的挥发油具有较好的抗氧化活性。

关键词:

English

Components and Their Antioxidant Activity of Essential Oil of Herba Artimisiae Sieversianae from Different Growth Periods

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
Received Date: 26 May 2017
Revised Date: 26 September 2017
Fund Project:
This work was supported by the National Natural Science Foundation of China (Nos. 21773050, 21528501), State Key Laboratory of Urban Water Resource and Environment (Harbin Institube of Technology)(No. 2017DX05), and HIT Environment and Ecology Innovation Special Funds (No. HSCJ201617).

Abstract: The effective exploitation of natural products is of great significance. Herein the essential oil from Herba Artimisiae Sieversianae in growth period and flower/fruit bearing period was extracted by ethanol extraction method. The optimal extraction condition was determined by orthogonal experiment, including extracting 3 times, soaking for 90 min, and the ratios of liquid to solid for Herba Artimisiae Sieversianae in growth period and flower/fruit bearing period were 10 mL:1 g and 8 mL:1 g, respectively. The main components of the products were confirmed by FT-IR and GC-MS, which were cineole, camphor, d-borneol, caryophyllene, cadina-1, 4-diene, calamenene, ethyl palmitate, etc. in herba artimisiae sieversianae in growth period, and camphor, caryophyllene, borneol, neryl formate, etc. in Herba Artimisiae Sieversianae in flower/fruit bearing period. The radical scavenging activity of the products was determined. The results showed that the IC₅₀ values of the essential oil from Herba Artimisiae Sieversianae in growth period and flower/fruit bearing period for 0.05 mmol/L DPPH solution were 0.40 mg/mL and 1.66 mg/mL, respectively. The essential oil extracted by ethanol from Herba Artimisiae Sieversianae was confirmed to possess good antioxidant activity.

Key words:

Essential oil of Herba Artimisiae Sieversianae
/ Ethanol extraction
/ Radical scavenging activity

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沈阳化工大学材料科学与工程学院沈阳 110142

白蒿挥发油成分的测定及其抗氧化活性分析

English

Components and Their Antioxidant Activity of Essential Oil of Herba Artimisiae Sieversianae from Different Growth Periods

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

白蒿挥发油成分的测定及其抗氧化活性分析

English

Components and Their Antioxidant Activity of Essential Oil of Herba Artimisiae Sieversianae from Different Growth Periods

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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