基于离子液的超声辅助萃取小蓼叶中的精油及真实溶剂似导体屏蔽模型研究（英文）

引用本文: Habib ULLAH, Cecilia D WILFRED, Maizatul S SHAHARUN. 基于离子液的超声辅助萃取小蓼叶中的精油及真实溶剂似导体屏蔽模型研究（英文）[J]. 色谱, 2017, 35(6): 656-664. doi: 10.3724/SP.J.1123.2017.02002 shu

Citation: Habib ULLAH, Cecilia D WILFRED, Maizatul S SHAHARUN. Ionic liquid based ultrasonication-assisted extraction of essential oil from the leaves of Persicaria minor and conductor-like screening model for realistic solvents study[J]. Chinese Journal of Chromatography, 2017, 35(6): 656-664. doi: 10.3724/SP.J.1123.2017.02002 shu

基于离子液的超声辅助萃取小蓼叶中的精油及真实溶剂似导体屏蔽模型研究（英文）

1.
Center of Research in Ionic Liquids Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia;
2.
Fundamental and Applied Science Department, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia

摘要: Ionic liquids (ILs) based ultrasonic-assisted extract has been applied for the extraction of essential oil from Persicaria minor leaves. The effects of temperature, sonication time, and particle size of the plant material on the yield of essential oil were investigated. Among the different ILs employed, 1-ethyl-3-methylimidazolium acetate was the most effective, providing a 9.55% yield of the essential oil under optimum conditions (70 ℃, 25 min, IL:hexane ratio of 7:10 (v/v), particle size 60-80 mesh). The performance of 1-ethyl-3-methylimidazolium acetate in the extraction was attributed to its low viscosity and ability to disintegrate the structural matrix of the plant material. The ability of 1-ethyl-3-methylimidazolium acetate was also confirmed using the conductor like-screening model for realistic solvents. This research proves that ILs can be used to extract essential oils from lignocellulosic biomass.

关键词:

gas chromatography mass spectrometry (GC-MS)
/ ionic liquid (IL)
/ ultrasonication
/ optimization
/ Persicaria minor
/ essential oil

English

Ionic liquid based ultrasonication-assisted extraction of essential oil from the leaves of Persicaria minor and conductor-like screening model for realistic solvents study

1.
Center of Research in Ionic Liquids Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia;
2.
Fundamental and Applied Science Department, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Received Date: 01 February 2017

Abstract: Ionic liquids (ILs) based ultrasonic-assisted extract has been applied for the extraction of essential oil from Persicaria minor leaves. The effects of temperature, sonication time, and particle size of the plant material on the yield of essential oil were investigated. Among the different ILs employed, 1-ethyl-3-methylimidazolium acetate was the most effective, providing a 9.55% yield of the essential oil under optimum conditions (70 ℃, 25 min, IL:hexane ratio of 7:10 (v/v), particle size 60-80 mesh). The performance of 1-ethyl-3-methylimidazolium acetate in the extraction was attributed to its low viscosity and ability to disintegrate the structural matrix of the plant material. The ability of 1-ethyl-3-methylimidazolium acetate was also confirmed using the conductor like-screening model for realistic solvents. This research proves that ILs can be used to extract essential oils from lignocellulosic biomass.

Key words:

gas chromatography mass spectrometry (GC-MS)
/ ionic liquid (IL)
/ ultrasonication
/ optimization
/ Persicaria minor
/ essential oil

1. [1] Vikram P, Chiruvella K K, Ripain H A, et al. Asian Pac J Trop Biomed, 2014, 4: 430
2. [2] Giarratana F, Muscolino D, Ragonese C, et al. J Essent Oil Res, 2016, 28: 457
3. [3] Jiao J, Gai Q Y, Zu G Y, et al. Sep Purif Technol, 2013, 107: 228
4. [4] Shaaban H A, El-Ghorab A H, Shibamoto T, et al. J Essent Oil Res, 2012, 24: 203
5. [5] Golmakani M T, Moayyedi M. J Essent Oil Res, 2016, 28: 272
6. [6] Bou Abdallah I, Baatour O, Mechrgui K, et al. J Essent Oil Res, 2016, 28: 545
7. [7] Sandrine P I, Christian G, Giancarlo C, et al. J Chromatogr A, 2013, 1305: 47
8. [8] Yang L, Wang H, Zu Y G, et al. Chem Eng J, 2011, 172: 705
9. [9] Cao Y, Wu J, Zhang T, et al. Chem Eng J, 2009, 147: 13[ZK)]
10. [10] [WB][ZK(#]Zhu S, Wu Y, Wang C, et al. Green Chem, 2006, 8: 325
11. [11] Xie H, Zhang S, Li S. Green Chem, 2006, 8: 630
12. [12] Biswas A, Shogren R, Willett J, et al. Carbohyd Polym, 2006, 66: 546
13. [13] Xie H, Li S, Zhang S. Green Chem, 2005, 7: 606
14. [14] Yan F, Texter J. Chem Commun, 2006, 25, 2696
15. [15] Fan J P, Cao J, Zhang X H, et al. Food Chem, 2012, 135: 2299
16. [16] Benvenuti F, Gironi F, Lamberti L. J Super Fluids, 2001, 20: 44
17. [17] Chang S, Abbaspour H, Nafchi A M, et al. J Essent Oil Bear Pl, 2016, 19: 1931
18. [18] Klamt A. Fluid Phase Equilibr, 2003, 206: 223
19. [19] Benazzouz A, Moity L, Pierlot C, et al. Colloid Surf A-Physicochem Eng Asp, 2014, 458: 101
20. [20] Durand M, Molinier V, Kunz W, et al. Chem-A Europ J, 2011, 17: 5155
21. [21] Garcia-Chavez L Y, Hermans A J, Hermans J, et al. Sep Purif Technol, 2012, 97: 2
22. [22] Zhou T, Qi Z. Chem Eng Sci, 2014, 115: 177
23. [23] Farhat A, Fabiano-Tixier A S, Visinoni F, et al. J Chromatogr A, 2010, 1217: 7345
24. [24] Muhammad N, Man Z, Bustam M A, et al. Chem Bio Eng R, 2015, 2: 257
25. [25] Gardeli C, Vassiliki P, Athanasios C, et al. Food Chem, 2008, 107: 1120
26. [26] Havlik J, Kokoska L, Valterova I, et al. Flavour Frag J, 2006, 21: 713
27. [27] Farooq M, Ramli A, Naeem A. RSC Advanc, 2016, 6: 872
28. [28] Yedhu Krishnan R, Rajan K S. Sep Purif Technol, 2016, 157: 169
29. [29] Avato P, Raffo F, Vartanian S, et al. Flavour Frag J, 2004, 19: 559
30. [30] Dallüge J, Beens J, Udo A. J Chromatogr A, 2003, 1000: 69
31. [31] Rusdi N A, Goh H H, Baharum S N. Plant Omics, 2016, 9: 289

扫一扫看文章

计量

PDF下载量: 3
文章访问数: 444
HTML全文浏览量: 40

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于离子液的超声辅助萃取小蓼叶中的精油及真实溶剂似导体屏蔽模型研究（英文）

English

Ionic liquid based ultrasonication-assisted extraction of essential oil from the leaves of Persicaria minor and conductor-like screening model for realistic solvents study

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于离子液的超声辅助萃取小蓼叶中的精油及真实溶剂似导体屏蔽模型研究（英文）

English

Ionic liquid based ultrasonication-assisted extraction of essential oil from the leaves of Persicaria minor and conductor-like screening model for realistic solvents study

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs