故宫养心殿佛塔鎏金铜钉涂层成分分析

引用本文: 魏乐, 金高娃, 丁俊杰, 郭志谋. 故宫养心殿佛塔鎏金铜钉涂层成分分析[J]. 分析化学, 2022, 50(9): 1407-1414. doi: 10.19756/j.issn.0253-3820.210721 shu

Citation: WEI Le, JIN Gao-Wa, DING Jun-Jie, GUO Zhi-Mou. Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum[J]. Chinese Journal of Analytical Chemistry, 2022, 50(9): 1407-1414. doi: 10.19756/j.issn.0253-3820.210721 shu

故宫养心殿佛塔鎏金铜钉涂层成分分析

魏乐 ^1, ,
金高娃 ^{2,3,
,} ,
丁俊杰 ^3, ,
郭志谋 ^2,3,

1.
故宫博物院文保科技部, 北京 100009;
2.
中国科学院大连化学物理研究所. 中国科学院分离分析化学重点实验室, 大连 116023;
3.
赣江中药创新中心, 南昌 330000

通讯作者: 金高娃,E-mail:jingw@dicp.ac.cn

基金项目:
国家重点研发计划专项项目（No.2019YFC1520300）和国家自然科学基金项目（No.22074141）资助。

摘要: 在对故宫养心殿西暖阁佛堂佛塔进行修复清洗时,发现鎏金铜钉外涂有一层特殊黑红色材质。涂层材质经甲醇/酸提取,采用液相色谱-质谱(LC-MS)法进行检测分析,同时结合X射线荧光能谱仪、X射线衍射仪及显微红外光谱仪,对其成分及上染工艺进行分析。分析结果表明,无机矿物主要成分含有石膏、石英和碳酸钙,还检测到锈蚀产物氯铜矿、氯化亚铜及草酸钙,植物胶作为调和剂。LC-MS分析结果表明,该铜钉采用紫檀作为显色物质进行上色,这种上色技巧使铜钉外观与紫檀佛塔浑然天成。本研究为混合材质类文物的分析提供了参考。

关键词:

English

Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum

1.
Conservation Department, the Palace Museum, Beijing 100009, China;
2.
CAS Key Lab of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
3.
Ganjiang Chinese Medicine Innovation Center, Nanchang 330000, China

Corresponding author: JIN Gao-Wa, jingw@dicp.ac.cn

Received Date: 02 September 2021
Revised Date: 20 June 2022
Fund Project:
Supported by the National Key R&D Program of China (No.2019YFC1520300) and the National Natural Science Foundation of China (No.22074141).

Abstract: The gilt brass nail components embedded in the Buddhist pagoda were coated with a special layer of dark red material which was discovered during the protection and restoration process. After pre-treatments with methanol/acid extraction, liquid chromatography-mass spectrometry (LC-MS) in combination with energy dispersive X-ray fluorescence (EDXRF), X-ray powder diffraction (XRD) and micro-Fourier transform infrared (micro-FTIR) was applied to analysis of the composition and manufacturing process. The results showed that the black layer consisted of gypsum, quartz and calcite, as well as atacamite, nantokite and weddellite as corrosion products with plant gum as effect additive. Red sandalwood was applied as coloring matter for dyeing to echo the whole style of pagoda naturally. This study provided a new view for the analysis of mix-media cultural relics.

Key words:

Gilt brass nail
/ Liquid chromatography-mass spectrometry
/ Red sandalwood
/ Cultural relics

1. [1]
  PIROK B W J, DEN UIJL M J, MORO G, BERBERS S V J, CROES C J M, VAN BOMMEL M R, SCHOENMAKERS P J. Anal. Chem., 2019, 91(4):3062-3069.PIROK B W J, DEN UIJL M J, MORO G, BERBERS S V J, CROES C J M, VAN BOMMEL M R, SCHOENMAKERS P J. Anal. Chem., 2019, 91(4):3062-3069.
2. [2]
  HAN J, WANROOIJ J, VAN BOMMEL M, QUYE A. J. Chromatogr. A, 2017, 1479:87-96.HAN J, WANROOIJ J, VAN BOMMEL M, QUYE A. J. Chromatogr. A, 2017, 1479:87-96.
3. [3]
  ZHANG Lin-Yu, TIAN Ke-Xin, WANG Yun-Li, DU Zhen-Xia. J. Beijing. Univ. Chem. Technol. (Nat. Sci. Ed.), 2017, 44(5):52-57. 张林玉, 田可心, 王允丽, 杜振霞. 北京化工大学学报(自然科学版), 2017, 44(5):52-57.
4. [4]
  TAMBURINI D, CARTWRIGHT C R, PULLAN M, VICKERS H. Archaeol. Anthrop. Sci., 2019, 11(4):1221-1239.TAMBURINI D, CARTWRIGHT C R, PULLAN M, VICKERS H. Archaeol. Anthrop. Sci., 2019, 11(4):1221-1239.
5. [5]
  LIU J, JI L, CHEN L, PEI K, ZHAO P, ZHOU Y, ZHAO F. Dyes Pigm., 2018, 153:137-143.LIU J, JI L, CHEN L, PEI K, ZHAO P, ZHOU Y, ZHAO F. Dyes Pigm., 2018, 153:137-143.
6. [6]
  CALA E, BENZI M, GOSETTI F, ZANIN A, GULMINI M, IDONE A, SERAFINI I, CICCOLA A, CURINI R, WHITWORTH I, ACETO M. Microchem. J., 2019, 150:104140.CALA E, BENZI M, GOSETTI F, ZANIN A, GULMINI M, IDONE A, SERAFINI I, CICCOLA A, CURINI R, WHITWORTH I, ACETO M. Microchem. J., 2019, 150:104140.
7. [7]
  PETROVICIU I, BERGHE I V, CRETU I, ALBU F, MEDVEDOVICI A. J. Cul. Heri., 2012, 13(1):89-97.PETROVICIU I, BERGHE I V, CRETU I, ALBU F, MEDVEDOVICI A. J. Cul. Heri., 2012, 13(1):89-97.
8. [8]
  AHMED H E, TAHOUN I F, ELKHOLY I, SHEHATA A B, ZIDDAN Y. Dyes Pigm., 2017, 145:486-492.AHMED H E, TAHOUN I F, ELKHOLY I, SHEHATA A B, ZIDDAN Y. Dyes Pigm., 2017, 145:486-492.
9. [9]
  LIU J, GUO D, ZHOU Y, WU Z, LI W, ZHAO F, ZHENG X. J. Archaeol. Sci., 2011, 38(7):1763-1770.LIU J, GUO D, ZHOU Y, WU Z, LI W, ZHAO F, ZHENG X. J. Archaeol. Sci., 2011, 38(7):1763-1770.
10. [10]
  LIU J, MOURI C, LAURSEN R, ZHAO F, ZHOU Y, LI W. J. Archaeol. Sci., 2013, 40(12):4444-4449.LIU J, MOURI C, LAURSEN R, ZHAO F, ZHOU Y, LI W. J. Archaeol. Sci., 2013, 40(12):4444-4449.
11. [11]
  HU Dong-Bo. Chinese Museum, 2009, (1):87-89. 胡东波. 中国博物馆, 2009, (1):87-89.
12. [12]
  WANG Zi-Lin. Palace Museum J., 2002, 3:28-40. 王子林. 故宫博物院院刊, 2002, 3:28-40.
13. [13]
  JI Li-Fang, WANG Min-Ying, ZHANG De-Jun. Stud. Nat. Cult. Herit., 2021, 6(1):29-37. 纪立芳, 王敏英, 张德军. 自然与文化遗产研究, 2021, 6(1):29-37.
14. [14]
  QU Feng. J. Nat. Museum China, 2020, 8:87-101. 屈峰. 中国国家博物馆馆刊, 2020, 8:87-101.
15. [15]
  WEI Shu-Ya, LI Qian-Qian, FU Ying-Chun. Kexue, 2016, 68(6):36-39. 魏书亚, 李倩倩, 付迎春. 科学, 2016, 68(6):36-39.
16. [16]
  MA Yue, LI Xiu-Hui. Chin. J. Hist. Sci. Technol., 2010, 31(2):207-214. 马越, 李秀辉. 中国科技史杂志, 2010, 31(2):207-214.
17. [17]
  XIE Ding-Lu, SUI Xian-Dong, LUO Yan-Gui. Mater. Rep., 2011, 25(S1):497-503. 谢定陆, 隋贤栋, 罗艳归. 材料导报, 2011, 25(S1):497-503.
18. [18]
  QU Liang, LI Xiu-Hui, WANG Shi-Wei, GAO Fei, MA Yue. Sci. Conserv. Archaeol., 2013, 25(1):30-39. 曲亮, 李秀辉, 王时伟, 高飞, 马越. 文物保护与考古科学, 2013, 25(1):30-39.
19. [19]
  LV Liang-Bo. Sci. Conserv. Archaeol., 2010, 22(3):76-80. 吕良波. 文物保护与考古科学, 2010, 22(3):76-80.
20. [20]
  QU Liang, GAO Fei, LIU Jian-Yu, HE Lin, LEI Yong, SHUI Wu-Yang. Museum, 2018, 2:119-127. 曲亮, 高飞, 刘建宇, 何林, 雷勇, 税午阳. 博物院, 2018, 2:119-127.
21. [21]
  PENG Wen-Shi, LIU Gao-Kui. Infrared Spectra of Minerals. Beijing:Science Press, 1982. 彭文世, 刘高魁. 矿物红外光谱图集. 北京:科学出版社, 1982.
22. [22]
  LI Zui-Xiong. Dunhuang Res., 1990, (3):69-83. 李最雄. 敦煌研究, 1990, (3):69-83.
23. [23]
  KHORSHA S, ALIZADEH M, MASHAYEKHI K. Adv. Hort. Sci., 2016, 30(2):111-118.KHORSHA S, ALIZADEH M, MASHAYEKHI K. Adv. Hort. Sci., 2016, 30(2):111-118.
24. [24]
  Philadelphia Museum of Art, Philadelphia. "IWX00086, Beeswax." Infrared and Raman Users Group, 2007. Web. .Philadelphia Museum of Art, Philadelphia. "IWX00086, Beeswax." Infrared and Raman Users Group, 2007. Web. .

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

故宫养心殿佛塔鎏金铜钉涂层成分分析

通讯作者: 金高娃,E-mail:jingw@dicp.ac.cn

English

Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum

Corresponding author: JIN Gao-Wa, jingw@dicp.ac.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

故宫养心殿佛塔鎏金铜钉涂层成分分析

通讯作者: 金高娃,E-mail:jingw@dicp.ac.cn

English

Analysis of Coating Components of Gilt Brass Nails in the Hall of Mental Cultivation (Yangxin Hall) of the Palace Museum

Corresponding author: JIN Gao-Wa, jingw@dicp.ac.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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