Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity

Min WENG ManHua ZHANG Tao SHEN

引用本文: Min WENG,  ManHua ZHANG,  Tao SHEN. Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity[J]. Chinese Chemical Letters, 1996, 7(10): 924-927. shu
Citation:  Min WENG,  ManHua ZHANG,  Tao SHEN. Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity[J]. Chinese Chemical Letters, 1996, 7(10): 924-927. shu

Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity

摘要: In this paper, the singlet and triplet state electron transfer processes between hypocrellin A(HA) and aromatic amines in solvents of various polarity have been studied by fluorescence and time-resolved transient absorption spectra.The results show, in.polar solvent, the quenching of HA fluorescence by aromatic amines results in Stern-Volmer plot, the investigation of transient absorption indicated that triplet-state electron transfer process from 3HA* to the ground-state of amines occured, and the values of the singlet and triplet state electron transfer rate constant were calculated, however in weak polar solvent, only the triplet-triplet absorption of HA was observed.

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  • 收稿日期:  1996-07-01
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