引用本文:
Min WENG, ManHua ZHANG, Tao SHEN. Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity[J]. Chinese Chemical Letters,
1996, 7(10): 924-927.
Citation: Min WENG, ManHua ZHANG, Tao SHEN. Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity[J]. Chinese Chemical Letters, 1996, 7(10): 924-927.
Citation: Min WENG, ManHua ZHANG, Tao SHEN. Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity[J]. Chinese Chemical Letters, 1996, 7(10): 924-927.
Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity
摘要:
In this paper, the singlet and triplet state electron transfer processes between hypocrellin A(HA) and aromatic amines in solvents of various polarity have been studied by fluorescence and time-resolved transient absorption spectra.The results show, in.polar solvent, the quenching of HA fluorescence by aromatic amines results in Stern-Volmer plot, the investigation of transient absorption indicated that triplet-state electron transfer process from 3HA* to the ground-state of amines occured, and the values of the singlet and triplet state electron transfer rate constant were calculated, however in weak polar solvent, only the triplet-triplet absorption of HA was observed.
English
Study on the Singlet and Triplet StateElectron Transfer between Hypocrellin A and Aromatic Amines in Solvents of Various Polarity
Abstract:
In this paper, the singlet and triplet state electron transfer processes between hypocrellin A(HA) and aromatic amines in solvents of various polarity have been studied by fluorescence and time-resolved transient absorption spectra.The results show, in.polar solvent, the quenching of HA fluorescence by aromatic amines results in Stern-Volmer plot, the investigation of transient absorption indicated that triplet-state electron transfer process from 3HA* to the ground-state of amines occured, and the values of the singlet and triplet state electron transfer rate constant were calculated, however in weak polar solvent, only the triplet-triplet absorption of HA was observed.
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