引用本文:
Jing Yang, Le Xin Song, Zheng Dang, Shu Zhen Pan, Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters,
2011, 22(11): 1347-1350.
doi:
10.1016/j.cclet.2011.05.029
Citation: Jing Yang, Le Xin Song, Zheng Dang, Shu Zhen Pan, Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters, 2011, 22(11): 1347-1350. doi: 10.1016/j.cclet.2011.05.029

Citation: Jing Yang, Le Xin Song, Zheng Dang, Shu Zhen Pan, Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters, 2011, 22(11): 1347-1350. doi: 10.1016/j.cclet.2011.05.029

Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine
摘要:
This study reveals that the noncovalent complexation between β-CD and Cu (HMTA)2+ makes a positive contribution to the coordination interaction between Cu2+ and HMTA in a tricomponent system. Besides, mono-and binuclear complexes:[β-CD·Cu]+ and[Cu-β-CD·Cu)+ were observed under the condition of ESI-MS.
English
Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine
Abstract:
This study reveals that the noncovalent complexation between β-CD and Cu(HMTA)2+ makes a positive contribution to the coordination interaction between Cu2+ and HMTA in a tricomponent system. Besides, mono-and binuclear complexes:[β-CD·Cu]+ and[Cu-β-CD·Cu)+ were observed under the condition of ESI-MS.
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Key words:
- Noncovalent complexation
- / Coordination interaction
- / β-Cyclodextrin
- / Copper chloride

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