Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine

Jing Yang Le Xin Song Zheng Dang Shu Zhen Pan Fang Yun Du

引用本文: Jing Yang,  Le Xin Song,  Zheng Dang,  Shu Zhen Pan,  Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters, 2011, 22(11): 1347-1350. doi: 10.1016/j.cclet.2011.05.029 shu
Citation:  Jing Yang,  Le Xin Song,  Zheng Dang,  Shu Zhen Pan,  Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters, 2011, 22(11): 1347-1350. doi: 10.1016/j.cclet.2011.05.029 shu

Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine

  • 基金项目:

    This project was supported by NSFC (No.21071139).

摘要: This study reveals that the noncovalent complexation between β-CD and Cu (HMTA)2+ makes a positive contribution to the coordination interaction between Cu2+ and HMTA in a tricomponent system. Besides, mono-and binuclear complexes:[β-CD·Cu]+ and[Cu-β-CD·Cu)+ were observed under the condition of ESI-MS.

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  • 收稿日期:  2011-03-15
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