引用本文:
Gang LIU, Feng HE, Yan Ping WANG, Jun FENG, Ren Xi ZHUO. Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups[J]. Chinese Chemical Letters,
2006, 17(1): 137-139.
Citation: Gang LIU, Feng HE, Yan Ping WANG, Jun FENG, Ren Xi ZHUO. Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups[J]. Chinese Chemical Letters, 2006, 17(1): 137-139.
Citation: Gang LIU, Feng HE, Yan Ping WANG, Jun FENG, Ren Xi ZHUO. Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups[J]. Chinese Chemical Letters, 2006, 17(1): 137-139.
Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups
摘要:
A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate (ATMC), was synthesized starting from glycerol, and the corresponding polycarbonates, poly(5-allyloxytrimethylene carbonate)(PATMC) were further synthesized by ring-opening polymerization in bulk at 150℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, 1H-NMR, 13C-NMR, and GPC analysis.
English
Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups
Abstract:
A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate (ATMC), was synthesized starting from glycerol, and the corresponding polycarbonates, poly(5-allyloxytrimethylene carbonate)(PATMC) were further synthesized by ring-opening polymerization in bulk at 150℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, 1H-NMR, 13C-NMR, and GPC analysis.
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