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Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands

LI Jia-Ming ,  SHI Zhong-Feng ,  HE Kun-Huan

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Citation:  LI Jia-Ming, SHI Zhong-Feng, HE Kun-Huan. Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 135-142. doi: 10.14102/j.cnki.0254-5861.2011-0797 shu

Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands

  • 1.

    College of Petroleum and Chemical Engineering, Qinzhou University, Qinzhou 535000, China

  • 基金项目:

    This work was supported by Guangxi Provincial Department of Education (No. KY2015ZD130)  (No. KY2015ZD130)

    the Natural Science Foundation of Guangxi Province (No. 2013GXNSFBA019030). The authors also acknowledge the financial support from the Natural Science Foundation of Qinzhou University (No. 2014PY-GJ05) (No. 2013GXNSFBA019030)

摘要: A new binuclear ZnII coordination complex, Zn2(bta)(phen)2(Cl)3 (1, Hbta = 2-(1H- benzotriazol-1-yl)acetic acid and phen = 1,10-phenanthroline), has been synthesized and characteri- zed by single-crystal X-ray diffraction, IR spectroscopy, elemental, and photoluminescent analysis. Complex 1 crystallizes in triclinic system, space group P with a = 9.3040(19), b = 10.694(2), c = 16.841(3) Å, α = 101.18(3), β = 105.77(3), γ = 91.72(3)°, V = 1575.8(5) Å3, C32H22Zn2Cl3N7O2, Mr = 773.66, Dc = 1.631 g/cm3, Z = 2, F(000) = 780, μ = 1.820 mm-1, the final R = 0.1238 and wR = 0.1131. X-ray diffraction analyses indicate that 1 displays two crystallographic independent ZnII metal centers with a distorted tetragonal pyramidal (ZnN4O) and a tetrahedral (ZnNCl3) geometries, respectively. The phen serves as a common N,N'-bidentate ligand, and the bta- as a unique N,O-bridged ligand in 1. In the crystal, 1 forms a stable 3D supramolecular architecture by trifurcated hydrogen bonding C-H…Cl interactions and C-H…π, π…π stacking. 1 showed photo-electric conversion properties.

English

  • 
    1. [1]

      (1) Zhang, R. H.; Xia, W. S.; Wang, H. X.; Zhou, Z. H. Metal-organic frameworks constructed from monomeric, dimeric and trimeric phenanthroline citrate zinc building units. Inorg. Chem. Commun. 2009, 12, 583-587.(1) Zhang, R. H.; Xia, W. S.; Wang, H. X.; Zhou, Z. H. Metal-organic frameworks constructed from monomeric, dimeric and trimeric phenanthroline citrate zinc building units. Inorg. Chem. Commun. 2009, 12, 583-587.

    2. [2]

      (2) Dai, M.; Zhu, L. W.; Yang, J. H.; Li, H. X.; Chen, M. M.; Ren, Z. G.; Lang, J. P. Spacer length effect on the formation of different zinc coordination polymers of 1,4-benzenedicarboxylate and flexible bipyrazolyl ligands. Inorg. Chem. Commun. 2013, 29, 70-75.(2) Dai, M.; Zhu, L. W.; Yang, J. H.; Li, H. X.; Chen, M. M.; Ren, Z. G.; Lang, J. P. Spacer length effect on the formation of different zinc coordination polymers of 1,4-benzenedicarboxylate and flexible bipyrazolyl ligands. Inorg. Chem. Commun. 2013, 29, 70-75.

    3. [3]

      (3) Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Metal carboxylates with open architectures. Angew. Chem. Int. Ed. 2004, 43, 1466-1496.(3) Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Metal carboxylates with open architectures. Angew. Chem. Int. Ed. 2004, 43, 1466-1496.

    4. [4]

      (4) Chu, Q.; Liu, G. X.; Huang, Y. Q.; Wang, X. F.; Sun, W. Y. Syntheses, structures, and optical properties of novel zinc(II) complexes with multicarboxylate and N-donor ligands. Dalton Trans. 2007, 36, 4302-4311.(4) Chu, Q.; Liu, G. X.; Huang, Y. Q.; Wang, X. F.; Sun, W. Y. Syntheses, structures, and optical properties of novel zinc(II) complexes with multicarboxylate and N-donor ligands. Dalton Trans. 2007, 36, 4302-4311.

    5. [5]

      (5) Tong, M. L.; Hu, S.; Wang, J.; Kitagawa, S.; Ng, S. W. Supramolecular isomerism in cadmium hydroxide phases. Temperature-dependent synthesis and structure of photoluminescent coordination polymers of α- and β-Cd2(OH)2(2,4-pyda). Cryst. Growth Des. 2005, 5, 837-839.(5) Tong, M. L.; Hu, S.; Wang, J.; Kitagawa, S.; Ng, S. W. Supramolecular isomerism in cadmium hydroxide phases. Temperature-dependent synthesis and structure of photoluminescent coordination polymers of α- and β-Cd2(OH)2(2,4-pyda). Cryst. Growth Des. 2005, 5, 837-839.

    6. [6]

      (6) Forster, P. M.; Burbank, A. R.; Livage, C.; Férey, G.; Cheetham, A. K. The role of temperature in the synthesis of hybrid inorganic-organic materials: the example of cobalt succinates. Chem. Commun. 2004, 368-369.(6) Forster, P. M.; Burbank, A. R.; Livage, C.; Férey, G.; Cheetham, A. K. The role of temperature in the synthesis of hybrid inorganic-organic materials: the example of cobalt succinates. Chem. Commun. 2004, 368-369.

    7. [7]

      (7) Chen, Y.; Li, H. X.; Liu, D.; Liu, L. L.; Li, N. Y.; Ye, H. Y.; Zhang, Y.; Lang, J. P. Solvent effects on the assembly of [Cu2I2]- or [Cu4I4]-based coordination polymers: isolation, structures and luminescent properties. Cryst. Growth Des. 2008, 8, 3810-3816.(7) Chen, Y.; Li, H. X.; Liu, D.; Liu, L. L.; Li, N. Y.; Ye, H. Y.; Zhang, Y.; Lang, J. P. Solvent effects on the assembly of [Cu2I2]- or [Cu4I4]-based coordination polymers: isolation, structures and luminescent properties. Cryst. Growth Des. 2008, 8, 3810-3816.

    8. [8]

      (8) Zheng, P. Q.; Ren, Y. P.; Long, L. S.; Huang, R. B.; Zheng, L. S. pH-dependent assembly of Keggin-based supramolecular architecture. Inorg. Chem. 2005, 44, 1190-1192.(8) Zheng, P. Q.; Ren, Y. P.; Long, L. S.; Huang, R. B.; Zheng, L. S. pH-dependent assembly of Keggin-based supramolecular architecture. Inorg. Chem. 2005, 44, 1190-1192.

    9. [9]

      (9) Liu, D.; Ren, Z. G.; Li, H. X. Chen, Y.; Wang, J.; Zhang, Y.; Lang, J. P. pH-Dependent solvothermal formation of two different 3D multiple interpenetrating nets from the same components. CrystEngComm. 2010, 12, 1912-1919.(9) Liu, D.; Ren, Z. G.; Li, H. X. Chen, Y.; Wang, J.; Zhang, Y.; Lang, J. P. pH-Dependent solvothermal formation of two different 3D multiple interpenetrating nets from the same components. CrystEngComm. 2010, 12, 1912-1919.

    10. [10]

      (10) Rispens, M. T.; Meetsma, A.; Rittberger, R.; Brabec, C. J.; Sariciftci, N. S.; Hummelen, J. C. Influence of the solvent on the crystal structure of PCBM and the efficiency of MDMO-PPV:PCBM ‘plastic’ solar cells. Chem. Commun. 2003, 2116-2118.(10) Rispens, M. T.; Meetsma, A.; Rittberger, R.; Brabec, C. J.; Sariciftci, N. S.; Hummelen, J. C. Influence of the solvent on the crystal structure of PCBM and the efficiency of MDMO-PPV:PCBM ‘plastic’ solar cells. Chem. Commun. 2003, 2116-2118.

    11. [11]

      (11) Dapporto, P.; Formica, M.; Fusi, V.; Giorgi, L.; Micheloni, M.; Paoli, P.; Pontellini, R.; Rossi, P. Addition of small molecules by Zn(II) and Cu(II) dinuclear complexes obtained by an amino-phenolic ligand. Crystal structures of the dinuclear zinc complex assembling butanolate and azide anions. Inorg. Chem. 2001, 40, 6186-6192.(11) Dapporto, P.; Formica, M.; Fusi, V.; Giorgi, L.; Micheloni, M.; Paoli, P.; Pontellini, R.; Rossi, P. Addition of small molecules by Zn(II) and Cu(II) dinuclear complexes obtained by an amino-phenolic ligand. Crystal structures of the dinuclear zinc complex assembling butanolate and azide anions. Inorg. Chem. 2001, 40, 6186-6192.

    12. [12]

      (12) Arora, H.; Barman, S. K.; Lloret, F.; Mukherjee, R. Isostructural dinuclear phenoxo-/acetato-bridged manganese(II), cobalt(II), and zinc(II) complexes with labile sites: kinetics of transesterification of 2-hydroxypropyl-p-nitrophenylphosphate. Inorg. Chem. 2012, 51, 5539-5553.(12) Arora, H.; Barman, S. K.; Lloret, F.; Mukherjee, R. Isostructural dinuclear phenoxo-/acetato-bridged manganese(II), cobalt(II), and zinc(II) complexes with labile sites: kinetics of transesterification of 2-hydroxypropyl-p-nitrophenylphosphate. Inorg. Chem. 2012, 51, 5539-5553.

    13. [13]

      (13) Neverov, A. A.; Liu, C. T.; Bunn, S. E.; Edwards, D.; White, C. J.; Melnychuk, S. A.; Brown, R. S. A simple DNase model system comprising a dinuclear Zn(II) complex in methanol accelerates the cleavage of a series of methyl aryl phosphate diesters by 1011-1013. J. Am. Chem. Soc. 2008, 130, 6639-6649.(13) Neverov, A. A.; Liu, C. T.; Bunn, S. E.; Edwards, D.; White, C. J.; Melnychuk, S. A.; Brown, R. S. A simple DNase model system comprising a dinuclear Zn(II) complex in methanol accelerates the cleavage of a series of methyl aryl phosphate diesters by 1011-1013. J. Am. Chem. Soc. 2008, 130, 6639-6649.

    14. [14]

      (14) Tsang, W. Y.; Edwards, D. R.; Melnychuk, S. A.; Liu, C. T.; Liu, C.; Neverov, A. A.; Williams, N. H.; Brown, R. S. Dinuclear Zn(II) complex promotes cleavage and isomerization of 2-hydroxypropyl alkyl phosphates by a common cyclic phosphate intermediate. J. Am. Chem. Soc. 2009, 131, 4159-4166.(14) Tsang, W. Y.; Edwards, D. R.; Melnychuk, S. A.; Liu, C. T.; Liu, C.; Neverov, A. A.; Williams, N. H.; Brown, R. S. Dinuclear Zn(II) complex promotes cleavage and isomerization of 2-hydroxypropyl alkyl phosphates by a common cyclic phosphate intermediate. J. Am. Chem. Soc. 2009, 131, 4159-4166.

    15. [15]

      (15) Liu, C. T. Neverov, A. A.; Brown, R. S. Biomimetic cleavage of RNA models promoted by a dinuclear Zn(II) complex in ethanol. Greater than 30 kcal/mol stabilization of the transition state for cleavage of a phosphate diester. J. Am. Chem. Soc. 2008, 130, 16711-16720.(15) Liu, C. T. Neverov, A. A.; Brown, R. S. Biomimetic cleavage of RNA models promoted by a dinuclear Zn(II) complex in ethanol. Greater than 30 kcal/mol stabilization of the transition state for cleavage of a phosphate diester. J. Am. Chem. Soc. 2008, 130, 16711-16720.

    16. [16]

      (16) Gao, H.; Ke, Z. F.; Yonker, N. J. D.; Wang, J. P.; Xu, H. Y.; Mao, Z. W.; Phillips, D. L.; Zhao, C. Y. Dinuclear Zn(II) complex catalyzed phosphodiester cleavage proceeds via a concerted mechanism: a density functional theory study. J. Am. Chem. Soc. 2011, 133, 2904-2915.(16) Gao, H.; Ke, Z. F.; Yonker, N. J. D.; Wang, J. P.; Xu, H. Y.; Mao, Z. W.; Phillips, D. L.; Zhao, C. Y. Dinuclear Zn(II) complex catalyzed phosphodiester cleavage proceeds via a concerted mechanism: a density functional theory study. J. Am. Chem. Soc. 2011, 133, 2904-2915.

    17. [17]

      (17) Bunn, S. E.; Liu, C. T.; Lu, Z. L.; Neverov, A. A.; Brown, R. S. The dinuclear Zn(II) complex catalyzed cyclization of a series of 2-hydroxypropyl aryl phosphate RNA models: progressive change in mechanism from rate-limiting P-O bond cleavage to substrate binding. J. Am. Chem. Soc. 2007, 129, 16238-16248.(17) Bunn, S. E.; Liu, C. T.; Lu, Z. L.; Neverov, A. A.; Brown, R. S. The dinuclear Zn(II) complex catalyzed cyclization of a series of 2-hydroxypropyl aryl phosphate RNA models: progressive change in mechanism from rate-limiting P-O bond cleavage to substrate binding. J. Am. Chem. Soc. 2007, 129, 16238-16248.

    18. [18]

      (18) Andrey, O. I.; Kovalevsky, Y.; Morrow, J. R.; Richard, J. P. Physical and kinetic analysis of the cooperative role of metal ions in catalysis of phosphodiester cleavage by a dinuclear Zn(II) complex. J. Am. Chem. Soc. 2003, 125, 1988-1993.(18) Andrey, O. I.; Kovalevsky, Y.; Morrow, J. R.; Richard, J. P. Physical and kinetic analysis of the cooperative role of metal ions in catalysis of phosphodiester cleavage by a dinuclear Zn(II) complex. J. Am. Chem. Soc. 2003, 125, 1988-1993.

    19. [19]

      (19) Bera, M.; Curtiss, A. B. S.; Musie, G. T.; Powell, D. R. New dinuclear cobalt(II) and zinc(II) complexes of a carboxylate-rich dinucleating ligand: synthesis, structure, spectroscopic characterization, and their interactions with sugars. Inorg. Chem. 2012, 51, 12093-12101.(19) Bera, M.; Curtiss, A. B. S.; Musie, G. T.; Powell, D. R. New dinuclear cobalt(II) and zinc(II) complexes of a carboxylate-rich dinucleating ligand: synthesis, structure, spectroscopic characterization, and their interactions with sugars. Inorg. Chem. 2012, 51, 12093-12101.

    20. [20]

      (20) Anbu, S.; Kamalraj, S.; Varghese, B.; Muthumary, J.; Kandaswamy, M. A series of oxyimine-based macrocyclic dinuclear zinc(II) complexes enhances phosphate ester hydrolysis, DNA binding, DNA hydrolysis, and lactate dehydrogenase inhibition and induces apoptosis. Inorg. Chem. 2012, 51, 5580-5592.(20) Anbu, S.; Kamalraj, S.; Varghese, B.; Muthumary, J.; Kandaswamy, M. A series of oxyimine-based macrocyclic dinuclear zinc(II) complexes enhances phosphate ester hydrolysis, DNA binding, DNA hydrolysis, and lactate dehydrogenase inhibition and induces apoptosis. Inorg. Chem. 2012, 51, 5580-5592.

    21. [21]

      (21) Kronik, L.; Shapira, Y. Surface photovoltage phenomena: theory, experiment, and applications. Surf. Sci. Rep. 1999, 37, 1-206.(21) Kronik, L.; Shapira, Y. Surface photovoltage phenomena: theory, experiment, and applications. Surf. Sci. Rep. 1999, 37, 1-206.

    22. [22]

      (22) Jing, L. Q.; Sun, X. J.; Shang, J.; Cai, W. M.; Xu, Z. L.; Du, Y. G.; Fu, H. G. Review of surface photovoltage spectra of nanosized semiconductor and its applications in heterogeneous photocatalysis. Sol. Energy Mater. Sol. Cells 2003, 79, 133-151.(22) Jing, L. Q.; Sun, X. J.; Shang, J.; Cai, W. M.; Xu, Z. L.; Du, Y. G.; Fu, H. G. Review of surface photovoltage spectra of nanosized semiconductor and its applications in heterogeneous photocatalysis. Sol. Energy Mater. Sol. Cells 2003, 79, 133-151.

    23. [23]

      (23) Kronik, L.; Shapira, Y. Surface photovoltage spectroscopy of semiconductor structures: at the crossroads of physics, chemistry and electrical engineering. Surf. Interface Anal. 2001, 31, 954-965.(23) Kronik, L.; Shapira, Y. Surface photovoltage spectroscopy of semiconductor structures: at the crossroads of physics, chemistry and electrical engineering. Surf. Interface Anal. 2001, 31, 954-965.

    24. [24]

      (24) Lin, Y.; Wang, D.; Zhao, Q.; Yang, M.; Zhang, Q. A study of quantum confinement properties of photogenerated charges in ZnO nanoparticles by surface photovoltage spectroscopy. J. Phys. Chem. B 2004, 108, 3202-3206.(24) Lin, Y.; Wang, D.; Zhao, Q.; Yang, M.; Zhang, Q. A study of quantum confinement properties of photogenerated charges in ZnO nanoparticles by surface photovoltage spectroscopy. J. Phys. Chem. B 2004, 108, 3202-3206.

    25. [25]

      (25) Xie, T.; Wang, D.; Zhu, L.; Wang, C.; Li, T.; Zhou, X.; Wang, M. Application of surface photovoltage technique to the determination of conduction types of azo pigment films. J. Phys. Chem. B 2000, 104, 8177-8181.(25) Xie, T.; Wang, D.; Zhu, L.; Wang, C.; Li, T.; Zhou, X.; Wang, M. Application of surface photovoltage technique to the determination of conduction types of azo pigment films. J. Phys. Chem. B 2000, 104, 8177-8181.

    26. [26]

      (26) Yu, M.; Zhang, W.; Fan, Y.; Jian, W.; Liu, G. [5-(p-alkoxy)phenyl-10,15,20-tri-phenyl] porphyrin and their rare earth complex liquid crystalline. J. Phys. Org. Chem. 2007, 20, 229-235.(26) Yu, M.; Zhang, W.; Fan, Y.; Jian, W.; Liu, G. [5-(p-alkoxy)phenyl-10,15,20-tri-phenyl] porphyrin and their rare earth complex liquid crystalline. J. Phys. Org. Chem. 2007, 20, 229-235.

    27. [27]

      (27) Streicher, F.; Sadewasser, S.; Enzenhofer, T.; Schock, H. W.; Lux-Steiner, M. C. Locally resolved surface photo voltage spectroscopy on Zn-doped CuInS2 polycrystalline thin films. Thin Solid Films 2009, 517, 2349-2352.(27) Streicher, F.; Sadewasser, S.; Enzenhofer, T.; Schock, H. W.; Lux-Steiner, M. C. Locally resolved surface photo voltage spectroscopy on Zn-doped CuInS2 polycrystalline thin films. Thin Solid Films 2009, 517, 2349-2352.

    28. [28]

      (28) Zidon, Y.; Shapira, Y.; Shaim, H.; Dittrich, T. Interactions at tetraphenyl-porphyrin/InP interfaces observed by surface photovoltage spectroscopy. Appl. Surf. Sci. 2008, 254, 3255-3261.(28) Zidon, Y.; Shapira, Y.; Shaim, H.; Dittrich, T. Interactions at tetraphenyl-porphyrin/InP interfaces observed by surface photovoltage spectroscopy. Appl. Surf. Sci. 2008, 254, 3255-3261.

    29. [29]

      (29) Yuan, W. Z.; Sun, J. Z.; Dong, Y.; Häussler, M.; Yang, F.; Xu, H. P.; Qin, A.; Lam, J. W. Y.; Zheng, Q.; Tang, B. Z. Wrapping carbon nanotubes in pyrene-containing poly(phenylacetylene) chains: solubility, stability, light emission, and surface photovoltaic properties. Macromolecules 2006, 39, 8011-8020.(29) Yuan, W. Z.; Sun, J. Z.; Dong, Y.; Häussler, M.; Yang, F.; Xu, H. P.; Qin, A.; Lam, J. W. Y.; Zheng, Q.; Tang, B. Z. Wrapping carbon nanotubes in pyrene-containing poly(phenylacetylene) chains: solubility, stability, light emission, and surface photovoltaic properties. Macromolecules 2006, 39, 8011-8020.

    30. [30]

      (30) Hang, T.; Ye, Q. Bis[2-(1H-1,2,3-benzotriazol-1-yl)acetic acid-kN3]dichloridozinc(II). Acta Crystallogr. 2008, E64, m758-m758.(30) Hang, T.; Ye, Q. Bis[2-(1H-1,2,3-benzotriazol-1-yl)acetic acid-kN3]dichloridozinc(II). Acta Crystallogr. 2008, E64, m758-m758.

    31. [31]

      (31) Zeng, L.; Wang, Q. L. μ-Oxalato-k4O',O'':O''',O''''-bis[diaqua(2,2'-bipyridyl-k2N,N')zinc]bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate. Acta Crystallog. 2012, E68, m196-m196.(31) Zeng, L.; Wang, Q. L. μ-Oxalato-k4O',O'':O''',O''''-bis[diaqua(2,2'-bipyridyl-k2N,N')zinc]bis[2-(1H-benzotriazol-1-yl)acetate] hexahydrate. Acta Crystallog. 2012, E68, m196-m196.

    32. [32]

      (32) Zeng, L. (Acetato-kO)diaqua[2-(1H-benzotriazol-1-yl)acetato-kO](1,10-phenanthroline- 2N,N')manganese(II) dihydrate. Acta Crystallogr. 2012, E68, m329-m329.(32) Zeng, L. (Acetato-kO)diaqua[2-(1H-benzotriazol-1-yl)acetato-kO](1,10-phenanthroline- 2N,N')manganese(II) dihydrate. Acta Crystallogr. 2012, E68, m329-m329.

    33. [33]

      (33) Liu, Q. Poly[μ2-aqua-bis[μ4-2-(1H-1,2,3-benzotriazol-1-yl)acetato]dipotassium]. Acta Crystallogr. 2012, E68, m379-m379.(33) Liu, Q. Poly[μ2-aqua-bis[μ4-2-(1H-1,2,3-benzotriazol-1-yl)acetato]dipotassium]. Acta Crystallogr. 2012, E68, m379-m379.

    34. [34]

      (34) Wang, W.; Fu, D. W.; Xu, X. B.; Ye, Q. Hydrothermal in situ synthesis of a novel three-dimensional tetrazole coordination polymer with manganese ions. Z. Anorg. Allg. Chem. 2011, 637, 467-471.(34) Wang, W.; Fu, D. W.; Xu, X. B.; Ye, Q. Hydrothermal in situ synthesis of a novel three-dimensional tetrazole coordination polymer with manganese ions. Z. Anorg. Allg. Chem. 2011, 637, 467-471.

    35. [35]

      (35) Hu, T. L.; Du, W. P.; Hu, B. W.; Li, J. R.; Bu, X. H.; Cao, R. Novel Ag(I) complexes with azole heterocycle ligands bearing acetic acid group: synthesis, characterization and crystal structures. CrystEngComm. 2008, 10, 1037-1043.(35) Hu, T. L.; Du, W. P.; Hu, B. W.; Li, J. R.; Bu, X. H.; Cao, R. Novel Ag(I) complexes with azole heterocycle ligands bearing acetic acid group: synthesis, characterization and crystal structures. CrystEngComm. 2008, 10, 1037-1043.

    36. [36]

      (36) Wang, Y. T.; Tang, G. M.; Wei, Y. Q.; Qin, T. X.; Li, T. D.; Ling, J. B.; Long, X. F. One new nonlinear optical and ferroelectric one-dimensional chain constructed by an unsymmetric bridging ligand. Inorg. Chem. Commun. 2009, 12, 1164-1167.(36) Wang, Y. T.; Tang, G. M.; Wei, Y. Q.; Qin, T. X.; Li, T. D.; Ling, J. B.; Long, X. F. One new nonlinear optical and ferroelectric one-dimensional chain constructed by an unsymmetric bridging ligand. Inorg. Chem. Commun. 2009, 12, 1164-1167.

    37. [37]

      (37) Zheng, Z.; Wu, R.; Li, J.; Han, Y.; Lu, J. Synthesis and crystal structures of Cd(II), Ni(II), and Mn(II) complexes of 1H-benzotriazole-1-acetic acid. J. Coord. Chem. 2010, 63, 1118-1129.(37) Zheng, Z.; Wu, R.; Li, J.; Han, Y.; Lu, J. Synthesis and crystal structures of Cd(II), Ni(II), and Mn(II) complexes of 1H-benzotriazole-1-acetic acid. J. Coord. Chem. 2010, 63, 1118-1129.

    38. [38]

      (38) Wang, J. H.; Tang, G. M.; Wang, Y. T.; Qin, T. X.; Ng, S. W. Metal-directed assembly of coordination polymers with the versatile ligand 2-(1H-benzotriazol-1-yl) acetic acid: from discrete structures to two-dimensional networks. CrystEngComm. 2014, 16, 2660-2683.(38) Wang, J. H.; Tang, G. M.; Wang, Y. T.; Qin, T. X.; Ng, S. W. Metal-directed assembly of coordination polymers with the versatile ligand 2-(1H-benzotriazol-1-yl) acetic acid: from discrete structures to two-dimensional networks. CrystEngComm. 2014, 16, 2660-2683.

    39. [39]

      (39) Chen, Y. H.; Li, C. Z.; Li, J. M. Synthesis and crystal structure of two dimensional cobalt(II) coordination polymer [CoL2(H2O)2]n. Chin. J. Synth. Chem. 2010, 18, 328-331.(39) Chen, Y. H.; Li, C. Z.; Li, J. M. Synthesis and crystal structure of two dimensional cobalt(II) coordination polymer [CoL2(H2O)2]n. Chin. J. Synth. Chem. 2010, 18, 328-331.

    40. [40]

      (40) Shi, Z. F.; Li, L.; Niu, S. Y.; Jin, J.; Chi, Y. X.; Zhang, L.; Liu, J. C.; Xing, Y. H. A series of dn transition metal coordination complexes: structures and comparative study of surface electron behaviors (n = 9, 8, 7, 6, 5). Inorg. Chim. Acta 2011, 368, 101-110.(40) Shi, Z. F.; Li, L.; Niu, S. Y.; Jin, J.; Chi, Y. X.; Zhang, L.; Liu, J. C.; Xing, Y. H. A series of dn transition metal coordination complexes: structures and comparative study of surface electron behaviors (n = 9, 8, 7, 6, 5). Inorg. Chim. Acta 2011, 368, 101-110.

    41. [41]

      (41) Shi, Z. F.; Li, J. M.; He, K. H.; Yin, Y. Z.; Niu, S. Y.; Jin, J.; Chi, Y. X. Synthesis, structure, thermal stability and surface photo-electric property of a novel three-dimensional Co(II) complex. Inorg. Chem. Commun. 2013, 35, 235-238.(41) Shi, Z. F.; Li, J. M.; He, K. H.; Yin, Y. Z.; Niu, S. Y.; Jin, J.; Chi, Y. X. Synthesis, structure, thermal stability and surface photo-electric property of a novel three-dimensional Co(II) complex. Inorg. Chem. Commun. 2013, 35, 235-238.

    42. [42]

      (42) Shi, Z. F.; Li, J. M.; Li, L.; Niu, S. Y. Synthesis, structure, and surface photoelectric properties of two novel cobalt(II) complexes. Z. Anorg. Allg. Chem. 2011, 637, 2282-2287.(42) Shi, Z. F.; Li, J. M.; Li, L.; Niu, S. Y. Synthesis, structure, and surface photoelectric properties of two novel cobalt(II) complexes. Z. Anorg. Allg. Chem. 2011, 637, 2282-2287.

    43. [43]

      (43) Li, J. M.; Zhang, X.; Shi, Z. F.; He, K. H. Synthesis, crystal structure, fluorescence, and surface photo-electric properties of a new Co(II) complex based on organosulfonate ligand. Russ. J. Coord. Chem. 2014, 40, 515-522..(43) Li, J. M.; Zhang, X.; Shi, Z. F.; He, K. H. Synthesis, crystal structure, fluorescence, and surface photo-electric properties of a new Co(II) complex based on organosulfonate ligand. Russ. J. Coord. Chem. 2014, 40, 515-522..

    44. [44]

      (44) Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. Göttingen University, Germany 1997.(44) Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. Göttingen University, Germany 1997.

    45. [45]

      (45) Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. Göttingen University, Germany 1997.(45) Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. Göttingen University, Germany 1997.

    46. [46]

      (46) Chen, X. M.; Cai, J. W. Single-crystal Structural Analysis Principles and Practices. The Science Press, Beijing 2003.(46) Chen, X. M.; Cai, J. W. Single-crystal Structural Analysis Principles and Practices. The Science Press, Beijing 2003.

    47. [47]

      (47) Jin, Z. M.; Pan, Y. J.; Li, X. F.; Hu, M. L.; Shen, L. Diazabicyclo[2.2.2]octane-1,4-diium occluded in cubic anionic coordinated framework: the role of trifurcated hydrogen bonds of N-H···O and C-H···O. J. Mol. Struct. 2003, 660, 67-72.(47) Jin, Z. M.; Pan, Y. J.; Li, X. F.; Hu, M. L.; Shen, L. Diazabicyclo[2.2.2]octane-1,4-diium occluded in cubic anionic coordinated framework: the role of trifurcated hydrogen bonds of N-H···O and C-H···O. J. Mol. Struct. 2003, 660, 67-72.

    48. [48]

      (48) Spek, A. L. Single-crystal structure validation with the program platon. J. Appl. Crystallogr. 2003, 36, 7-13.(48) Spek, A. L. Single-crystal structure validation with the program platon. J. Appl. Crystallogr. 2003, 36, 7-13.

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  • 收稿日期:  2015-05-05
  • 网络出版日期:  2015-09-23
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