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Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property

ZHOU Zhong-Yuan ,  XING Xiu-Shuang ,  HAN Yun-Hu ,  TIAN Chong-Bin ,  DU Shao-Wu

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Citation:  ZHOU Zhong-Yuan, XING Xiu-Shuang, HAN Yun-Hu, TIAN Chong-Bin, DU Shao-Wu. Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 119-128. doi: 10.14102/j.cnki.0254-5861.2011-0815 shu

Two Novel Complexes Based on N-N Bridged Ligand: Syntheses, Crystal Structures, Fluorescence and Magnetic Property

  • 1.

    a College of Chemistry, Fuzhou University, Fuzhou 350108, China;

  • 2.

    b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;

  • 3.

    c Graduate University of Chinese Academy of Sciences, Beijing 100039, China

    • 通讯作者: TIAN Chong-Bin,
    DU Shao-Wu,
  • 基金项目:

    This project was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

摘要: Two novel coordination compounds, 1 [Zn4(L1)4(NO3)2(H2O)2](NO3)2·2H2O and 2 [Mn2(L2)2(DMF)(H2O)3](ClO4)2·DMF (HL1 = N'-[(1E)-pyridine-2-ylmethylidene]pyrazine-2- carbohydrazide, H2L2 = 2-hydroxy-3-methoxybenzaldehyde(pyrazin-2-ylcarbonyl)hydrazone), based on the N-N bridged ligands were prepared and structurally characterized. Compound 1 represents the [2*2] molecular squares, in which both N atoms belonging to the N-N bridged ligands are connected to the Zn centers. The emission of compound 1 exhibits a blue shift, which can be assigned to strong electrostatic interaction between ZnII ions and the L1-1. Compound 2 represents a rare phenol-O bridged Mn2II complex. The magnetic investigation indicates weak antiferromagnetic interactions between the MnII centers.

English

  • 
    1. [1]

      (1) Jiang, H. L.; Makal, T. A.; Zhou, H. C. Interpenetration control in metal-organic frameworks for functional applications. Coord. Chem. Rev. 2013, 257, 2232-2249.(1) Jiang, H. L.; Makal, T. A.; Zhou, H. C. Interpenetration control in metal-organic frameworks for functional applications. Coord. Chem. Rev. 2013, 257, 2232-2249.

    2. [2]

      (2) Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815-5840.(2) Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815-5840.

    3. [3]

      (3) Sun, H. L.; Wang, Z. M.; Gao, S. Strategies towards single-chain magnets. Coord. Chem. Rev. 2010, 54, 1081-1100.(3) Sun, H. L.; Wang, Z. M.; Gao, S. Strategies towards single-chain magnets. Coord. Chem. Rev. 2010, 54, 1081-1100.

    4. [4]

      (4) Zhang, H. B.; Lin, P.; Shan, X. C.; Du, F. L.; Li, Q. P.; Du, S. W. An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission. Chem. Commun. 2013, 49, 2231-2233.(4) Zhang, H. B.; Lin, P.; Shan, X. C.; Du, F. L.; Li, Q. P.; Du, S. W. An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission. Chem. Commun. 2013, 49, 2231-2233.

    5. [5]

      (5) Tian, C. B.; Lin, Z. J.; Du, S. W. Three new three-dimensional frameworks based on hepta-, hexa-, and pentanuclear cobalt clusters derived from substituted isophthalic acids: synthesis, structures, and magnetic properties. Cryst. Growth Des. 2013, 13, 3746-3753.(5) Tian, C. B.; Lin, Z. J.; Du, S. W. Three new three-dimensional frameworks based on hepta-, hexa-, and pentanuclear cobalt clusters derived from substituted isophthalic acids: synthesis, structures, and magnetic properties. Cryst. Growth Des. 2013, 13, 3746-3753.

    6. [6]

      (6) Han, Y. H.; Tian, C. B.; Du, S. W. An unusual chiral 3D inorganic connectivity featuring a {Pb18} wheel: rapid and highly selective and sensitive sensing of Co(II). Dalton Trans. 2014, 43, 11461-11464.(6) Han, Y. H.; Tian, C. B.; Du, S. W. An unusual chiral 3D inorganic connectivity featuring a {Pb18} wheel: rapid and highly selective and sensitive sensing of Co(II). Dalton Trans. 2014, 43, 11461-11464.

    7. [7]

      (7) Tian, C. B.; He, C.; Han, Y. H.; Wei, Q.; Li, Q. P.; Lin, P.; Du, S. W. Four new MnII inorganic-organic hybrid frameworks with diverse inorganic magnetic chain's sequences: syntheses, structures, magnetic, NLO, and dielectric properties. Inorg. Chem. 2015, 54, 2560-2571.(7) Tian, C. B.; He, C.; Han, Y. H.; Wei, Q.; Li, Q. P.; Lin, P.; Du, S. W. Four new MnII inorganic-organic hybrid frameworks with diverse inorganic magnetic chain's sequences: syntheses, structures, magnetic, NLO, and dielectric properties. Inorg. Chem. 2015, 54, 2560-2571.

    8. [8]

      (8) Yang, P. P.; Song, X. Y.; Liu, R. N.; Li, L. C.; Liao, D. Z. Syntheses, crystal structures and magnetic properties of a novel family of penta-manganese complexes derived from an assembly system containing polydentate hydroxy-rich Schiff-base ligands. Dalton Trans. 2010, 39, 6285-6294.(8) Yang, P. P.; Song, X. Y.; Liu, R. N.; Li, L. C.; Liao, D. Z. Syntheses, crystal structures and magnetic properties of a novel family of penta-manganese complexes derived from an assembly system containing polydentate hydroxy-rich Schiff-base ligands. Dalton Trans. 2010, 39, 6285-6294.

    9. [9]

      (9) Liu, C. M.; Xiong, R. G.; Zhang, D. Q.; Zhu, D. B. Nanoscale homochiral C3-symmetric mixed-valence manganese cluster complexes with both ferromagnetic and ferroelectric properties. J. Am. Chem. Soc. 2010, 132, 4044-4045.(9) Liu, C. M.; Xiong, R. G.; Zhang, D. Q.; Zhu, D. B. Nanoscale homochiral C3-symmetric mixed-valence manganese cluster complexes with both ferromagnetic and ferroelectric properties. J. Am. Chem. Soc. 2010, 132, 4044-4045.

    10. [10]

      (10) Liu, J. L.; Lin, W. Q.; Chen, Y. C.; Leng, J. D.; Guo, F. S.; Tong, M. L. Symmetry-related [LnIII6MnIII12] clusters toward single-molecule magnets and cryogenic magnetic refrigerants. Inorg. Chem. 2013, 52 457-463.(10) Liu, J. L.; Lin, W. Q.; Chen, Y. C.; Leng, J. D.; Guo, F. S.; Tong, M. L. Symmetry-related [LnIII6MnIII12] clusters toward single-molecule magnets and cryogenic magnetic refrigerants. Inorg. Chem. 2013, 52 457-463.

    11. [11]

      (11) Xu, Z. Q.; Thompson, L. K.; Black, D. A.; Ralph, C.; Miller, D. O.; Leech, M. A.; Howard, J. A. K. N-N bridged dinuclear complexes with Mn(II), Ni(II), Cu(II), Zn(II) and Cd(II); examples with antiferromagnetic and ferromagnetic coupling. J. Chem. Soc. Dalton Trans. 2001, 2042-2048.(11) Xu, Z. Q.; Thompson, L. K.; Black, D. A.; Ralph, C.; Miller, D. O.; Leech, M. A.; Howard, J. A. K. N-N bridged dinuclear complexes with Mn(II), Ni(II), Cu(II), Zn(II) and Cd(II); examples with antiferromagnetic and ferromagnetic coupling. J. Chem. Soc. Dalton Trans. 2001, 2042-2048.

    12. [12]

      (12) Yu, G. M.; Zhao, L.; Guo, Y. N.; Xu, G. F.; Zou, L. F.; Tang, J. K.; Li, Y. H. Synthesis, structures and magnetic properties of di- and tetranuclear manganese complexes derived from a 3-methoxysalicylaldehyde benzoylhydrazide ligand. J. Mol. Struct. 2010, 982, 139-144.(12) Yu, G. M.; Zhao, L.; Guo, Y. N.; Xu, G. F.; Zou, L. F.; Tang, J. K.; Li, Y. H. Synthesis, structures and magnetic properties of di- and tetranuclear manganese complexes derived from a 3-methoxysalicylaldehyde benzoylhydrazide ligand. J. Mol. Struct. 2010, 982, 139-144.

    13. [13]

      (13) Zou, L. F.; Zhao, L.; Chen, P.; Guo, Y. N.; Guo, Y.; Li, Y. H.; Tang, J. K. Phenoxido and alkoxido-bridged dinuclear dysprosium complexes showing single-molecule magnet behavior. Dalton Trans. 2012, 41, 2966-2971.(13) Zou, L. F.; Zhao, L.; Chen, P.; Guo, Y. N.; Guo, Y.; Li, Y. H.; Tang, J. K. Phenoxido and alkoxido-bridged dinuclear dysprosium complexes showing single-molecule magnet behavior. Dalton Trans. 2012, 41, 2966-2971.

    14. [14]

      (14) Lin, S. Y.; Xu, G. F.; Guo, Y. N.; Guo, Y.; Tang, J. K. Observation of slow magnetic relaxation in triple-stranded lanthanide helicates. Dalton Trans. 2011, 40, 8213-8217.(14) Lin, S. Y.; Xu, G. F.; Guo, Y. N.; Guo, Y.; Tang, J. K. Observation of slow magnetic relaxation in triple-stranded lanthanide helicates. Dalton Trans. 2011, 40, 8213-8217.

    15. [15]

      (15) Xue, S. F.; Zhao, L.; Guo, Y. N.; Deng, R. P.; Guo, Y.; Tang, J. K. A series of tetranuclear lanthanide complexes comprising two edge-sharing triangular units with field-induced slow magnetic relaxation for Dy4 species. Dalton Trans. 2011, 40, 8347-8352.(15) Xue, S. F.; Zhao, L.; Guo, Y. N.; Deng, R. P.; Guo, Y.; Tang, J. K. A series of tetranuclear lanthanide complexes comprising two edge-sharing triangular units with field-induced slow magnetic relaxation for Dy4 species. Dalton Trans. 2011, 40, 8347-8352.

    16. [16]

      (16) Zhang, P.; Zhang, L.; Lin, S. Y.; Xue, S. F.; Tang, J. K. Modulating magnetic dynamics of Dy2 system through the coordination geometry and magnetic interaction. Inorg. Chem. 2013, 52, 4587-4592.(16) Zhang, P.; Zhang, L.; Lin, S. Y.; Xue, S. F.; Tang, J. K. Modulating magnetic dynamics of Dy2 system through the coordination geometry and magnetic interaction. Inorg. Chem. 2013, 52, 4587-4592.

    17. [17]

      (17) Guo, Y. N.; Chen, X. H.; Xue, S. F.; Tang, J. K. Modulating magnetic dynamics of three Dy2 complexes through keto-enol tautomerism of the o-vanillin picolinoylhydrazone ligand. Inorg. Chem. 2011, 50, 9705-9713.(17) Guo, Y. N.; Chen, X. H.; Xue, S. F.; Tang, J. K. Modulating magnetic dynamics of three Dy2 complexes through keto-enol tautomerism of the o-vanillin picolinoylhydrazone ligand. Inorg. Chem. 2011, 50, 9705-9713.

    18. [18]

      (18) Zhang, L.; Zhang, P.; Zhao, L.; Lin, S. Y.; Xue, S. F.; Tang, J. K.; Liu, Z. L. Two locally chiral dysprosium compounds with salen-type ligands that show slow magnetic relaxation behavior. Eur. J. Inorg. Chem. 2013, 1351-1357.(18) Zhang, L.; Zhang, P.; Zhao, L.; Lin, S. Y.; Xue, S. F.; Tang, J. K.; Liu, Z. L. Two locally chiral dysprosium compounds with salen-type ligands that show slow magnetic relaxation behavior. Eur. J. Inorg. Chem. 2013, 1351-1357.

    19. [19]

      (19) Mu, Y. Q.; Han, M. L.; Wang, B. H.; Xia, W.; Dong, W. W.; Li, D. S. A co-ligand firstly introduced to 9-fluorenone-2,7-dicarboxylate-based MOF: synthesis, structure and photoluminescent property. Inorg. Chem. Commun. 2014, 46, 259-262.(19) Mu, Y. Q.; Han, M. L.; Wang, B. H.; Xia, W.; Dong, W. W.; Li, D. S. A co-ligand firstly introduced to 9-fluorenone-2,7-dicarboxylate-based MOF: synthesis, structure and photoluminescent property. Inorg. Chem. Commun. 2014, 46, 259-262.

    20. [20]

      (20) Anwar, M. U.; Thompson, L. K.; Dawe, L. N.; Habib, F.; Murugesu, M. Predictable self-assembled [2*2] Ln(III)4 square grids (Ln = Dy, Tb)-SMM behaviour in a new lanthanide cluster motif. Chem. Commun. 2012, 48, 4576-4578.(20) Anwar, M. U.; Thompson, L. K.; Dawe, L. N.; Habib, F.; Murugesu, M. Predictable self-assembled [2*2] Ln(III)4 square grids (Ln = Dy, Tb)-SMM behaviour in a new lanthanide cluster motif. Chem. Commun. 2012, 48, 4576-4578.

    21. [21]

      (21) Xue, S. F.; Zhao, L.; Guo, Y. N.; Tang, J. K. A novel windmill-type DyIII [2 * 2] grid exhibiting slow magnetic relaxation. Dalton Trans. 2012, 41, 351-353.(21) Xue, S. F.; Zhao, L.; Guo, Y. N.; Tang, J. K. A novel windmill-type DyIII [2 * 2] grid exhibiting slow magnetic relaxation. Dalton Trans. 2012, 41, 351-353.

    22. [22]

      (22) Shuvaev, K. V.; Dawe, L. N.; Thompson, L. K. Formation of unusual molecular rectangles and squares containing low spin and high spin Co(II) and Fe(II) centers. Dalton Trans. 2010, 39, 4768-4776.(22) Shuvaev, K. V.; Dawe, L. N.; Thompson, L. K. Formation of unusual molecular rectangles and squares containing low spin and high spin Co(II) and Fe(II) centers. Dalton Trans. 2010, 39, 4768-4776.

    23. [23]

      (23) Sutradhar, M.; Martins, L. M. D. R. S.; Silva, M. F. G.; Alegria, E. C. B. A.; Liu, C. M.; Pombeiro, A. J. L. Dinuclear Mn(II, II) complexes: magnetic properties and microwave assisted oxidation of alcohols. Dalton Trans. 2014, 43, 3966-3977.(23) Sutradhar, M.; Martins, L. M. D. R. S.; Silva, M. F. G.; Alegria, E. C. B. A.; Liu, C. M.; Pombeiro, A. J. L. Dinuclear Mn(II, II) complexes: magnetic properties and microwave assisted oxidation of alcohols. Dalton Trans. 2014, 43, 3966-3977.

    24. [24]

      (24) Lu, Z. L.; Yuan, M.; Pan, F.; Gao, S.; Zhang, D. Q.; Zhu, D. B. Syntheses, crystal structures and magnetic characterization of five new dimeric manganese(III) tetradentate schiff base complexes exhibiting single-molecule-magnet behavior. Inorg. Chem. 2006, 45, 3538-3548.(24) Lu, Z. L.; Yuan, M.; Pan, F.; Gao, S.; Zhang, D. Q.; Zhu, D. B. Syntheses, crystal structures and magnetic characterization of five new dimeric manganese(III) tetradentate schiff base complexes exhibiting single-molecule-magnet behavior. Inorg. Chem. 2006, 45, 3538-3548.

    25. [25]

      (25) Sailaja, S.; Reddy, K. R.; Rajasekharan, M. V.; Hureau, C.; Riviere, E.; Cano, J.; Girerd, J. J. Synthesis, structure, and magnetic properties of [MnIII(salpn)NCS]n, a helical polymer, and the dimer [MnIII(salpn)NCS]2. weak ferromagnetism in [MnIII(salpn)NCS]n related to the strong magnetic anisotropy in Jahn-Teller Mn(III) (salpnH2) N,N'-bis(salicylidene)-1,3-diaminopropane). Inorg. Chem. 2003, 42, 180-186.(25) Sailaja, S.; Reddy, K. R.; Rajasekharan, M. V.; Hureau, C.; Riviere, E.; Cano, J.; Girerd, J. J. Synthesis, structure, and magnetic properties of [MnIII(salpn)NCS]n, a helical polymer, and the dimer [MnIII(salpn)NCS]2. weak ferromagnetism in [MnIII(salpn)NCS]n related to the strong magnetic anisotropy in Jahn-Teller Mn(III) (salpnH2) N,N'-bis(salicylidene)-1,3-diaminopropane). Inorg. Chem. 2003, 42, 180-186.

    26. [26]

      (26) Kachi-Terajima, C.; Miyasaka, H.; Sugiura, K.; Clerac, R.; Nojiri, H. From an ST = 3 single-molecule magnet to diamagnetic ground state depending on the molecular packing of MnIII salen-type dimers decorated by N,N'-dicyano-1,4-naphthoquinonediiminate radicals. Inorg. Chem. 2006, 45, 4381-4390.(26) Kachi-Terajima, C.; Miyasaka, H.; Sugiura, K.; Clerac, R.; Nojiri, H. From an ST = 3 single-molecule magnet to diamagnetic ground state depending on the molecular packing of MnIII salen-type dimers decorated by N,N'-dicyano-1,4-naphthoquinonediiminate radicals. Inorg. Chem. 2006, 45, 4381-4390.

    27. [27]

      (27) Koval, I. A.; Huisman, M.; Stassen, A. F.; Gamez, P.; Lutz, M.; Spek, A. L.; Pursche, D.; Krebs, B.; Reedijk, J. New dinuclear Co(II) and Mn(II) complexes of the phenol-based compartmental ligand containing formyl and amine functions: structural, spectroscopic and magnetic properties. Inorg. Chim. Acta 2004, 357, 294-300.(27) Koval, I. A.; Huisman, M.; Stassen, A. F.; Gamez, P.; Lutz, M.; Spek, A. L.; Pursche, D.; Krebs, B.; Reedijk, J. New dinuclear Co(II) and Mn(II) complexes of the phenol-based compartmental ligand containing formyl and amine functions: structural, spectroscopic and magnetic properties. Inorg. Chim. Acta 2004, 357, 294-300.

    28. [28]

      (28) Preda, A. M.; Silvestru, A.; Farcas, S.; Bienko, A.; Mrozinski, J.; Andruh, M. New manganese(II) complexes with tetraorganodichalcogenoimidodiphosphinato ligands. Crystal and molecular structure of monomeric Mn[(SPMe2)(SPPh2)N]2 and dimeric [Mn{(OPPh2){OP(OEt)2}N}2(H2O)]2. Polyhedron 2008, 27, 2905-2910.(28) Preda, A. M.; Silvestru, A.; Farcas, S.; Bienko, A.; Mrozinski, J.; Andruh, M. New manganese(II) complexes with tetraorganodichalcogenoimidodiphosphinato ligands. Crystal and molecular structure of monomeric Mn[(SPMe2)(SPPh2)N]2 and dimeric [Mn{(OPPh2){OP(OEt)2}N}2(H2O)]2. Polyhedron 2008, 27, 2905-2910.

    29. [29]

      (29) Qian, M.; Gou, S. H.; Yu, Z.; Ju, H. X.; Xu, Y.; Duan, C. Y.; You, X. Z. Synthesis, crystal structure and properties of a macrocyclic dinuclear manganese(II) complex with functional o-methylenephenolic pendant arms. Inorg. Chim. Acta 2001, 317, 157-162.(29) Qian, M.; Gou, S. H.; Yu, Z.; Ju, H. X.; Xu, Y.; Duan, C. Y.; You, X. Z. Synthesis, crystal structure and properties of a macrocyclic dinuclear manganese(II) complex with functional o-methylenephenolic pendant arms. Inorg. Chim. Acta 2001, 317, 157-162.

    30. [30]

      (30) Gomez, V.; Corbella, M. Versatility in the coordination modes of n-chlorobenzoato ligands: synthesis, structure and magnetic properties of three types of polynuclear MnII compounds. Eur. J. Inorg. Chem. 2009, 4471-4482.(30) Gomez, V.; Corbella, M. Versatility in the coordination modes of n-chlorobenzoato ligands: synthesis, structure and magnetic properties of three types of polynuclear MnII compounds. Eur. J. Inorg. Chem. 2009, 4471-4482.

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  • 收稿日期:  2015-05-21
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