Syntheses, Structures and Properties of Two New Coordination Polymers with Flexible Ligands as Linkers

YAO Hua-Gang LU Xiu-Xia ZHENG Jia-Xin XIAO Yong-Le LIN Huan-Jie CAI Wei-Yi

Citation:  YAO Hua-Gang, LU Xiu-Xia, ZHENG Jia-Xin, XIAO Yong-Le, LIN Huan-Jie, CAI Wei-Yi. Syntheses, Structures and Properties of Two New Coordination Polymers with Flexible Ligands as Linkers[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 107-113. doi: 10.14102/j.cnki.0254-5861.2011-0806 shu

Syntheses, Structures and Properties of Two New Coordination Polymers with Flexible Ligands as Linkers

    通讯作者: YAO Hua-Gang,
  • 基金项目:

    Supported by the National Natural Science Foundation of China (No. 21301035) (No. 21301035)

摘要: Two new coordination polymers, [ZnL1]n (1, H2L1 = 5-(4-pyridyl)-methoxyl iso- phthalic acid) and [Ni(L2)2(H2O)4]n (2, HL2 = 4-(pyridin-4-ylmethoxy)benzolic acid), have been synthesized and characterized by elemental analysis, PXRD, IR spectra, and single-crystal X-ray diffraction. Compound 1 has a three-dimensional framework constructed by 6-bridged L12- anions connecting the Zn2(O2C)4 paddlewheel-like units. Compound 2 contains a mononuclear molecular unit, and the central nickel atom adopts a slightly distorted octahedral geometry by two nitrogen atoms from different L2- ligands and four oxygen atoms from water molecules. These molecular units link each other via four types of O-H…O hydrogen bonds to form an extended three-dimen- sional (3D) supramolecular network. The thermal and photoluminescent properties of 1 and 2 have also been investigated.

English

  • 
    1. [1]

      (1) Ferey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F. Crystallized frameworks with giant pores: are there limits to the possible? Acc. Chem. Res. 2005, 38, 217-225.(1) Ferey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F. Crystallized frameworks with giant pores: are there limits to the possible? Acc. Chem. Res. 2005, 38, 217-225.

    2. [2]

      (2) Robin, A. Y.; Fromm, K. M. Coordination polymer networks with O- and N-donors: what they are, why and how they are made. Coord. Chem. Rev. 2006, 250, 2127-2157.(2) Robin, A. Y.; Fromm, K. M. Coordination polymer networks with O- and N-donors: what they are, why and how they are made. Coord. Chem. Rev. 2006, 250, 2127-2157.

    3. [3]

      (3) Cook, T. R.; Zheng, Y. R.; Stang, P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials. Chem. Rev. 2013, 113, 734-777.(3) Cook, T. R.; Zheng, Y. R.; Stang, P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials. Chem. Rev. 2013, 113, 734-777.

    4. [4]

      (4) Sun, X. W.; You, J. M.; Xu, X. H.; Li, X. J. A Zn(II) metal-organic framework consisting of hexagonal cavities constructed by benzyl-functionalized 5-aminoisophthalate. Chin. J. Struct. Chem. 2015, 4, 562-568.(4) Sun, X. W.; You, J. M.; Xu, X. H.; Li, X. J. A Zn(II) metal-organic framework consisting of hexagonal cavities constructed by benzyl-functionalized 5-aminoisophthalate. Chin. J. Struct. Chem. 2015, 4, 562-568.

    5. [5]

      (5) Tian, Z. F.; Lin, J. G.; Su, Y.; Wen, L. L.; Liu, Y. M.; Zhu, H. Z.; Meng, Q. J. Flexible ligand, structural, and topological diversity: isomerism in Zn(NO3)2 coordination polymers. Cryst. Growth Des. 2007, 7, 1863-1867.(5) Tian, Z. F.; Lin, J. G.; Su, Y.; Wen, L. L.; Liu, Y. M.; Zhu, H. Z.; Meng, Q. J. Flexible ligand, structural, and topological diversity: isomerism in Zn(NO3)2 coordination polymers. Cryst. Growth Des. 2007, 7, 1863-1867.

    6. [6]

      (6) Chen, B.; Xiang, S.; Qin, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.(6) Chen, B.; Xiang, S.; Qin, G. Metal-organic frameworks with functional pores for recognition of small molecules. Acc. Chem. Res. 2010, 43, 1115-1124.

    7. [7]

      (7) Eubank, J. F.; Wojtas, L.; Hight, M. R.; Bousquet, T.; Kravtsov, V. C.; Eddaoudi, M. The next chapter in MOF pillaring strategies: trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms. J. Am. Chem. Soc. 2011, 133, 17532-17535.(7) Eubank, J. F.; Wojtas, L.; Hight, M. R.; Bousquet, T.; Kravtsov, V. C.; Eddaoudi, M. The next chapter in MOF pillaring strategies: trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms. J. Am. Chem. Soc. 2011, 133, 17532-17535.

    8. [8]

      (8) Li, L. J.; Chen, L.; Du, D. Y.; Wang, X. L.; Shao, K. Z.; Su, Z. M. Synthesis and luminescent properties of two zinc(II) coordination polymers constructed by 4-(pyridin-4-ylmethoxy)benzolic acid ligand. Z. Anorg. Allg. Chem. 2011, 637, 1419-1422.(8) Li, L. J.; Chen, L.; Du, D. Y.; Wang, X. L.; Shao, K. Z.; Su, Z. M. Synthesis and luminescent properties of two zinc(II) coordination polymers constructed by 4-(pyridin-4-ylmethoxy)benzolic acid ligand. Z. Anorg. Allg. Chem. 2011, 637, 1419-1422.

    9. [9]

      (9) Qi, L.; Hu, J. S.; Huang, L. F.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Syntheses, characterizations, and properties of six metal-organic complexes based on flexible ligand 5-(4-pyridyl)-methoxyl isophthalic acid. Cryst. Growth Des. 2010, 10, 4176-4183.(9) Qi, L.; Hu, J. S.; Huang, L. F.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Syntheses, characterizations, and properties of six metal-organic complexes based on flexible ligand 5-(4-pyridyl)-methoxyl isophthalic acid. Cryst. Growth Des. 2010, 10, 4176-4183.

    10. [10]

      (10) Zhang, X.; Huang, Y. Y.; Yao, Y. G. Unusual pillar-layer framework of a heterometallic dysprosium(III)-silver(I) coordination polymer with (3,4,5)-connected topology. Inorg. Chem. Commun. 2013, 28, 49-51.(10) Zhang, X.; Huang, Y. Y.; Yao, Y. G. Unusual pillar-layer framework of a heterometallic dysprosium(III)-silver(I) coordination polymer with (3,4,5)-connected topology. Inorg. Chem. Commun. 2013, 28, 49-51.

    11. [11]

      (11) Tao, Z. L.; Qi, L.; Zheng, H. G. Syntheses, crystal structures and properties of two metal-organic complexes based on 5-(4-pyridyl)-methoxyl isophthalic acid. Chin. J. Struct. Chem. 2013, 32, 1067-1075.(11) Tao, Z. L.; Qi, L.; Zheng, H. G. Syntheses, crystal structures and properties of two metal-organic complexes based on 5-(4-pyridyl)-methoxyl isophthalic acid. Chin. J. Struct. Chem. 2013, 32, 1067-1075.

    12. [12]

      (12) Xu, G. J.; Zhao, Y. H.; Shao, K. Z.; Lan, Y. Q.; Wang, X. L.; Su, Z. M.; Yan, L. K. Three novel 3D (3,8)-connected metal-organic frameworks constructed from flexible-rigid mixed ligands. CrystEngComm. 2009, 11, 1842-1848.(12) Xu, G. J.; Zhao, Y. H.; Shao, K. Z.; Lan, Y. Q.; Wang, X. L.; Su, Z. M.; Yan, L. K. Three novel 3D (3,8)-connected metal-organic frameworks constructed from flexible-rigid mixed ligands. CrystEngComm. 2009, 11, 1842-1848.

    13. [13]

      (13) Ashiry, K. O.; Zhao, Y. H.; Shao, K. Z.; Su, Z. M.; Xu, G. J. Synthesis and characterization of three coordination polymers based on dipyridylbenzoates and 1,4-bezenedicarboxylate. Polyhedron 2009, 28, 975-979.(13) Ashiry, K. O.; Zhao, Y. H.; Shao, K. Z.; Su, Z. M.; Xu, G. J. Synthesis and characterization of three coordination polymers based on dipyridylbenzoates and 1,4-bezenedicarboxylate. Polyhedron 2009, 28, 975-979.

    14. [14]

      (14) Bruker. SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA 2007.(14) Bruker. SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA 2007.

    15. [15]

      (15) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area Detector Data. University of Göttingen, Germany 1996.(15) Sheldrick, G. M. SADABS, A Program for Empirical Absorption Correction of Area Detector Data. University of Göttingen, Germany 1996.

    16. [16]

      (16) Sheldrick, G. M. A short history of SHELX. Acta Cryst. 2008, A64, 112-122.(16) Sheldrick, G. M. A short history of SHELX. Acta Cryst. 2008, A64, 112-122.

    17. [17]

      (17) Li, X. M.; Wang, Q. W.; Liu, B. Synthesis and crystal structure of a zinc(II) complex with 2-(4'-chlorine-benzoyl)-benzoic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 2011, 30, 1646-1649.(17) Li, X. M.; Wang, Q. W.; Liu, B. Synthesis and crystal structure of a zinc(II) complex with 2-(4'-chlorine-benzoyl)-benzoic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 2011, 30, 1646-1649.

    18. [18]

      (18) Ma, B. Q.; Mulfort, K. L.; Hupp, J. T. Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions. Inorg. Chem. 2005, 44, 4912-4914.(18) Ma, B. Q.; Mulfort, K. L.; Hupp, J. T. Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions. Inorg. Chem. 2005, 44, 4912-4914.

    19. [19]

      (19) Blatov, V. A. TOPOS, A Multipurpose Crystallochemical Analysis with the Program Package. Samara State University, Samara, Russian Federation 2004.(19) Blatov, V. A. TOPOS, A Multipurpose Crystallochemical Analysis with the Program Package. Samara State University, Samara, Russian Federation 2004.

    20. [20]

      (20) Zhang, X.; Cheng, J. K.; Chen, F.; Sun, M. L.; Yao, Y. G. Isomeric photoluminescent lead(II) coordination polymers based on designed pyridinecarboxylate ligands. Inorg. Chem. Commun. 2011, 14, 358-361.(20) Zhang, X.; Cheng, J. K.; Chen, F.; Sun, M. L.; Yao, Y. G. Isomeric photoluminescent lead(II) coordination polymers based on designed pyridinecarboxylate ligands. Inorg. Chem. Commun. 2011, 14, 358-361.

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  • 收稿日期:  2015-05-11
  • 网络出版日期:  2015-08-12
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