Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

FAN Guang DENG Ling-Juan MA Zhan-Ying LI Xiao-Bo ZHANG Yin-Li SUN Jia-Juan

Citation:  FAN Guang, DENG Ling-Juan, MA Zhan-Ying, LI Xiao-Bo, ZHANG Yin-Li, SUN Jia-Juan. Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 100-106. doi: 10.14102/j.cnki.0254-5861.2011-0804 shu

Thiocyanate-controlled Copper(II)-L-arginine Complex: Synthesis, Crystal Structure and Characterization

  • 基金项目:

    Supported by the National Natural Science Foundation of China (No. 21203160) (No. 21203160)

    Education Department Foundation of Shaanxi Province (No. 12JK0631) (No. 12JK0631)

    Natural Science Foundation of Shaanxi Province (No. 2013JM2013) (No. 2013JM2013)

    Special Research Fund of Xianyang Normal University (No. 11XSYK204, 11XSYK205) (No. 11XSYK204, 11XSYK205)

摘要: A novel thiocyanate-controlled copper(II)-L-arginine complex with the formula of Cu(Arg)(SCN)2 (1, Arg: L-arginine) has been obtained from aqueous solution and structurally characterized by single-crystal X-ray diffraction method. Crystal data: orthorhombic, space group P212121, a = 6.0156(5), b = 12.1905(11), c = 18.4203(16) Å, V = 1350.8(2) Å3, Z = 4, μ = 1.933 mm-1, F(000) = 724, S = 1.084, the final R = 0.0410, wR = 0.0754 for 1893 observed reflections with I > 2σ(I), and R = 0.0559, wR = 0.0820 for all reflections. In addition, elemental analysis, IR, TG-DTG and magnetism characterization are presented.

English

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  • 收稿日期:  2015-05-11
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