Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid

LIN Xiao-Ying YANG Pan CHEN Jun LIU Ming-Hua LIN Cheng

Citation:  LIN Xiao-Ying, YANG Pan, CHEN Jun, LIU Ming-Hua, LIN Cheng. Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 61-68. doi: 10.14102/j.cnki.0254-5861.2011-0948 shu

Solvothermal Synthesis, Crystal Structure and Photoluminescence Property of a 3D Lead(II) Coordination Polymer Based on Terephthalic Acid

  • 基金项目:

    This work was supported by the Natural Science Foundation of Fujian province (2015J01033)  (2015J01033)

    Technology of Fujian Province (2012H6002) (2012H6002)

摘要: Solvothermal reaction of Pb(NO3)2·6H2O with rigid linear ligand terephthalic acid (H2pta) in N,N-dimethylformamide (DMF) produced a new three-dimensional (3D) lead(II) coordination polymer [Pb2(pta)1.5(μ4-OH)(DMF)]n 1, and its structure was characterized by single-crystal X-ray diffraction analyses. In polymer 1, the μ4-OH bridges the nearby lead(II) ions into an infinite one-dimensional (1D) chain, and then the organic ligand pta2- joins the neighbored chains into a 3D structure by two similar connection modes in different configurations. The solid-state photoluminescent studies revealed that 1 exhibits a strong greenish emission mainly originating from ligand-to-metal charge transfer between the delocalized π bonds of the aromatic carboxylate ligand pta2- and the p orbitals of the Pb2+ centers.

English

  • 
    1. [1]

      (1) Li, N. Y.; Ma, W.; Wang, S. J.; Liu, D. Effect of substituent carboxylic group on the self-assembly of cadmium coordination polymers: syntheses, topological analyses and photoluminescence properties. Inorg. Chem. Commun. 2015, 58, 1-4.(1) Li, N. Y.; Ma, W.; Wang, S. J.; Liu, D. Effect of substituent carboxylic group on the self-assembly of cadmium coordination polymers: syntheses, topological analyses and photoluminescence properties. Inorg. Chem. Commun. 2015, 58, 1-4.

    2. [2]

      (2) Du, P.; Yu, J. S. Photoluminescence and cathodoluminescence properties of Eu3+ ions activated AMoO4 (A = Mg, Ca, Sr, Ba)(2) Du, P.; Yu, J. S. Photoluminescence and cathodoluminescence properties of Eu3+ ions activated AMoO4 (A = Mg, Ca, Sr, Ba)

    3. [3]

      phosphors. Mater. Res. Bull. 2015, 70, 553-558.phosphors. Mater. Res. Bull. 2015, 70, 553-558.

    4. [4]

      (3) Dalal, M.; Taxak, V. B.; Lohra, S.; Sangwan, D.; Khatkar, S. P. Photoluminescence and structural properties of Eu3+ doped SrZnV2O7 nanocrystals.(3) Dalal, M.; Taxak, V. B.; Lohra, S.; Sangwan, D.; Khatkar, S. P. Photoluminescence and structural properties of Eu3+ doped SrZnV2O7 nanocrystals.

    5. [5]

      J. Lumin. 2015, 161, 63-70.J. Lumin. 2015, 161, 63-70.

    6. [6]

      (4) Liu, S. Q.; Liang, Y. J.; Tong, M. H.; Yu, D. Y.; Zhu, Y. L.; Wu, X. Y.; Yan, C. J. Photoluminescence properties of novel white phosphor of(4) Liu, S. Q.; Liang, Y. J.; Tong, M. H.; Yu, D. Y.; Zhu, Y. L.; Wu, X. Y.; Yan, C. J. Photoluminescence properties of novel white phosphor of

    7. [7]

      Dy3+-doped LaBSiO5 glass. Mat. Sci. Semicon. Proc. 2015, 38, 266-270.Dy3+-doped LaBSiO5 glass. Mat. Sci. Semicon. Proc. 2015, 38, 266-270.

    8. [8]

      (5) Chékir-Mzali, J.; Horchani-Naifer, K.; Férid, M. Synthesis of Er3+-doped Na3La(PO4)2 micro-powders and photoluminescence(5) Chékir-Mzali, J.; Horchani-Naifer, K.; Férid, M. Synthesis of Er3+-doped Na3La(PO4)2 micro-powders and photoluminescence

    9. [9]

      properties. Superlattice Microst. 2015, 85, 445-453.properties. Superlattice Microst. 2015, 85, 445-453.

    10. [10]

      (6) Zhu, D. Y.; Mu, Z. H. Synthesis of Sm3+ and Dy3+ doped LaBWO6 for evaluation as potential materials in luminescent display(6) Zhu, D. Y.; Mu, Z. H. Synthesis of Sm3+ and Dy3+ doped LaBWO6 for evaluation as potential materials in luminescent display

    11. [11]

      applications. Displays 2014, 35, 261-265.applications. Displays 2014, 35, 261-265.

    12. [12]

      (7) Huang, Y. L.; Seo, H. J. A novel red-emitting nano-phosphor of Eu3+-doped LaBWO6. Mater. Lett. 2012, 84, 107-109.(7) Huang, Y. L.; Seo, H. J. A novel red-emitting nano-phosphor of Eu3+-doped LaBWO6. Mater. Lett. 2012, 84, 107-109.

    13. [13]

      (8) Dabre, K. V.; Par, K. K.; Dhoble, S. J. Synthesis and photoluminescence properties of microcrystalline Sr2ZnWO6:RE3+ (RE = Eu, Dy,(8) Dabre, K. V.; Par, K. K.; Dhoble, S. J. Synthesis and photoluminescence properties of microcrystalline Sr2ZnWO6:RE3+ (RE = Eu, Dy,

    14. [14]

      Sm and Pr) phosphors. Alloy. Compd. 2014, 617, 129-134.Sm and Pr) phosphors. Alloy. Compd. 2014, 617, 129-134.

    15. [15]

      (9) Shen, X.; Yan, B. Photofunctional hybrids of lanthanide functionalized bio-MOF-1 for fluorescence tuning and sensing. Colloid. (9) Shen, X.; Yan, B. Photofunctional hybrids of lanthanide functionalized bio-MOF-1 for fluorescence tuning and sensing. Colloid.

    16. [16]

      Interf. Sci. 2015, 451, 63-68.Interf. Sci. 2015, 451, 63-68.

    17. [17]

      (10) Liu, Y. F.; Feng, J.; Zhang, Y. F.; Cui, H. F.; Yin, D.; Bi, Y. G.; Song, J. F.; Chen, Q. D.; Sun, H. B. Improved efficiency of indium-tin-oxide-free(10) Liu, Y. F.; Feng, J.; Zhang, Y. F.; Cui, H. F.; Yin, D.; Bi, Y. G.; Song, J. F.; Chen, Q. D.; Sun, H. B. Improved efficiency of indium-tin-oxide-free

    18. [18]

      organic light-emitting devices using PEDOT:PSS/graphene oxide composite anode. Org. Electron. 2015, 26, 81-85.organic light-emitting devices using PEDOT:PSS/graphene oxide composite anode. Org. Electron. 2015, 26, 81-85.

    19. [19]

      (11) Liao, J. K.; Tang, X. G.; Gao, Y.; Wan, W. J.; Zhang, X. X.; Liu, Y.; Liu, Y. Z. Polarization dispersion characteristics analysis of optical rib(11) Liao, J. K.; Tang, X. G.; Gao, Y.; Wan, W. J.; Zhang, X. X.; Liu, Y.; Liu, Y. Z. Polarization dispersion characteristics analysis of optical rib

    20. [20]

      waveguides in organic/polymer photonic devices. Opt. Commun. 2015, 350, 241-247.waveguides in organic/polymer photonic devices. Opt. Commun. 2015, 350, 241-247.

    21. [21]

      (12) Wang, Z. F.; Wang, Y. H.; Li, Y. Z.; Liu, B. T. Enhanced photoluminescence of BaMgAl10O17:Eu2+ nanophosphor for PDP application. (12) Wang, Z. F.; Wang, Y. H.; Li, Y. Z.; Liu, B. T. Enhanced photoluminescence of BaMgAl10O17:Eu2+ nanophosphor for PDP application.

    22. [22]

      Alloy. Compd. 2011, 509, 343-346.Alloy. Compd. 2011, 509, 343-346.

    23. [23]

      (13) Sen, K.; Samaddar, P. Organized polyvinyl alcohol assemblies: eligible luminescent centers for species dependent metal sensing. J. (13) Sen, K.; Samaddar, P. Organized polyvinyl alcohol assemblies: eligible luminescent centers for species dependent metal sensing. J.

    24. [24]

      2014, 200, 369-373.2014, 200, 369-373.

    25. [25]

      (14) Santra, A.; Bharadwaj, P. K. Solvent-induced structural diversity of partially fluorinated, stable Pb(II) metal-organic(14) Santra, A.; Bharadwaj, P. K. Solvent-induced structural diversity of partially fluorinated, stable Pb(II) metal-organic

    26. [26]

      and their luminescence properties. Cryst. Growth Des. 2014, 14, 1476-1485.and their luminescence properties. Cryst. Growth Des. 2014, 14, 1476-1485.

    27. [27]

      (15) Rachuri, Y.; Bisht, K. K.; Parmar, B.; Suresh, E. Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for(15) Rachuri, Y.; Bisht, K. K.; Parmar, B.; Suresh, E. Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for

    28. [28]

      selective detection of organic nitro compounds and iodine capture. Solid State Chem. 2015, 223, 23-31.selective detection of organic nitro compounds and iodine capture. Solid State Chem. 2015, 223, 23-31.

    29. [29]

      (16) Zhao, Y. H.; Xu, H. B.; Fu, Y. M.; Shao, K. Z.; Yang, S. Y.; Su, Z. M.; Hao, X. R.; Zhu, D. X.; Wang, E. B. A series of lead(II)-organic frameworks(16) Zhao, Y. H.; Xu, H. B.; Fu, Y. M.; Shao, K. Z.; Yang, S. Y.; Su, Z. M.; Hao, X. R.; Zhu, D. X.; Wang, E. B. A series of lead(II)-organic frameworks

    30. [30]

      based on pyridyl acid derivatives: syntheses, structures, and luminescent properties. Cryst. Growth Des. 2008, 8, 3566-3576.based on pyridyl acid derivatives: syntheses, structures, and luminescent properties. Cryst. Growth Des. 2008, 8, 3566-3576.

    31. [31]

      (17) Lin, J. D.; Wu, S. T.; Li, Z. H.; Du, S. W. A series of novel Pb(II) or Pb(II)/M(II) (M = Ca and Sr) hybrid inorganic-organic frameworks based on(17) Lin, J. D.; Wu, S. T.; Li, Z. H.; Du, S. W. A series of novel Pb(II) or Pb(II)/M(II) (M = Ca and Sr) hybrid inorganic-organic frameworks based on

    32. [32]

      acids with diverse Pb-O-M (M = Pb, Ca and Sr) inorganic connectivities. CrystEngComm. 2010, 12, 4252-4262acids with diverse Pb-O-M (M = Pb, Ca and Sr) inorganic connectivities. CrystEngComm. 2010, 12, 4252-4262

    33. [33]

      (18) Tang, Q.; Liu, S. X.; Liu, Y. W.; He, D. F.; Miao, J.; Wang, X. Q.; Ji, Y. J.; Zheng, Z. P. Color tuning and white light emission via in situ(18) Tang, Q.; Liu, S. X.; Liu, Y. W.; He, D. F.; Miao, J.; Wang, X. Q.; Ji, Y. J.; Zheng, Z. P. Color tuning and white light emission via in situ

    34. [34]

      doping of luminescent lanthanide metal-organic frameworks. Inorg. Chem. 2014, 53, 289-293.doping of luminescent lanthanide metal-organic frameworks. Inorg. Chem. 2014, 53, 289-293.

    35. [35]

      (19) Jin, Y. H.; Hu, Y. H.; Chen, L.; Wang, X. J.; Mu, Z. F.; Ju, G. F.; Yang, Z. F. A novel emitting color tunable phosphor Ba3Gd(PO4)3: Ce3+, Tb3+(19) Jin, Y. H.; Hu, Y. H.; Chen, L.; Wang, X. J.; Mu, Z. F.; Ju, G. F.; Yang, Z. F. A novel emitting color tunable phosphor Ba3Gd(PO4)3: Ce3+, Tb3+

    36. [36]

      based on energy transfer. J. Physica B: Condensed Matter. 2014, 436, 105-110.based on energy transfer. J. Physica B: Condensed Matter. 2014, 436, 105-110.

    37. [37]

      (20) Vallejos, J.; Brito, I.; Cárdenas, A.; Bolte, M.; Llanos, J.; López-Rodríguez, M.; Lavín, V.; Martín, I. R. A direct white-light-(20) Vallejos, J.; Brito, I.; Cárdenas, A.; Bolte, M.; Llanos, J.; López-Rodríguez, M.; Lavín, V.; Martín, I. R. A direct white-light-

    38. [38]

      emitting coordination polymers with tunable green-white photoluminescence by variation of counterion. Inorg. Chem. emitting coordination polymers with tunable green-white photoluminescence by variation of counterion. Inorg. Chem.

    39. [39]

      Commun. 2014, 39, 14-20.Commun. 2014, 39, 14-20.

    40. [40]

      (21) Xu, C. J.; Wan, J. T.; Li, B. C. Monochromatic light-emitting copolymer of methyl methacrylate and Eu-complexed 5-acrylamido-1,10-(21) Xu, C. J.; Wan, J. T.; Li, B. C. Monochromatic light-emitting copolymer of methyl methacrylate and Eu-complexed 5-acrylamido-1,10-

    41. [41]

      phenanthroline. Dyes Pigments. 2013, 98, 493-498.phenanthroline. Dyes Pigments. 2013, 98, 493-498.

    42. [42]

      (22) Rachuri, Y.; Bisht, K. K.; Parmar, B.; Suresh, E. Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for(22) Rachuri, Y.; Bisht, K. K.; Parmar, B.; Suresh, E. Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for

    43. [43]

      selective detection of organic nitro compounds and iodine capture. Sold State Chem. 2015, 223, 23-31.selective detection of organic nitro compounds and iodine capture. Sold State Chem. 2015, 223, 23-31.

    44. [44]

      (23) Wang, M.; Huang, R. Y.; Wang, Z. Q.; Wu, G. H. Solvent-dependent luminescence behavior of a new charge-transfer Cu(I)-MOF: an(23) Wang, M.; Huang, R. Y.; Wang, Z. Q.; Wu, G. H. Solvent-dependent luminescence behavior of a new charge-transfer Cu(I)-MOF: an

    45. [45]

      experimental and theoretical investigation. Inorg. Chem. Commun. 2015, 56, 41-44.experimental and theoretical investigation. Inorg. Chem. Commun. 2015, 56, 41-44.

    46. [46]

      (24) Li, J.; Yang, G. P.; Hou, L.; Cui, L.; Li., Y. P.; Wang, Y. Y.; Shi, Q. Z. Three new solvent-directed 3D lead(II)-MOFs displaying the unique(24) Li, J.; Yang, G. P.; Hou, L.; Cui, L.; Li., Y. P.; Wang, Y. Y.; Shi, Q. Z. Three new solvent-directed 3D lead(II)-MOFs displaying the unique

    47. [47]

      properties of luminescence and selective CO2 sorption. J. Dalton. 2013, 42, 13590-13598.properties of luminescence and selective CO2 sorption. J. Dalton. 2013, 42, 13590-13598.

    48. [48]

      (25) Sun, J. Y.; Zhang, D. J.; Wang, L.; Cao, Y.; Li, D.; Zhang, L Y.; Song, W.; Fan, Y.; Xu, J. N. Two novel lead(II)-tetrazolate frameworks(25) Sun, J. Y.; Zhang, D. J.; Wang, L.; Cao, Y.; Li, D.; Zhang, L Y.; Song, W.; Fan, Y.; Xu, J. N. Two novel lead(II)-tetrazolate frameworks

    49. [49]

      based on cubane [Pb4(OH)4]4+ clusters trapping long lifetime luminescence emission. CrystEngComm. 2012, 14, 3982-3988.based on cubane [Pb4(OH)4]4+ clusters trapping long lifetime luminescence emission. CrystEngComm. 2012, 14, 3982-3988.

    50. [50]

      (26) Li, Z. P.; Xing, Y. H.; Wang, C. G.; Li, J.; Zeng, X. Q.; Ge, M. F.; Niu, S. Y. A new coordination polymer [Pb(1,4-BDC)]n containing a unique(26) Li, Z. P.; Xing, Y. H.; Wang, C. G.; Li, J.; Zeng, X. Q.; Ge, M. F.; Niu, S. Y. A new coordination polymer [Pb(1,4-BDC)]n containing a unique

    51. [51]

      μ6-bridging coordination mode. Z. Anorg. Allg. Chem. 2009, 635, 1650-1653.μ6-bridging coordination mode. Z. Anorg. Allg. Chem. 2009, 635, 1650-1653.

    52. [52]

      (27) CrystalClear, version 1.35.; Software User's Guide for the Rigaku R-Axis and Mercury and Jupiter CCD Automated X-ray Imaging(27) CrystalClear, version 1.35.; Software User's Guide for the Rigaku R-Axis and Mercury and Jupiter CCD Automated X-ray Imaging

    53. [53]

      System.; Rigaku Molecular Structure Corporation: UT 2002.System.; Rigaku Molecular Structure Corporation: UT 2002.

    54. [54]

      (28) (a) Sheldrick, G. M. SHELXS-97, Program for Structure Refinement. University of Göttingen: Germany 1997;(28) (a) Sheldrick, G. M. SHELXS-97, Program for Structure Refinement. University of Göttingen: Germany 1997;

    55. [55]

      (b) Sheldrick, G. M. SHELXL-97, Program for Structure Solution. University of Göttingen: Germany 1997.(b) Sheldrick, G. M. SHELXL-97, Program for Structure Solution. University of Göttingen: Germany 1997.

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  1042
  • HTML全文浏览量:  44
文章相关
  • 收稿日期:  2015-08-18
  • 网络出版日期:  2015-10-18
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章