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Non-covalent Bonded 3D Supramolecular Architectures Based on Acid-base Adducts

LI Wei-Dong ,  FANG Xu ,  QIAO Rui ,  CHEN Shui-Sheng

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Citation:  LI Wei-Dong, FANG Xu, QIAO Rui, CHEN Shui-Sheng. Non-covalent Bonded 3D Supramolecular Architectures Based on Acid-base Adducts[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 46-54. doi: 10.14102/j.cnki.0254-5861.2011-0805 shu

Non-covalent Bonded 3D Supramolecular Architectures Based on Acid-base Adducts

  • 1.

    College of Chemistry & Chemical Engineering, Fuyang Normal College, Fuyang 236041, China

  • 基金项目:

    the disguished organic project (2013JCJS01) (2013JCJS01)

摘要: Two novel acid-base adducts, [H2L12+](Hpbda)2 (1, L1 = 1,4-di(1H-imidazol-4-yl) benzene, H2pbda = 1,4-benzenedicarboxylic acid) and [H2L22+](NO3)2 (2, L2 = 1,4-di(1-carboxy- methyl-imidazol-4-yl)benzene), have been prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analysis. Compound 1 crystallizes in monoclinic, space group P21/n with a = 5.3525(11), b = 9.1471(19), c = 19.314(4) Å, β = 92.342(3)°, V = 944.8(3) Å3, Z = 2, C16H16N6O10, Mr = 452.35, Dc = 1.590 g/cm3, μ = 0.135 mm-1, S = 1.058, F(000) = 468, the final R = 0.0661 and wR = 0.1887 for 2298 observed reflections (I > 2σ(I)). Compound 2 crystallizes in monoclinic, space group P21/c with a = 9.6923(10), b = 17.2950(17), c = 7.1880(7) Å, β = 94.801(2)°, V = 1200.7(2) Å3, Z = 2, C28H22N4O8, Mr = 542.50, Dc = 1.501 g/cm3, μ = 0.112 mm-1, S = 1.060, F(000) = 564, the final R = 0.0394 and wR = 0.1017 for 2768 observed reflections (I > 2σ(I)). In the title compounds, both of L1 and L2 ligands act as weak base to accept protons to exhibit diprotonated H2L12+ and H2L22+ form, which can effectively employ as hydrogen bonding donors to combine anion moieties to form binary adducts respectively. In the crystal packing diagram of two polymers, there exist extensive noncovalent interactions including charge-transfer interactions, C(N)-H…π and N-H…O, C-H…O, O-H…O hydrogen bonding interactions between co-crystal moieties which consolidate the structures of supramolecular polymers, thus generating three-dimensional (3D) frameworks.

English

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  • 收稿日期:  2015-05-01
  • 网络出版日期:  2015-09-24
通讯作者: 陈斌, bchen63@163.com
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