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An Organic-inorganic Hybrid Two-dimensional Bilayer Assembled from 1:2-Type [Er(α-PW11O39)2]11- Moieties and [Cu(dap)2]2+ Linkers

LUO Jie ,  SONG Kai-Fang ,  ZHAO Hao-Zhe ,  ZHAO Jun-Wei ,  CHEN Li-Juan

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Citation:  LUO Jie, SONG Kai-Fang, ZHAO Hao-Zhe, ZHAO Jun-Wei, CHEN Li-Juan. An Organic-inorganic Hybrid Two-dimensional Bilayer Assembled from 1:2-Type [Er(α-PW11O39)2]11- Moieties and [Cu(dap)2]2+ Linkers[J]. Chinese Journal of Structural Chemistry, 2016, 35(1): 39-45. doi: 10.14102/j.cnki.0254-5861.2011-0817 shu

An Organic-inorganic Hybrid Two-dimensional Bilayer Assembled from 1:2-Type [Er(α-PW11O39)2]11- Moieties and [Cu(dap)2]2+ Linkers

  • 1.

    Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

    • 通讯作者: ZHAO Jun-Wei,
    CHEN Li-Juan,
  • 基金项目:

    This work was supported by the Natural Science Foundation of China (21301049, U1304208) (21301049, U1304208)

    the Natural Science Foundation of Henan Province (122300410106) (122300410106)

摘要: A new organic-inorganic hybrid phosphotungstate-based CuII-ErIII heterometallic derivative [Cu(dap)2(H2O)][Cu(dap)2]4.5[Er(α-PW11O39)2]·4H2O (1, dap = 1,2-diaminopropane) has been hydrothermally prepared and characterized by elemental analysis, IR spectra and X-ray single-crystal diffraction. 1 belongs to the triclinic space group P with a = 13.453(3), b = 20.137(4), c = 24.565(4) Å, α = 103.468(4), β = 103.829(4), γ = 98.296(4)°, V = 6148.0(19) Å3, Z = 2, μ = 22.212 mm-1, GOOF = 1.030, R = 0.0744 and wR = 0.1700. Structural analysis indicates that 1 exhibits a special two-dimensional double-layer structure constructed from 1:2-type [Er(α-PW11O39)2]11- moieties and [Cu(dap)2]2+ linkers. From the topological viewpoint, 1 displays a scare two-dimensional five-connected topology in which the [Er(α-PW11O39)2]11- moieties function as the five-connected nodes. Furthermore, its thermogravimetric behavior has been studied.

English

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