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改性活性炭负载三聚磷酸二氢铝催化合成苯甲醛乙二醇缩醛

黄润均 ,  周家添 ,  谢威 ,  陈东莲 ,  韦冬萍 ,  袁爱群 ,  梁慧

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引用本文: 黄润均, 周家添, 谢威, 陈东莲, 韦冬萍, 袁爱群, 梁慧. 改性活性炭负载三聚磷酸二氢铝催化合成苯甲醛乙二醇缩醛[J]. 应用化学, 2016, 33(6): 649-654. doi: 10.11944/j.issn.1000-0518.2016.06.150378 shu
Citation:  HUANG Runjun, ZHOU Jiatian, XIE wei, CHEN donglian, WEI dongping, YUAN Aiqun, LIANG Hui. Synthesis of Benzaldehyde Glycol Acetal Catalyzed by Aluminum Dihydrogen Tripolyphosphate Supported on Modified Activated Carbon[J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 649-654. doi: 10.11944/j.issn.1000-0518.2016.06.150378 shu

改性活性炭负载三聚磷酸二氢铝催化合成苯甲醛乙二醇缩醛

  • 1.

    a 桂林理工大学南宁分校 南宁 530001;

  • 2.

    b 广西民族大学化学化工学院 南宁 530006;

  • 3.

    c 广西工业职业技术学院 南宁 530004

    • 通讯作者: 袁爱群,教授;Tel/Fax:0771-5075800;E-mail:aiqunyuan1999@sina.com;研究方向:材料化学
  • 基金项目:

    2015广西科技开发项目（14125002-6) 

    2014年南宁市科技开发项目（20145201) 

    2013广西教育厅项目（2013YB105，200103YB041) 

    2014广西工业职业技术学院项目 

摘要: 采用硝酸改性活性炭后负载三聚磷二氢铝用于催化合成苯甲醛乙二醇缩醛，通过单因素实验考察醇醛摩尔比、催化剂用量及反应时间等因素对产品收率的影响，并采用正交实验获取较佳工艺条件。结果表明，该催化反应中，当反应温度为110℃时，各因素对收率的影响顺序为：醇醛比 >反应时间 >带水剂加入量 >催化剂用量。优化反应条件为：苯甲醛0.2 mol，醇醛摩尔比2.5，反应时间75 min，催化剂加入量4%（占反应物总质量），带水剂加入量25 mL，苯甲醛乙二醇缩醛收率86.5%，催化剂经5次重复使用后收率仍大于86.0%。

English

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  • 收稿日期:  2015-10-27
  • 网络出版日期:  2015-12-17
通讯作者: 陈斌, bchen63@163.com
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