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十二烷基硫酸钠对两性咪唑类离子液体表面活性剂1-磺丙基-3-十二烷基咪唑内盐界面聚集行为的影响

尚亚卓 ,  王雨琴 ,  董修言 ,  朱云峰 ,  刘洪来

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引用本文: 尚亚卓, 王雨琴, 董修言, 朱云峰, 刘洪来. 十二烷基硫酸钠对两性咪唑类离子液体表面活性剂1-磺丙基-3-十二烷基咪唑内盐界面聚集行为的影响[J]. 应用化学, 2016, 33(6): 641-648. doi: 10.11944/j.issn.1000-0518.2016.06.150351 shu
Citation:  SHANG Yazhuo, WANG Yuqin, DONG Xiuyan, ZHU Yunfeng, LIU Honglai. Effect of Sodium Dodecyl Sulfate on Interfacial Aggregation Behavior of Zwitterionic Imidazole Surfactant 3-(1-Dodecyl-3-imidazolio)propanesulfonate[J]. Chinese Journal of Applied Chemistry, 2016, 33(6): 641-648. doi: 10.11944/j.issn.1000-0518.2016.06.150351 shu

十二烷基硫酸钠对两性咪唑类离子液体表面活性剂1-磺丙基-3-十二烷基咪唑内盐界面聚集行为的影响

  • 1.

    华东理工大学化学与分子工程学院 上海 200237

    • 通讯作者: 尚亚卓,教授;Tel/Fax:021-64252767;E-mail:shangyazhuo@ecust.edu.cn;研究方向:胶体与界面化学
  • 基金项目:

    国家自然科学基金资助项目（21476072,21173079） 

摘要: 利用界面扩张流变技术，研究了两性咪唑类离子液体表面活性剂1-磺丙基-3-十二烷基咪唑内盐（C12imSP）的界面聚集行为，探讨传统表面活性剂十二烷基硫酸钠（SDS）对C12imSP界面聚集行为的影响机制。结果表明，少量SDS的加入可以填补界面上疏松的C12imSP分子间的空位，界面上形成表面活性剂混合吸附膜，界面张力显著降低；提高SDS的浓度，其分子从体相向界面层的扩散交换占优势，界面层分子逐渐达到饱和吸附，此后体系中有混合胶束形成。体相胶束中富集的SDS分子对C12imSP分子的“收纳”作用及进一步的“挽留”作用，加之C12imSP分子本身相对较大的空间位阻效应导致界面上的C12imSP分子一旦通过扩散作用被交换至体相，其很难再回复到表面层，即界面膜以SDS分子为主。通过调节体系中SDS的含量，可以实现对混合体系SDS/C12imSP/NaCl（0.1 mol/L）界面聚集行为的调控，进而实现对界面膜性质的调控。

English

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  • 收稿日期:  2015-09-29
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