引用本文:
Fu Pei LIANG, Zi Lu CHEN, Rui Xiang HU, Hong LIANG, Zhao Hui ZHOU. Infinite Three-Dimensional Coordination Polymers:Synthesis and Structures of[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n,[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and[Zn(4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (H2O)n (pic)2n[J]. Chinese Chemical Letters,
2000, 11(4): 369-372.
Citation: Fu Pei LIANG, Zi Lu CHEN, Rui Xiang HU, Hong LIANG, Zhao Hui ZHOU. Infinite Three-Dimensional Coordination Polymers:Synthesis and Structures of[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n,[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and[Zn(4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (H2O)n (pic)2n[J]. Chinese Chemical Letters, 2000, 11(4): 369-372.
Citation: Fu Pei LIANG, Zi Lu CHEN, Rui Xiang HU, Hong LIANG, Zhao Hui ZHOU. Infinite Three-Dimensional Coordination Polymers:Synthesis and Structures of[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n,[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and[Zn(4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (H2O)n (pic)2n[J]. Chinese Chemical Letters, 2000, 11(4): 369-372.
Infinite Three-Dimensional Coordination Polymers:Synthesis and Structures of[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n,[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and[Zn(4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (H2O)n (pic)2n
摘要:
Three Complexes of the formula[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n (1),[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n (2) and [Zn (4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (pic)2n (H2O)n (3) (4,4'-bpy=4,4'-bipyridine; pic=picric anion) have been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. They all have infinite three-dimensional network structure, crystallizing in the monoclinic space group C2/c (1) and Cc (2,3).
English
Infinite Three-Dimensional Coordination Polymers:Synthesis and Structures of[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n,[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and[Zn(4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (H2O)n (pic)2n
Abstract:
Three Complexes of the formula[Cd (4,4'-bpy)2 (H2O)2]n (pic)2n (1),[Zn (4,4'-bpy)2 (H2O)2]n-(pic)2n (H2O)2n (2) and [Zn (4,4'-bpy)2 (H2O)2]n (4,4'-bpy)n (pic)2n (H2O)n (3) (4,4'-bpy=4,4'-bipyridine; pic=picric anion) have been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. They all have infinite three-dimensional network structure, crystallizing in the monoclinic space group C2/c (1) and Cc (2,3).
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Key words:
- Clathration
- / 4,4'-bipyridine
- / picric anion
- / three-dimensional network
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