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壳聚糖负载辛可宁催化剂的制备及其在水中催化不对称Aldol反应

赵文善 ,  曲程科 ,  杨莉莉 ,  崔元臣

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引用本文: 赵文善, 曲程科, 杨莉莉, 崔元臣. 壳聚糖负载辛可宁催化剂的制备及其在水中催化不对称Aldol反应[J]. 催化学报, 2015, 36(3): 367-371. doi: 10.1016/S1872-2067(14)60248-5 shu
Citation:  Wenshan Zhao, Chengke Qu, Lili Yang, Yuanchen Cui. Chitosan- supported cinchonine as an efficient organocatalyst for direct asymmetric aldol reaction in water[J]. Chinese Journal of Catalysis, 2015, 36(3): 367-371. doi: 10.1016/S1872-2067(14)60248-5 shu

壳聚糖负载辛可宁催化剂的制备及其在水中催化不对称Aldol反应

    通讯作者: 崔元臣
摘要: 以丁二酸酐为连接臂, 经两步反应制备了壳聚糖负载辛可宁有机催化剂(CTS-SA-CN), 并研究了CTS-SA-CN在水体系中对酮与多种芳香醛的直接不对称aldol反应的催化性能.结果表明, 在CTS-SA-CN催化下, 酮与多种芳香醛发生直接不对称aldol反应, 可得到99%的产率和96%的ee值.另外, CTS-SA-CN可通过简单过滤实现回收, 重复使用5次活性并没有明显下降.

English

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  • 发布日期:  2015-03-20
  • 收稿日期:  2014-09-04
  • 网络出版日期:  2014-10-10
通讯作者: 陈斌, bchen63@163.com
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