Preyssler heteropolyacid supported on silica coated NiFe2O4 nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

引用本文: Hossein Eshghi, Ali Javid, Amir Khojastehnezhad, Farid Moeinpour, Fatemeh F. Bamoharram, Mehdi Bakavoli, Masoud Mirzaei. Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones[J]. 催化学报, 2015, 36(3): 299-307. doi: 10.1016/S1872-2067(14)60265-5 shu

Citation: Hossein Eshghi, Ali Javid, Amir Khojastehnezhad, Farid Moeinpour, Fatemeh F. Bamoharram d, Mehdi Bakavoli, Masoud Mirzaei. Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones[J]. Chinese Journal of Catalysis, 2015, 36(3): 299-307. doi: 10.1016/S1872-2067(14)60265-5 shu

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

通讯作者: Ali Javid, Amir Khojastehnezhad; Ali Javid, Amir Khojastehnezhad

摘要: A novel magnetic acidic catalyst comprising Preyssler (H₁₄[NaP₅W₃₀O₁₁₀]) heteropoly acid supported on silica coated nickel ferrite nanoparticles (NiFe₂O₄@SiO₂) was prepared. The catalyst was characterized by Fourier transform infrared, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectrum, VSM and particle size neasurement. Its catalytic activity was investigated for the synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones derivatives by the Biginelli reaction. With the catalyst, the reactions occurred in less than 1 h with good to excel-lent yields. More importantly, the catalyst was easily separated from the reaction mixture by an external magnet and reused at least five times without degradation in the activity.

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English

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

1.
a Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran;

Corresponding author: Ali Javid, Amir Khojastehnezhad; Ali Javid, Amir Khojastehnezhad

Received Date: 19 October 2014
Available Online: 20 March 2015

Abstract: A novel magnetic acidic catalyst comprising Preyssler (H₁₄[NaP₅W₃₀O₁₁₀]) heteropoly acid supported on silica coated nickel ferrite nanoparticles (NiFe₂O₄@SiO₂) was prepared. The catalyst was characterized by Fourier transform infrared, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectrum, VSM and particle size neasurement. Its catalytic activity was investigated for the synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones derivatives by the Biginelli reaction. With the catalyst, the reactions occurred in less than 1 h with good to excel-lent yields. More importantly, the catalyst was easily separated from the reaction mixture by an external magnet and reused at least five times without degradation in the activity.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

通讯作者: Ali Javid, Amir Khojastehnezhad; Ali Javid, Amir Khojastehnezhad

English

Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones

Corresponding author: Ali Javid, Amir Khojastehnezhad; Ali Javid, Amir Khojastehnezhad

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