引用本文:
张卫华, 忻新泉. 2,2'-对苯二甲硫基二乙酸与醋酸钴在低热温度下的固-固相反应[J]. 应用化学,
1997, 14(3): 81-83.
Citation: Zhang Weihua, Xin Xinquan. The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio) Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature[J]. Chinese Journal of Applied Chemistry, 1997, 14(3): 81-83.
Citation: Zhang Weihua, Xin Xinquan. The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio) Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature[J]. Chinese Journal of Applied Chemistry, 1997, 14(3): 81-83.
2,2'-对苯二甲硫基二乙酸与醋酸钴在低热温度下的固-固相反应
摘要:
有机硫醚酸类化合物除用于含硫大环化合物的合成中间体外,由于其在结构上同时存在着可与金属配位的羧基氧原子和硫原子,近年来在配位化学领域也得到广泛的应用,但室温和低热温度下的固相配位化学反应研究报道较少[1].
-
关键词:
- 2,2'-对苯二甲硫基二乙酸
- / 醋酸钴
- / 固-固相反应
- / 动力学
English
The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio) Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature
Abstract:
The solid-solid state reaction of 2,2'-(p-phenylenedimethylenethio) diacetic acid with cobalt acetate tetrahydrate has been studied. XRD, IR, ESR, TG-DTA and elemental analysis were used to characterize the solid product. The kinetics of the isothermal solid state reaction was investigated by using the electrical conductivity measurement. The kinetics of this system conforms to a A3 mechanism, the activation energy is calculated to be Ea=104.7 kJ/mol.
-
-
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 377
- HTML全文浏览量: 16
下载:
