引用本文:
宋保林, 孙柏旺, 牛德仲, 路再生, 卢祥生. 1-羟基-2(1H)-吡啶硫酮及其甲基衍生物与Cr(Ⅲ)配合物的合成和性质[J]. 应用化学,
1993, 10(5): 78-80.
Citation: Song Baolin, Sun Baiwang, Niu Dezhong, Lu Zaisheng, Lu Xiangsheng. SYNTHESIS AND PROPERTIES OF THE COORDINATION COMPOUNDS OF Cr(Ⅲ)WITH 1-HYDROXY-2(1H)-PYRIDINETHIONE AND ITS METHYL DERIVATIVES[J]. Chinese Journal of Applied Chemistry, 1993, 10(5): 78-80.
Citation: Song Baolin, Sun Baiwang, Niu Dezhong, Lu Zaisheng, Lu Xiangsheng. SYNTHESIS AND PROPERTIES OF THE COORDINATION COMPOUNDS OF Cr(Ⅲ)WITH 1-HYDROXY-2(1H)-PYRIDINETHIONE AND ITS METHYL DERIVATIVES[J]. Chinese Journal of Applied Chemistry, 1993, 10(5): 78-80.
1-羟基-2(1H)-吡啶硫酮及其甲基衍生物与Cr(Ⅲ)配合物的合成和性质
摘要:
Edrissi[1]认为Cr(Ⅲ)与1-羟基-2(1H)-吡啶硫酮(HPT)的甲基衍生物不能给出任何反应,并且将与HPT的配合物注明为绿色溶液。本文在过去工作的基础上[2~4]合成了S-(1-氧化-2-吡啶基)硫代苯甲酸酯(PTB)和3-CH3-PTB;并合成了3个铬配合物。通过元素分析,紫外-可见,红外光谱,摩尔电导和TG-DTA-DTG作了表征。探讨了形成机理并研究了抑菌活性。
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关键词:
- 铬(Ⅲ)配合物
- / 羟基吡啶硫酮
- / 羟基甲基-吡啶硫酮
- / S-(氧化吡啶基)硫代苯甲酸酯
- / S-(甲基氧化吡啶基)硫代苯甲酸酯
- / 合成
- / 抑菌活性
English
SYNTHESIS AND PROPERTIES OF THE COORDINATION COMPOUNDS OF Cr(Ⅲ)WITH 1-HYDROXY-2(1H)-PYRIDINETHIONE AND ITS METHYL DERIVATIVES
Abstract:
Three Cr (Ⅲ) coordination compounds of S-(1-oxide-2-pyridyl)thiobenzoate (PTB) and its 3-methyl derivatives (3-CH3-PTB) and 1-hydroxy-4-methyl-2(1H)-pyridinethione (4-CH3-HPT) have been synthesized. They have been characterized by elemental analyses, UV, IR, molar conductance and TG-DTA-DTG. The antibacterial activities of the complexes have been tested.
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