引用本文:
潘平来, 柳忠阳, 袁国卿, 蒋大智. 顺二羰基铑(Ⅰ)共聚物催化剂的合成、结构与催化甲醇羰基化反应性能的研究[J]. 应用化学,
1993, 10(5): 72-74.
Citation: Pan Pinglai, Liu Zhongyang, Yuan Guoqing, Jiang Dazhi. SYNTHESIS, STRUCTURE OF CIS-DICARBONYL RHODIUM(Ⅰ) COPOLYMER COMPLEXES AND THEIR CATALYTIC PROPERTY FOR METHANOL CARBONYLATION[J]. Chinese Journal of Applied Chemistry, 1993, 10(5): 72-74.
Citation: Pan Pinglai, Liu Zhongyang, Yuan Guoqing, Jiang Dazhi. SYNTHESIS, STRUCTURE OF CIS-DICARBONYL RHODIUM(Ⅰ) COPOLYMER COMPLEXES AND THEIR CATALYTIC PROPERTY FOR METHANOL CARBONYLATION[J]. Chinese Journal of Applied Chemistry, 1993, 10(5): 72-74.
顺二羰基铑(Ⅰ)共聚物催化剂的合成、结构与催化甲醇羰基化反应性能的研究
English
SYNTHESIS, STRUCTURE OF CIS-DICARBONYL RHODIUM(Ⅰ) COPOLYMER COMPLEXES AND THEIR CATALYTIC PROPERTY FOR METHANOL CARBONYLATION
Abstract:
A series of 4-vinyl pyridine-methyl acrylate copolymer complexes with tetracarbonyldichlorodirhodium were prepared. Their structure characteristics and catalytic properties for methanol carbonylation to synthesize acetic acid have been studied. The macromolecular complexes containing cis-dicarbonyl rhodium in structure have a higher catalytic activity in methanol carbonylation and an excellent thermal stability. There appeared two coordination units in the copolymer complexes: 
x=0，1,2 The carbonylation of methanol catalyzed by the complexes can be carried out in mild conditions with-out any side-products. The selectivity of carbonylation reaction was approximately 100%.
x=0，1,2 The carbonylation of methanol catalyzed by the complexes can be carried out in mild conditions with-out any side-products. The selectivity of carbonylation reaction was approximately 100%.-
Key words:
- vinyl pyridine
- / methyl acrylate
- / copolymer
- / cis-dicarbonyl rhodium complex
- / methanol carbonylation
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