引用本文:
董文魁. 铜(Ⅱ)(溴代苯并-15-冠-5)配合物的研究[J]. 应用化学,
1993, 10(4): 89-91.
Citation: Dong Wenkui. STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ) (BROMOSUBSTITUTED BENZO-15-CROWN-5)[J]. Chinese Journal of Applied Chemistry, 1993, 10(4): 89-91.
Citation: Dong Wenkui. STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ) (BROMOSUBSTITUTED BENZO-15-CROWN-5)[J]. Chinese Journal of Applied Chemistry, 1993, 10(4): 89-91.
铜(Ⅱ)(溴代苯并-15-冠-5)配合物的研究
English
STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ) (BROMOSUBSTITUTED BENZO-15-CROWN-5)
Abstract:
In this paper, the two coordination compounds of copper perchlorate with 4'-bromo(or 4',5'-dibromo)-benzo=15-crown-5 have been prepared in acetone medium, the composition of the new coordination compounds have been determined as Cu(ClO4)2·L·3H2O(L=4'-bromobenzo-15-crown-5 or 4', 5'-dibromo-benzo-15-crown-5), the IR, UV, TG-DTA,X-ray powder diffraction analysis and molar conductance of these coordination compounds have also been studied. It shows that coordination number of the coordination compounds is 9.
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Key words:
- copper perchlorate
- / crown ether
- / coordination compound
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