引用本文:
张伟德, 詹瑞云, 叶兴凯, 吴越. 固载化金属酞菁(MPc)催化性能的研究Ⅱ.MPc通过配位连接在硅胶上及其对O2的活化作用[J]. 应用化学,
1993, 10(4): 39-42.
Citation: Zhang Weide, Zhan Ruiyun, Ye Xingkai, Wu Yue. STUDY ON CATALYTIC ACTIVITY OF SUPPORTED METAL PHTHALOCYANINE(MPc) Ⅱ. MPc LINKED TO THE SURFACE OF SILICA GEL AND ITS ACTIVATION ACTION ON OXYGEN[J]. Chinese Journal of Applied Chemistry, 1993, 10(4): 39-42.
Citation: Zhang Weide, Zhan Ruiyun, Ye Xingkai, Wu Yue. STUDY ON CATALYTIC ACTIVITY OF SUPPORTED METAL PHTHALOCYANINE(MPc) Ⅱ. MPc LINKED TO THE SURFACE OF SILICA GEL AND ITS ACTIVATION ACTION ON OXYGEN[J]. Chinese Journal of Applied Chemistry, 1993, 10(4): 39-42.
固载化金属酞菁(MPc)催化性能的研究Ⅱ.MPc通过配位连接在硅胶上及其对O2的活化作用
English
STUDY ON CATALYTIC ACTIVITY OF SUPPORTED METAL PHTHALOCYANINE(MPc) Ⅱ. MPc LINKED TO THE SURFACE OF SILICA GEL AND ITS ACTIVATION ACTION ON OXYGEN
Abstract:
The MPcs (M=Fe2+, Co2+, Cu2+; Pc=phthalocyanine) were coordinated with -(CH2)3N(C2H5)2 group of SiO2,which had been linked with above group through organic synthesis.The UV-Vis diffuse reflection spectra revealed this supporting. ESR result indicated that only the supported CoPe and FePc were capable of reacting with O2 producing O2-.
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Key words:
- metal phthalocyanine
- / supported catalyst
- / oxygen activation
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