引用本文:
吴琼, 邢娜, 马喜彤, 徐丽婷, 邢永恒. 乳酸促进的仲钼酸铵催化氧化环己烷过程[J]. 应用化学,
2015, 32(1): 85-92.
doi:
10.11944/j.issn.1000-0518.2015.01.140071
Citation: WU Qiong, XING Na, MA Xitong, XU Liting, XING Yongheng. Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 85-92. doi: 10.11944/j.issn.1000-0518.2015.01.140071
Citation: WU Qiong, XING Na, MA Xitong, XU Liting, XING Yongheng. Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 85-92. doi: 10.11944/j.issn.1000-0518.2015.01.140071
乳酸促进的仲钼酸铵催化氧化环己烷过程
English
Lactic Acid Promoted Cyclohexane Oxidation with Ammonium Paramolybdate
Abstract:
Cyclohexane oxidation is one of the most important industrial reactions. In order to find more efficient and cheap catalysts for this reaction,we studied the catalytic activity of ammonium paramolybdate (APM). By GC analysis,we focus on the effects of the species and the amount of the acids on the reactivity. Compared with nitric acid,lactic acid is more effective for the oxidation of cyclohexanol to cyclohexanone,and thus improve the TON(turn over number) value of the target products from 124 to 161. Furthermore,we propose a possible reaction mechanism of this new way for green oxidation of cyclohexane.
-
Key words:
- ammonium paramolybdate
- / lactic acid
- / nitric acid
- / cyclohexane oxidation
- / mechanism
-
-
扫一扫看文章
计量
- PDF下载量: 1
- 文章访问数: 665
- HTML全文浏览量: 35
下载:
