引用本文:
张思辉, 邓正华, 罗春樵, 万国祥. 等离子体引发聚合制备梳形聚醚及其锂盐络合物的离子电导性[J]. 应用化学,
1990, 7(4): 17-21.
Citation: Zhang Sihui, Deng Zhenghua, Luo Chunqiao, Wan Guoxiang. PREPARATION OF COMB-POLYETHER BY PLASMA-INITIATED POLYMERIZATION AND THE IONIC CONDUCTIVITY OF ITS LITHIUM SALT COMPLEXES[J]. Chinese Journal of Applied Chemistry, 1990, 7(4): 17-21.
Citation: Zhang Sihui, Deng Zhenghua, Luo Chunqiao, Wan Guoxiang. PREPARATION OF COMB-POLYETHER BY PLASMA-INITIATED POLYMERIZATION AND THE IONIC CONDUCTIVITY OF ITS LITHIUM SALT COMPLEXES[J]. Chinese Journal of Applied Chemistry, 1990, 7(4): 17-21.
等离子体引发聚合制备梳形聚醚及其锂盐络合物的离子电导性
English
PREPARATION OF COMB-POLYETHER BY PLASMA-INITIATED POLYMERIZATION AND THE IONIC CONDUCTIVITY OF ITS LITHIUM SALT COMPLEXES
Abstract:
The yield and the composition of the comb-polyether prepared by plasma-initiated poly-merization methoxypolyglycol methactylates were found in dependence on the power of plasma generator, the discharge time, the temperature and the time of postpolymerization, the kind of solvent, and the monomer concentration.The structure of the comb-polyether is identical with that prepared by radicalinitiated polymerization, but the former has a greater molecular weight and is little crosslinked. The plasma initiated comb-polyether can be plasticized to increase the ionic conductivity of its lithium salt complexes.
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