引用本文:
刘世昌, 朱天培. 稀土硝酸盐与穴醚(2.2)及穴醚(2.2.2)配合物的合成和性质[J]. 应用化学,
1986, 3(5): 58-63.
Citation: Liu Shichang, Zhu Tianpei. SYNTHESIS AND PROPERTIES OF LANTHANIDE NITRATES COMPLEXES WITH CRYPTANDS(2.2.2) AND (2.2)[J]. Chinese Journal of Applied Chemistry, 1986, 3(5): 58-63.
Citation: Liu Shichang, Zhu Tianpei. SYNTHESIS AND PROPERTIES OF LANTHANIDE NITRATES COMPLEXES WITH CRYPTANDS(2.2.2) AND (2.2)[J]. Chinese Journal of Applied Chemistry, 1986, 3(5): 58-63.
稀土硝酸盐与穴醚(2.2)及穴醚(2.2.2)配合物的合成和性质
摘要:
由三价稀土、镧、铕和镱的硝酸盐分别与穴醚(2.2),穴醚(2.2.2)反应,合成相应的五种固体配合物,并进行了元素分析,IR,NMR,TG,DTA,电化学等性质的研究。
English
SYNTHESIS AND PROPERTIES OF LANTHANIDE NITRATES COMPLEXES WITH CRYPTANDS(2.2.2) AND (2.2)
Abstract:
Five complexes of the lanthanide nitrates with the cryptand (2.2.2) and cryptand(2.2),La(NO3)3·(2.2),Eu(NO3)3·(2.2)·H2O, Yb(NO3)3(2.2)·2H2O,La2 (NO3)6(2.2.2)MeCN·3H2O, Eu2(NO3)6·(2.2.2)·MeCN·3H2O, have been synthesized in acetonitrile.The complexes were characterized by elemental analyses, IR, NMR, DTA, TG, and electrochemical data.
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