质子交换膜燃料电池梯度化膜电极

引用本文: 陈光颖, 赵波, 王诚, 荆平, 肖宇, 牛萌, 赵鹏程. 质子交换膜燃料电池梯度化膜电极[J]. 化学通报, 2016, 79(1): 9-15. shu

Citation: Chen Guangying, Zhao Bo, Wang Cheng, Jing Ping, Xiao Yu, Niu Meng, Zhao Pengcheng. Gradient Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell[J]. Chemistry, 2016, 79(1): 9-15. shu

质子交换膜燃料电池梯度化膜电极

陈光颖 ^1, ,
赵波 ^2, ,
王诚 ^{1,
,} ,
荆平 ^2, ,
肖宇 ^2, ,
牛萌 ^2, ,
赵鹏程 ^2,

1.
1. 清华大学核能与新能源技术研究院北京 100084;
2.
2. 国网智能电网研究院北京 102211

通讯作者: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

摘要: 为实现质子交换膜燃料电池的高性能（高功率密度或大电流密度）、低成本（低铂载量）、长寿命发电，人们尝试在燃料电池的核心部件膜电极结构中引入梯度化设计的概念。梯度化膜电极包括膜电极中各组件的梯度化：气体扩散层的PTFE含量与孔隙率的梯度化，催化层的催化剂与Nafion用量的梯度化以及微孔层的疏水性与孔隙率的梯度化。梯度化膜电极中催化剂分布、孔隙率分布、亲/疏水性分布合理，具有良好的三相反应界面以及质子、电子、反应气体、水等多相物质高效传输通道，从而能满足在低铂载量、低加湿以及高电流密度条件下高性能稳定工作。本文整理了近几年来有关燃料电池梯度化膜电极研究的相关文献，梳理了梯度化膜电极研究发展脉络，归纳总结了各种梯度化膜电极的制备方法、性能以及构效关系，并展望了梯度化膜电极下一步研究方向，对高性能、低成本、长寿命的燃料电池开发具有指导意义。

关键词:

English

Gradient Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell

1.
1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084;
2.
2. State Grid Smart Grid Research Institute, Beijing 102211

Corresponding author: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

Received Date: 29 June 2015

Abstract: To achieve proton exchange membrane fuel cell long-life high-performance (high power density or high current density) power generation at low cost (low platinum loading), gradient design is introduced into fabrication of MEA. Gradient MEA includes gradient of each MEA assembly:gradient PTFE content and porosity of gas diffusion layer, gradient content of catalyst and Nafion in catalyst layer, and gradient hydrophobicity and porosity of micro-porous layer. Gradient MEA has reasonable distribution of catalyst, porosity and hydrophilicity/hydrophobicity, together with good three phase boundary and multiphase mass transmission channels (e.g. proton,electron,reactant gas and water transmission channels), thus achieving stable high performance of PEMFC at circumstance of low Pt loading, low humidity and high current density. Manufacturing methods, performance and structure-activity relationship of gradient MEA are reviwed in this paper based on the latest research literatures and patents,which has guiding significance for developing of low cost, long-life and high performance MEA.

Key words:

Proton exchange membrane fuel cell (PEMFC)
/ Membrane electrode assembly (MEA)
/ Gradient
/ Catalyst layer (CL)
/ Gas diffusion layer (GDL)
/ Micro-porous layer (MPL)

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

质子交换膜燃料电池梯度化膜电极

通讯作者: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

English

Gradient Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell

Corresponding author: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

质子交换膜燃料电池梯度化膜电极

通讯作者: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

English

Gradient Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell

Corresponding author: 王诚,男,副研究员。E-mail:wangcheng@tsinghua.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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