引用本文:
潘娜, 于慧, 姜建壮. 取代自由酞菁及二层和三层钕三明治型配合物的红外光谱[J]. 应用化学,
2000, 17(4): 409-410.
Citation: PAN Na, YU Hui, JIANG Jian-Zhuang. IR Spectral Characteristics of Substituted Phthalocyanine and Its Sandwich-Type Neodymium Double- and Triple-Decker Complexes[J]. Chinese Journal of Applied Chemistry, 2000, 17(4): 409-410.
Citation: PAN Na, YU Hui, JIANG Jian-Zhuang. IR Spectral Characteristics of Substituted Phthalocyanine and Its Sandwich-Type Neodymium Double- and Triple-Decker Complexes[J]. Chinese Journal of Applied Chemistry, 2000, 17(4): 409-410.
取代自由酞菁及二层和三层钕三明治型配合物的红外光谱
English
IR Spectral Characteristics of Substituted Phthalocyanine and Its Sandwich-Type Neodymium Double- and Triple-Decker Complexes
Abstract:
An assignment of the IR bands for a free substituted phthalocyanine H2[Pc-(OC8H17)8], its sandwich-type neodymium(Ⅲ) double- and triple-decker complex, Nd[Pc(OC8H17)8]2 and (Pc)Nd[Pc(OC8H17)8]Nd[Pc(OC8H17)8] has been done. It is found that in H2[Pc(OC8H17)8] and (Pc)Nd[Pc(OC8H17)8]Nd[Pc(OC8H17)8] the characteristic IR peaks appeared at 1330 cm-1(w), 1380 cm-1(s) and 1070~1080 cm-1 (rs) for bivalent phthalocynine anions: Pc2- or Pc(OC8H17)82-, and in Nd[Pc(OC8H17)8]2 the characteristic peaks appeared at 1315 cm-1 (rs) and 1380 cm-1 (s) were assigned for single phthalocyanine anion free radical.
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Key words:
- sandwich phthalocyanine complex
- / neodymium complex
- / infrared spectrum
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