引用本文:
周传佩, 陈文生, 刘义, 屈松生. L-亮氨酸与醋酸铜固相配位反应的热化学研究[J]. 应用化学,
2001, 18(2): 152-154.
Citation: ZHOU Chuan-Pei, CHEN Wen-Sheng, LIU Yi, QU Song-Sheng. Study on Thermochemistry of Solid State Coordination Reaction of L-Leucine with Copper Acetate[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 152-154.
Citation: ZHOU Chuan-Pei, CHEN Wen-Sheng, LIU Yi, QU Song-Sheng. Study on Thermochemistry of Solid State Coordination Reaction of L-Leucine with Copper Acetate[J]. Chinese Journal of Applied Chemistry, 2001, 18(2): 152-154.
L-亮氨酸与醋酸铜固相配位反应的热化学研究
English
Study on Thermochemistry of Solid State Coordination Reaction of L-Leucine with Copper Acetate
Abstract:
The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydrochloric acid(4 mol/L), a new thermochemical cycle is designed. The values of ΔfHmθ=15.64 kJ/mol, ΔfHmθ(trans-Cu(L-Leu)2,s)=-1194.7 kJ/mol are evalcated.
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Key words:
- L-leucine
- / copper acetate
- / solid-solid state reaction
- / thermochemistry
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