引用本文:
曾明华, 梁宏, 胡瑞祥, 刘旭红, 邓业成, 黄社群. 二羟乙基二硫代氨基甲酸铋配合物的合成,晶体结构及杀菌活性[J]. 应用化学,
2001, 18(10): 837-839.
Citation: ZENG Ming-Hua, LIANG Hong, HU Rui-Xiang, LIU Xu-Hong, Deng Ye-Cheng, Huang She-Qun. Synthesis, Structure and Antibacterial Activity of Dithiocarbamate Complex of Bi(Ⅲ)[J]. Chinese Journal of Applied Chemistry, 2001, 18(10): 837-839.
Citation: ZENG Ming-Hua, LIANG Hong, HU Rui-Xiang, LIU Xu-Hong, Deng Ye-Cheng, Huang She-Qun. Synthesis, Structure and Antibacterial Activity of Dithiocarbamate Complex of Bi(Ⅲ)[J]. Chinese Journal of Applied Chemistry, 2001, 18(10): 837-839.
二羟乙基二硫代氨基甲酸铋配合物的合成,晶体结构及杀菌活性
English
Synthesis, Structure and Antibacterial Activity of Dithiocarbamate Complex of Bi(Ⅲ)
Abstract:
The tris(N,N-iminodiethanoldithiocarbamate) bismuth(Ⅲ) complex (Bi2(deadtc)6) has been synthesized and its structure has been investigated by single crystal X-ray diffractometry. The binuclear complex is centrosymmetric. The resulting coordination polyhedron appears a distorted octahedra with four strong (0.266 7~0.280 9 nm) and two weak (0.306 3~0.310 5 nm) Bi-S bonds. Experiments show that the antibacterial activity of the complex is superior to that of the ligand and that of Mancozeb.
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Key words:
- bismuth complex
- / dithicarbamate
- / crystal structure
- / antibacterial activity
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