引用本文:
罗春华, 于美娜, 赵凌, 程格. 固态反应合成2,4,6-三苯氧基-1,3,5-均三嗪衍生物[J]. 应用化学,
2005, 22(7): 811-812.
Citation: LUO Chun-Hua, YU Mei-Na, ZHAO Ling, CHENG Ge. Synthesis of 2,4,6-Tris (phenyoxy)-1,3,5-triazine Derivatives by Solid-state Reaction[J]. Chinese Journal of Applied Chemistry, 2005, 22(7): 811-812.
Citation: LUO Chun-Hua, YU Mei-Na, ZHAO Ling, CHENG Ge. Synthesis of 2,4,6-Tris (phenyoxy)-1,3,5-triazine Derivatives by Solid-state Reaction[J]. Chinese Journal of Applied Chemistry, 2005, 22(7): 811-812.
固态反应合成2,4,6-三苯氧基-1,3,5-均三嗪衍生物
English
Synthesis of 2,4,6-Tris (phenyoxy)-1,3,5-triazine Derivatives by Solid-state Reaction
Abstract:
Triaryl cyanurates,2,4,6-tris (phenyoxy)-1,3,5-triazine derivatives,were prepared by solid-state reaction,which was carried out between cyanuric chloride and phenols with the molar ratio of 1:3 in the presence of potassium hydroxide as catalyst at room temperature.It is shown that the yields of the products are mainly affected by the reactivity of phenols due to the substituted group and its position.Under the same conditions,2,4,6-tris (p-methoxyphenyoxy)-1,3,5-triazine was synthesized from p-methoxyphenol in the yield of 89% and 2,4,6-tris (o-chlorophenyoxy)-1,3,5-triazine was synthesized from o-chlorophenol in the yield of 30%.
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Key words:
- solid-state reaction
- / condensation
- / cyanuric chloride
- / tris (phenyoxy) triazine
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