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一个基于苯并噻唑的铜离子荧光探针的合成、晶体结构和光谱性质

范方禄 ,  靖金球 ,  陈雪梅

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引用本文: 范方禄, 靖金球, 陈雪梅. 一个基于苯并噻唑的铜离子荧光探针的合成、晶体结构和光谱性质[J]. 无机化学学报, 2015, (3): 548-554. doi: 10.11862/CJIC.2015.026 shu
Citation:  FAN Fang-Lu, JING Jin-Qiu, CHEN Xue-Mei. Synthesis, Crystal Structure and Spectroscopic Property of a Benzothiazole-Based Fluorescent Probe for Cu2+[J]. Chinese Journal of Inorganic Chemistry, 2015, (3): 548-554. doi: 10.11862/CJIC.2015.026 shu

一个基于苯并噻唑的铜离子荧光探针的合成、晶体结构和光谱性质

  • 1.

    1 湖北理工学院材料与冶金学院, 黄石 435003;

  • 2.

    2 湖北理工学院化学与化工学院, 黄石 435003

    • 通讯作者: 范方禄 flfan2014@163.com
  • 基金项目:

    国家自然科学基金(No.51173060)资助。 (No.51173060)

摘要: 合成和表征了一个苯并噻唑类的荧光探针N-(4-(苯并噻唑-2-基)苯基)-2-((2-羟乙基)(吡啶-2-甲基)氨基)乙酰胺 (FL), 用光谱法研究了它与各种金属离子的识别特性。结果表明：FL对Cu2+具有较高的选择性和灵敏度, 并且对Cu2+的识别不受其它金属离子的干扰。FL与Cu2+形成配合物的结合比为1:1, 其荧光强度与Cu2+浓度(3.8~9.6 μmol·L-1)呈现较好的线性关系, 而且它还可应用于自来水和湖水等水体样品中Cu2+的检测。

English

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  • 收稿日期:  2014-09-19
  • 网络出版日期:  2014-10-21
通讯作者: 陈斌, bchen63@163.com
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