注册 English

自组装和共缩聚法制备磺酸基修饰的硅柱磷酸锆

花益香 ,  刘文晋 ,  王红宁 ,  陈若愚

downloadPDF
引用本文: 花益香, 刘文晋, 王红宁, 陈若愚. 自组装和共缩聚法制备磺酸基修饰的硅柱磷酸锆[J]. 无机化学学报, 2015, (3): 493-500. doi: 10.11862/CJIC.2015.065 shu
Citation:  HUA Yi-Xiang, LIU Wen-Jin, WANG Hong-Ning, CHEN Ruo-Yu. Preparation of Sulfonic Acid-Functionalized Silica-Pillared Zirconium Phosphate with the Self-Assembly Method and Cocondensation[J]. Chinese Journal of Inorganic Chemistry, 2015, (3): 493-500. doi: 10.11862/CJIC.2015.065 shu

自组装和共缩聚法制备磺酸基修饰的硅柱磷酸锆

  • 1.

    常州大学石油化工学院, 常州 213164

    • 通讯作者: 陈若愚 cxdcry@163.com
  • 基金项目:

    国家自然科学基金(No.21101017/B0107)资助项目。 (No.21101017/B0107)

摘要: 以十六胺插层磷酸锆为原料, 利用十二烷基二甲基苄基氯化铵为导向模板剂, 通过正硅酸乙酯和巯丙基三甲氧基硅烷的层间共水解缩聚, 并结合双氧水对巯丙基的熏蒸氧化, 制备了磺酸基修饰的硅柱磷酸锆材料。通过XRD、SEM、N2吸附-脱附和FT-IR等方法对柱撑材料进行了结构表征。结果表明, 通过调变预撑剂和模板剂中的碳链长度可以优化材料的柱撑结构和孔结构, 磺酸基修饰的材料孔径分布在2.17 nm左右, 比表面积可达163 m2·g-1, 且保留有规整有序的柱撑磷酸锆层板结构。磺酸基的修饰则成功调变了材料的酸位性质, Brönsted酸量最高可达2.71 mmol·g-1, 总酸量可达5.20 mmol·g-1。利用柠檬酸与正丁醇的酯化反应为探针反应, 由于磺酸基修饰的硅柱磷酸锆材料具有独特的空间反应效应和较为丰富的Brönsted酸位, 酯化反应转化率最高可达95.74%。

English

  • 

    1. [1] TANG Yi(唐颐), XU Jin-Suo(徐金锁), GAO Zi(高滋). Chinese J. Catal.(催化学报), 1998,19(4):354-359[1] TANG Yi(唐颐), XU Jin-Suo(徐金锁), GAO Zi(高滋). Chinese J. Catal.(催化学报), 1998,19(4):354-359

    2. [2] Chen R, Wang J, Wang H, et al. Solid State Sci., 2011,13: 630-635[2] Chen R, Wang J, Wang H, et al. Solid State Sci., 2011,13: 630-635

    3. [3] Jiménez-Jiménez J, Rubio-Alonso M, Quesada D, et al. J. Mater. Chem., 2005,15(34):3466-3472[3] Jiménez-Jiménez J, Rubio-Alonso M, Quesada D, et al. J. Mater. Chem., 2005,15(34):3466-3472

    4. [4] Jiménez-Jiménez J, Algarra M, Rodríguez-Castellón E, et al. J. Hazard. Mater., 2011,190(1):694-699[4] Jiménez-Jiménez J, Algarra M, Rodríguez-Castellón E, et al. J. Hazard. Mater., 2011,190(1):694-699

    5. [5] Algarra M, Jiménez-Jiménez J, Miranda M, et al. Surf. Interface Anal., 2013,45(2):612-618[5] Algarra M, Jiménez-Jiménez J, Miranda M, et al. Surf. Interface Anal., 2013,45(2):612-618

    6. [6] Liu W, Wang H, He M, et al. Catal. Lett., 2014,144(4):663-673[6] Liu W, Wang H, He M, et al. Catal. Lett., 2014,144(4):663-673

    7. [7] Polverejan M, Liu Y, Pinnavaia T. Chem. Mater., 2002,14 (5):2283-2288[7] Polverejan M, Liu Y, Pinnavaia T. Chem. Mater., 2002,14 (5):2283-2288

    8. [8] Wei L, Tang T, Huang B. Microporous Mesoporous Mater., 2004,67(2):175-179[8] Wei L, Tang T, Huang B. Microporous Mesoporous Mater., 2004,67(2):175-179

    9. [9] LI Yin(李颖), LIU Ke(刘可), HUA Wei-Ming(华伟明), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011, 32(003):731-737[9] LI Yin(李颖), LIU Ke(刘可), HUA Wei-Ming(华伟明), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011, 32(003):731-737

    10. [10] LIAO Ju-Fang(廖菊芳), WU Quan-Zhou(邬泉周), YIN Qiang (尹强), et al. Acta Chim. Sinica(化学学报), 2006,64:2419-2424[10] LIAO Ju-Fang(廖菊芳), WU Quan-Zhou(邬泉周), YIN Qiang (尹强), et al. Acta Chim. Sinica(化学学报), 2006,64:2419-2424

    11. [11] YUAN Xing-Dong(袁兴东), SHEN Jian(沈健), LI Guo-Hui (李国辉), et al. Chinese J. Catal.(催化学报), 2003,24(2):83-86[11] YUAN Xing-Dong(袁兴东), SHEN Jian(沈健), LI Guo-Hui (李国辉), et al. Chinese J. Catal.(催化学报), 2003,24(2):83-86

    12. [12] Yang H, Song H, Zhang H, et al. J. Mol. Catal. A Chem., 2014,381:54-60[12] Yang H, Song H, Zhang H, et al. J. Mol. Catal. A Chem., 2014,381:54-60

    13. [13] Xu J, Jiang J, Zuo Z, et al. Process Saf. Environ. Prot., 2010, 88(1):28-30[13] Xu J, Jiang J, Zuo Z, et al. Process Saf. Environ. Prot., 2010, 88(1):28-30

    14. [14] Wang H, Liu W, Yao W, et al. Appl. Surf. Sci., 2013,268: 179-187[14] Wang H, Liu W, Yao W, et al. Appl. Surf. Sci., 2013,268: 179-187

    15. [15] Ha B, Char K, Si H. J. Phys. Chem. B, 2005,109:24434-24440[15] Ha B, Char K, Si H. J. Phys. Chem. B, 2005,109:24434-24440

    16. [16] Wang H, Tang M, Zhang K, et al. J. Hazard. Mater., 2014, 268:115-163[16] Wang H, Tang M, Zhang K, et al. J. Hazard. Mater., 2014, 268:115-163

    17. [17] Yang Q, Liu J, Yang J, et al. J. Catal., 2004,228(2):265-272[17] Yang Q, Liu J, Yang J, et al. J. Catal., 2004,228(2):265-272

    18. [18] Wei Q, Nie Z, Hao Y, et al. Mater. Lett., 2005,59(28):3611-3615[18] Wei Q, Nie Z, Hao Y, et al. Mater. Lett., 2005,59(28):3611-3615

    19. [19] Prabakar S, Assink R A. J. Non-Cryst. Solids, 1997,211(1): 39-48[19] Prabakar S, Assink R A. J. Non-Cryst. Solids, 1997,211(1): 39-48

    20. [20] Wang J, Li F, Zhou H, et al. Chem. Mater., 2009,21(4):612-620[20] Wang J, Li F, Zhou H, et al. Chem. Mater., 2009,21(4):612-620

    21. [21] Li B, Mao H, Li X, et al. J. Colloid Interface Sci., 2009,336 (1):244-249[21] Li B, Mao H, Li X, et al. J. Colloid Interface Sci., 2009,336 (1):244-249

    22. [22] Zhou Y, Huang R, Ding F, et al. ACS Appl. Mater. Inter., 2014,6:7417-7425[22] Zhou Y, Huang R, Ding F, et al. ACS Appl. Mater. Inter., 2014,6:7417-7425

    23. [23] Jie G, Liu B, Pan H, et al. Anal. Chem., 2007,79(15):5574-5581[23] Jie G, Liu B, Pan H, et al. Anal. Chem., 2007,79(15):5574-5581

    24. [24] Giguère P A, Liu I D. Can. J. Chem., 1957,35(4):283-293[24] Giguère P A, Liu I D. Can. J. Chem., 1957,35(4):283-293

    25. [25] Quijano C, Alvarez B, Gatti R, et al. Biochem. J., 1997,322: 167-173[25] Quijano C, Alvarez B, Gatti R, et al. Biochem. J., 1997,322: 167-173

    26. [26] CHEN Zhi-Yong(陈志勇). Non-Metal Mines(非金属矿), 2005,28(5):14-16[26] CHEN Zhi-Yong(陈志勇). Non-Metal Mines(非金属矿), 2005,28(5):14-16

    27. [27] WU Bao-Ping(武宝萍), QI Yu-Tai(亓玉台), YUAN Xing-Dong(袁兴东). Ind. Catal.(工业催化), 2004,12(1):32-35[27] WU Bao-Ping(武宝萍), QI Yu-Tai(亓玉台), YUAN Xing-Dong(袁兴东). Ind. Catal.(工业催化), 2004,12(1):32-35

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  251
  • HTML全文浏览量:  19
文章相关
  • 收稿日期:  2014-09-12
  • 网络出版日期:  2014-11-17
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net