注册 English

液相共存成分对氨法脱碳吸收液解吸CO2的影响研究

马双忱 ,  王梦璇 ,  宋卉卉 ,  藏斌

downloadPDF
引用本文: 马双忱, 王梦璇, 宋卉卉, 藏斌. 液相共存成分对氨法脱碳吸收液解吸CO2的影响研究[J]. 燃料化学学报, 2013, 41(4): 477-483. shu
Citation:  MA Shuang-chen, WANG Meng-xuan, SONG Hui-hui, ZANG Bin. Influence of liquid coexisting components on CO2 desorption from decarburization absorbing solution by ammonia method[J]. Journal of Fuel Chemistry and Technology, 2013, 41(4): 477-483. shu

液相共存成分对氨法脱碳吸收液解吸CO2的影响研究

    通讯作者: 马双忱(1968-), 男, 辽宁大连人, 教授, 博士, 主要从事燃煤烟气污染控制方面的研究. Tel: 0312-7522714; E-mail: msc1225@163.com.
  • 基金项目:

    国家自然科学基金(21176064). (21176064)

摘要: 考察了烟气中SO2、NOx和CO2与氨水的反应机理,研究了模拟解吸液解吸过程中主要液相共存成分,如(NH4)2SO3、(NH4)2SO4、NH4NO3、NaCl、NH4Cl和(NH4)2CO3对CO2解吸的影响.研究表明,不同液相共存成分、质量分数、pH值、表面张力等对CO2解吸产生一定影响,大部分液相共存成分的存在,会降低脱碳溶液CO2的解吸量.质量分数低于10％的液相共存组分对脱碳吸收液CO2解吸过程的制约作用依次为(NH4)2SO3>NH4NO3>(NH4)2SO4>NaCl>(NH4)2CO3.因此,在碳捕集前应对烟气中的杂质成分进行脱除,减少其对解吸液理化特性的影响.

English

  • 

    1. [1] REINER D, LIANG X. Opportunities and hurdles in applying CCS technologies in China-with a focus on industrial stakeholders[J]. Energy Procedia, 2009, 1(1): 4827-4834.[1] REINER D, LIANG X. Opportunities and hurdles in applying CCS technologies in China-with a focus on industrial stakeholders[J]. Energy Procedia, 2009, 1(1): 4827-4834.

    2. [2] DERKS P W J, VERSTEEG G F. Kinetics of absorption of carbon dioxide in aqueous ammonia solutions[J]. Energy Procedia, 2009, 1: 1139-1146.[2] DERKS P W J, VERSTEEG G F. Kinetics of absorption of carbon dioxide in aqueous ammonia solutions[J]. Energy Procedia, 2009, 1: 1139-1146.

    3. [3] PEHNT M, HENKEL J. Life cycle assessment of carbon dioxide capture and storage from lignite power plants[J]. Int J Green Gas Con, 2009, 3(1): 49-66.[3] PEHNT M, HENKEL J. Life cycle assessment of carbon dioxide capture and storage from lignite power plants[J]. Int J Green Gas Con, 2009, 3(1): 49-66.

    4. [4] IPCC, IPCC Fourth Assessment Report (AR4). Cambridge: Cambridge University Press, 2007.[4] IPCC, IPCC Fourth Assessment Report (AR4). Cambridge: Cambridge University Press, 2007.

    5. [5] SCHIMEL D S, HOUSE J I, HIBBARD K A. Recent patterns and mechanisms of carbon exchange by terrestrial ecosystems[J]. Nature, 2001, 414: 169-172.[5] SCHIMEL D S, HOUSE J I, HIBBARD K A. Recent patterns and mechanisms of carbon exchange by terrestrial ecosystems[J]. Nature, 2001, 414: 169-172.

    6. [6] THE CLIMATE GROUP. CCS in China: Status, challenges and opportunities . Beijing, 2010[6] THE CLIMATE GROUP. CCS in China: Status, challenges and opportunities . Beijing, 2010

    7. [7] RUBIN E S, CHEN C, RAO A B. Cost and performance of fossil fuel power plants with CO2 capture and storage[J]. Energy Policy, 2007, 35: 4444-4454[7] RUBIN E S, CHEN C, RAO A B. Cost and performance of fossil fuel power plants with CO2 capture and storage[J]. Energy Policy, 2007, 35: 4444-4454

    8. [8] IPCC. Carbon dioxide capture and storage[M]. Cambridge: Cambridge University Press, 2005.[8] IPCC. Carbon dioxide capture and storage[M]. Cambridge: Cambridge University Press, 2005.

    9. [9] PAZUKI G R, PAHLEVANZADEH H and MOHSENI AHOOEI A. Solubility of CO2 in aqueous ammonia solution at low temperature[J]. Calphad, 2006, 30(1): 27-32.[9] PAZUKI G R, PAHLEVANZADEH H and MOHSENI AHOOEI A. Solubility of CO2 in aqueous ammonia solution at low temperature[J]. Calphad, 2006, 30(1): 27-32.

    10. [10] RESNIK K R, YEH J T, PENNLINE H W. Aqua ammonia process for simultaneous removal of CO2, SO2 and NOx[J]. Envir Technol Manag, 2004, 4(1／2): 89-103.[10] RESNIK K R, YEH J T, PENNLINE H W. Aqua ammonia process for simultaneous removal of CO2, SO2 and NOx[J]. Envir Technol Manag, 2004, 4(1／2): 89-103.

    11. [11] 蒋丽芬, 娄爱娟. 多功能脱硫塔在氨法烟气脱硫中的应用[J]. 化工进展, 2011, 30(12): 2804-2808. (JIANG Li-fen, LOU Ai-juan. Application of multifunctional desulphurization tower in flue gas desulphurization by ammonia method[J]. Chemical Industry and Engineering Progress, 2011, 30(12): 2804-2808.)[11] 蒋丽芬, 娄爱娟. 多功能脱硫塔在氨法烟气脱硫中的应用[J]. 化工进展, 2011, 30(12): 2804-2808. (JIANG Li-fen, LOU Ai-juan. Application of multifunctional desulphurization tower in flue gas desulphurization by ammonia method[J]. Chemical Industry and Engineering Progress, 2011, 30(12): 2804-2808.)

    12. [12] AHMED A B,OSAMA I F,NOUSHAD K, SERAJ A G, ANDRZEJ C, JANUSZ L, ANDRZEJ P, BOGDAN T, ZBIGNIEW Z. Electron beam flue gas treatment technology for simultaneous removal of SO2 and NOx from combustion of liquid fuels[J]. Fuel, 2008, 28(3): 1446-1452.[12] AHMED A B,OSAMA I F,NOUSHAD K, SERAJ A G, ANDRZEJ C, JANUSZ L, ANDRZEJ P, BOGDAN T, ZBIGNIEW Z. Electron beam flue gas treatment technology for simultaneous removal of SO2 and NOx from combustion of liquid fuels[J]. Fuel, 2008, 28(3): 1446-1452.

    13. [13] WHITTAKER A G, MOUNT A R, HEAL M R. Physical chemistry[M]. Beijing: Science Press, 2001.[13] WHITTAKER A G, MOUNT A R, HEAL M R. Physical chemistry[M]. Beijing: Science Press, 2001.

    14. [14] PRADHAN M P, JOSHI J B. Absorption of NOx gas in aqueous NaOH solutions: Selectivity and optimization[J]. AIChE J. 1999, 45(1): 38-50.[14] PRADHAN M P, JOSHI J B. Absorption of NOx gas in aqueous NaOH solutions: Selectivity and optimization[J]. AIChE J. 1999, 45(1): 38-50.

    15. [15] THOMAS D,VANDERSCHUREN J. Analysis and prediction of the liquid phase composition for the absorption of nitrogen oxides into aqueous solutions[J].Se Purif Technol, 2000, 18(1): 37-45.[15] THOMAS D,VANDERSCHUREN J. Analysis and prediction of the liquid phase composition for the absorption of nitrogen oxides into aqueous solutions[J].Se Purif Technol, 2000, 18(1): 37-45.

    16. [16] AOKI M, TNAKA H, KOMIYAMA H, NOUE H. Simultaneous absorption of NO and NO2 into alkaline solutions[J]. J Chem Eng Jpn, 1982, 15(5): 362-367.[16] AOKI M, TNAKA H, KOMIYAMA H, NOUE H. Simultaneous absorption of NO and NO2 into alkaline solutions[J]. J Chem Eng Jpn, 1982, 15(5): 362-367.

    17. [17] DE PAIVA J L, KACHAN G C. Absorption of nitrogen oxides in aqueous solutions in a structured packing pilot column[J]. Chem Eng Process, 2004, 43(7): 941-948.[17] DE PAIVA J L, KACHAN G C. Absorption of nitrogen oxides in aqueous solutions in a structured packing pilot column[J]. Chem Eng Process, 2004, 43(7): 941-948.

    18. [18] 马双忱, 孙云雪, 赵毅, 方文武, 韩剑, 梁丕昭. 氨水捕集模拟烟气中二氧化碳的实验与理论研究[J].化学学报, 2011, 69(12): 1469-1474. (MA Shuang-chen, SUN Yun-xue, Zhao Yi, FANG Wen-wu, HAN Jian, LIANG Pi-zhao. Experimental and mechanism research on CO2 capture from simulating flue gas using ammonia solution[J] Acta Chim Sinica, 2011, 69(12): 1469-1474.)[18] 马双忱, 孙云雪, 赵毅, 方文武, 韩剑, 梁丕昭. 氨水捕集模拟烟气中二氧化碳的实验与理论研究[J].化学学报, 2011, 69(12): 1469-1474. (MA Shuang-chen, SUN Yun-xue, Zhao Yi, FANG Wen-wu, HAN Jian, LIANG Pi-zhao. Experimental and mechanism research on CO2 capture from simulating flue gas using ammonia solution[J] Acta Chim Sinica, 2011, 69(12): 1469-1474.)

    19. [19] 刘少敏. 碳酸平衡规律在水质分析中碱度测定的应用[J]. 淮南职业技术学院学报, 2002, 2(2): 75-77. (LIU Shao-min. Application on the balance of carbonic acid in the alkalinity measurement of the water analysis[J]. Journal of Huainan vocational & technical college, 2002, 2(2): 75-77.[19] 刘少敏. 碳酸平衡规律在水质分析中碱度测定的应用[J]. 淮南职业技术学院学报, 2002, 2(2): 75-77. (LIU Shao-min. Application on the balance of carbonic acid in the alkalinity measurement of the water analysis[J]. Journal of Huainan vocational & technical college, 2002, 2(2): 75-77.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  477
  • HTML全文浏览量:  43
文章相关
  • 收稿日期:  2012-09-11
  • 网络出版日期:  2012-11-23
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net