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不同有机胺修饰MCM-41的CO2吸附性能和热稳定性

刘之琳 ,  滕阳 ,  张锴 ,  曹晏 ,  潘伟平

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引用本文: 刘之琳, 滕阳, 张锴, 曹晏, 潘伟平. 不同有机胺修饰MCM-41的CO2吸附性能和热稳定性[J]. 燃料化学学报, 2013, 41(4): 469-476. shu
Citation:  LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. Journal of Fuel Chemistry and Technology, 2013, 41(4): 469-476. shu

不同有机胺修饰MCM-41的CO2吸附性能和热稳定性

    通讯作者: 张锴, E-mail: kzhang@ncepu.edu.cn.
  • 基金项目:

    国家自然科学基金 (51061130538) (51061130538)

    国家高技术发展研究计划(863计划, 2012AA06A115) (863计划, 2012AA06A115)

    111引智计划(B12034). (B12034)

摘要: 将乙二胺(EDA,60 g/mol)、四乙烯五胺(TEPA,189 g/mol)和两种聚乙烯亚胺600(PEI600g/mol; PEI1800g/mol)分别负载在MCM-41上制备氨基功能化介孔材料,研究其对CO2的吸附性能和热稳定性.结果表明,除了EDA-MCM41,其他三种材料随着胺分子量增大CO2吸附性能下降,但是热稳定性却有所提高,其中,TEPA-MCM41的吸附容量最大,达到2.7 mmol/g.同时发现,乙二胺在制备过程中随溶剂挥发而难以完全负载在MCM-41上.在纯N2气氛和再生温度100 ℃条件下,经10次循环实验后,TEPA-MCM41的吸附能力下降了7.4%,而PEI600-MCM41和PEI1800-MCM41吸附能力保持不变,且质量变化在1%以内,表现出良好的再生稳定性.采用80%CO2/20%N2对吸附饱和的材料进行再生,四种材料的再生温度将提高到160 ℃以上,高分子量PEI600-MCM41和PEI1800-MCM41相比于TEPA-MCM41具有更好的热稳定性.

English

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  • 收稿日期:  2012-09-29
  • 网络出版日期:  2012-12-11
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